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In the case of the bulky 4,4\u2032-(anthracene-9,10-diyl)dibenzoic acid ligand (abdH<jats:sub>2<\/jats:sub>), we demonstrate that the presence of numerous \u03c0\u2013\u03c0 and C\u2014H...\u03c0 interactions outweigh the formation of saturated coordination complexes with zinc, leading to the formation of a dimethylformamide (DMF) solvate, namely 4,4\u2032-(anthracene-9,10-diyl)dibenzoic acid dimethylformamide disolvate, C<jats:sub>28<\/jats:sub>H<jats:sub>18<\/jats:sub>O<jats:sub>4<\/jats:sub>\u00b72C<jats:sub>3<\/jats:sub>H<jats:sub>7<\/jats:sub>NO or<jats:bold>[(abdH<jats:sub>2<\/jats:sub>)(DMF)<jats:sub>2<\/jats:sub>]<\/jats:bold>, at low concentrations of zinc. Meanwhile, at higher zinc concentrations, the abdH<jats:sub>2<\/jats:sub>ligand gives rise to the nonporous one-dimensional coordination polymer<jats:italic>catena<\/jats:italic>-poly[[bis(dimethylformamide-\u03ba<jats:italic>O<\/jats:italic>)zinc(II)]-\u03bc-4,4\u2032-(anthracene-9,10-diyl)dibenzoato-\u03ba<jats:sup>2<\/jats:sup><jats:italic>O<\/jats:italic>:<jats:italic>O<\/jats:italic>\u2032], [Zn(C<jats:sub>28<\/jats:sub>H<jats:sub>16<\/jats:sub>O<jats:sub>4<\/jats:sub>)(C<jats:sub>3<\/jats:sub>H<jats:sub>7<\/jats:sub>NO)<jats:sub>2<\/jats:sub>]<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>or<jats:bold>[Zn(abd)(DMF)<jats:sub>2<\/jats:sub>]<\/jats:bold><jats:italic><jats:bold><jats:sub>n<\/jats:sub><\/jats:bold><\/jats:italic>, when assembled in dimethylformamide, while a related compound is observed when<jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>-dimethylacetamide (DMA) is used as the solvent, namely<jats:italic>catena<\/jats:italic>-poly[[[bis(<jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>-dimethylacetamide-\u03ba<jats:italic>O<\/jats:italic>)zinc(II)]-\u03bc-4,4\u2032-(anthracene-9,10-diyl)dibenzoato-\u03ba<jats:sup>2<\/jats:sup><jats:italic>O<\/jats:italic>:<jats:italic>O<\/jats:italic>\u2032]<jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>-dimethylacetamide monosolvate], {[Zn(C<jats:sub>28<\/jats:sub>H<jats:sub>16<\/jats:sub>O<jats:sub>4<\/jats:sub>)(C<jats:sub>4<\/jats:sub>H<jats:sub>9<\/jats:sub>NO)<jats:sub>2<\/jats:sub>]\u00b7C<jats:sub>4<\/jats:sub>H<jats:sub>9<\/jats:sub>NO}<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>or<jats:bold>{[Zn(abd)(DMA)<jats:sub>2<\/jats:sub>]\u00b7DMA}<\/jats:bold><jats:italic><jats:bold><jats:sub>n<\/jats:sub><\/jats:bold><\/jats:italic>. Attempts to use other amide-based solvents did not give rise to any other assembled structures.<\/jats:p>","DOI":"10.1107\/s2053229618016649","type":"journal-article","created":{"date-parts":[[2018,11,29]],"date-time":"2018-11-29T17:06:03Z","timestamp":1543511163000},"page":"1774-1780","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["One-dimensional networks formed<i>via<\/i>the self-assembly of anthracenedibenzoic acid with zinc(II)"],"prefix":"10.1107","volume":"74","author":[{"given":"Allison M.","family":"Rabon","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7064-7780","authenticated-orcid":true,"given":"Kayla L.","family":"Goolsby","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Michael C.","family":"Young","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2018,11,30]]},"reference":[{"key":"sk3702_bb1","doi-asserted-by":"crossref","first-page":"59","DOI":"10.1016\/0022-2860(85)85041-9","volume":"128","author":"Almenningen","year":"1985","journal-title":"J. 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