{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,15]],"date-time":"2025-10-15T17:51:39Z","timestamp":1760550699449,"version":"3.33.0"},"reference-count":36,"publisher":"International Union of Crystallography (IUCr)","issue":"12","license":[{"start":{"date-parts":[[2018,11,15]],"date-time":"2018-11-15T00:00:00Z","timestamp":1542240000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2018,11,15]],"date-time":"2018-11-15T00:00:00Z","timestamp":1542240000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"accepted":{"date-parts":[[2018,11,5]]},"published-print":{"date-parts":[[2018,12,1]]},"abstract":"<jats:p>Two products of the reactions of CuI with 1-benzoyl-3-(4-bromophenyl)thiourea and with 1-benzoyl-3-(2-iodophenyl)thiourea have been obtained and characterized, namely poly[[[1-benzoyl-3-(4-bromophenyl)thiourea-\u03ba<jats:italic>S<\/jats:italic>]-\u03bc<jats:sub>3<\/jats:sub>-iodido-copper(I)] acetone hemisolvate], {[CuI(C<jats:sub>14<\/jats:sub>H<jats:sub>11<\/jats:sub>BrN<jats:sub>2<\/jats:sub>OS)]\u00b70.5C<jats:sub>3<\/jats:sub>H<jats:sub>6<\/jats:sub>O}<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub>, and poly[\u03bc<jats:sub>4<\/jats:sub>-iodido-\u03bc<jats:sub>3<\/jats:sub>-iodido-[<jats:italic>N<\/jats:italic>-(benzo[<jats:italic>d<\/jats:italic>]thiazol-2-yl)benzamide-\u03ba<jats:italic>N<\/jats:italic>]dicopper(I)], [Cu<jats:sub>2<\/jats:sub>I<jats:sub>2<\/jats:sub>(C<jats:sub>14<\/jats:sub>H<jats:sub>10<\/jats:sub>N<jats:sub>2<\/jats:sub>OS)]<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub>. Their structures, determined by single-crystal X-ray diffraction analysis, exhibit different stoichiometries and molecular organizations; however, both compounds are polymeric and possess close Cu...Cu contacts. The first product contains a (CuI)<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub> double chain supported by the thiourea derivative coordinated <jats:italic>via<\/jats:italic> the S atom. In the second case, the ligand undergoes dehalogenation and cyclization to form <jats:italic>N<\/jats:italic>-(benzo[<jats:italic>d<\/jats:italic>]thiazol-2-yl)benzamide that serves as the <jats:italic>N<\/jats:italic>-donor ligand which is connected to both sides of a (CuI)<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub> quadruple chain. In both hybrid inorganic chains, I atoms bridge three or four Cu atoms. The coordination centres adopt more or less distorted tetrahedral geometries. The structures of the (CuI)<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub> kernels of the ribbons are similar to fragments of the layers in high-pressure phase V copper(I) iodide. Only weak S...O, C\u2014H...O, C\u2014H...I and \u03c0\u2013\u03c0 interactions hold the ribbons together, allowing the formation of crystals.<\/jats:p>","DOI":"10.1107\/s2053229618015620","type":"journal-article","created":{"date-parts":[[2018,11,15]],"date-time":"2018-11-15T16:59:17Z","timestamp":1542301157000},"page":"1650-1655","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":5,"title":["Copper(I) iodide ribbons coordinated with thiourea derivatives"],"prefix":"10.1107","volume":"74","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0710-3531","authenticated-orcid":true,"given":"Damian","family":"Rosiak","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2955-8046","authenticated-orcid":true,"given":"Andrzej","family":"Okuniewski","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2453-8214","authenticated-orcid":true,"given":"Jaros\u0142aw","family":"Chojnacki","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2018,11,15]]},"reference":[{"key":"qf3017_bb1","doi-asserted-by":"crossref","first-page":"3858","DOI":"10.1039\/C8CE00594J","volume":"20","author":"Ate\u015f","year":"2018","journal-title":"CrystEngComm"},{"key":"qf3017_bb2","doi-asserted-by":"crossref","unstructured":"Berry, J. 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