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The two representative compounds contain a well-established Cu<jats:sub>3<\/jats:sub>cluster supporting a given 4<jats:sup>4<\/jats:sup>network. The ligand length is the underlying factor that controls the degree of interpenetration. Controlled interpenetration can be facile to realise by elongating protocols. Compound<jats:bold>I<\/jats:bold>shows a non-interpenetrating 4<jats:sup>4<\/jats:sup>network, whereas<jats:bold>II<\/jats:bold>features a threefold interpenetrating network. Furthermore, similar hydrogen-bond interactions extend the different interpenetrating 4<jats:sup>4<\/jats:sup>networks into three-dimensional supramolecular topologies. Variable-temperature magnetic studies showed a ferromagnetic coupling behaviour in the two complexes.<\/jats:p>","DOI":"10.1107\/s2053229618014262","type":"journal-article","created":{"date-parts":[[2018,10,26]],"date-time":"2018-10-26T12:49:30Z","timestamp":1540558170000},"page":"1540-1546","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Controlled interpenetration of 4<sup>4<\/sup>networks: syntheses and structures of two Cu<sub>3<\/sub>-cluster coordination polymers"],"prefix":"10.1107","volume":"74","author":[{"given":"Guanghui","family":"Sun","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Weilian","family":"Xie","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hong","family":"Xiao","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Guohai","family":"Xu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2018,10,26]]},"reference":[{"key":"jx3020_bb1","unstructured":"Batten, S. 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