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Herein, six isostructural group IIB coordination compounds containing a 2-{[(2-methoxyphenyl)imino]methyl}phenol ligand, namely dichloridobis(2-{(\n                    <jats:italic>E<\/jats:italic>\n                    )-[(2-methoxyphenyl)azaniumylidene]methyl}phenolato-\u03ba\n                    <jats:italic>O<\/jats:italic>\n                    )zinc(II), [ZnCl\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>28<\/jats:sub>\n                    H\n                    <jats:sub>26<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    )],\n                    <jats:bold>1<\/jats:bold>\n                    , diiodidobis(2-{(\n                    <jats:italic>E<\/jats:italic>\n                    )-[(2-methoxyphenyl)azaniumylidene]methyl}phenolato-\u03ba\n                    <jats:italic>O<\/jats:italic>\n                    )zinc(II), [ZnI\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>28<\/jats:sub>\n                    H\n                    <jats:sub>26<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    )],\n                    <jats:bold>2<\/jats:bold>\n                    , dibromidobis(2-{(\n                    <jats:italic>E<\/jats:italic>\n                    )-[(2-methoxyphenyl)azaniumylidene]methyl}phenolato-\u03ba\n                    <jats:italic>O<\/jats:italic>\n                    )cadmium(II), [CdBr\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>28<\/jats:sub>\n                    H\n                    <jats:sub>26<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    )],\n                    <jats:bold>3<\/jats:bold>\n                    , diiodidobis(2-{(\n                    <jats:italic>E<\/jats:italic>\n                    )-[(2-methoxyphenyl)azaniumylidene]methyl}phenolato-\u03ba\n                    <jats:italic>O<\/jats:italic>\n                    )cadmium(II), [CdI\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>28<\/jats:sub>\n                    H\n                    <jats:sub>26<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    )],\n                    <jats:bold>4<\/jats:bold>\n                    , dichloridobis(2-{(\n                    <jats:italic>E<\/jats:italic>\n                    )-[(2-methoxyphenyl)azaniumylidene]methyl}phenolato-\u03ba\n                    <jats:italic>O<\/jats:italic>\n                    )mercury(II), [HgCl\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>28<\/jats:sub>\n                    H\n                    <jats:sub>26<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    )],\n                    <jats:bold>5<\/jats:bold>\n                    , and diiodidobis(2-{(\n                    <jats:italic>E<\/jats:italic>\n                    )-[(2-methoxyphenyl)azaniumylidene]methyl}phenolato-\u03ba\n                    <jats:italic>O<\/jats:italic>\n                    )mercury(II), [HgI\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>28<\/jats:sub>\n                    H\n                    <jats:sub>26<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    )],\n                    <jats:bold>6<\/jats:bold>\n                    , were synthesized and characterized by X-ray crystallography and spectroscopic techniques. All six compounds exhibit an infinite one-dimensional ladder in the solid state governed by the formation of hydrogen-bonding and \u03c0\u2013\u03c0 stacking interactions. The crystal structures of these compounds were studied using geometrical and Hirshfeld surface analyses. They have also been studied using M06-2X\/def2-TZVP calculations and Bader's theory of `atoms in molecules'. The energies associated with the interactions, including the contribution of the different forces, have been evaluated. In general, the \u03c0\u2013\u03c0 stacking interactions are stronger than those reported for conventional \u03c0\u2013\u03c0 complexes, which is attributed to the influence of the metal coordination, which is stronger for Zn than either Cd or Hg. The results reported herein might be useful for understanding the solid-state architecture of metal-containing materials that contain\n                    <jats:italic>M<\/jats:italic>\n                    <jats:sup>II<\/jats:sup>\n                    <jats:italic>X<\/jats:italic>\n                    <jats:sub>2<\/jats:sub>\n                    subunits and aromatic organic ligands.\n                  <\/jats:p>","DOI":"10.1107\/s2053229618018314","type":"journal-article","created":{"date-parts":[[2019,1,25]],"date-time":"2019-01-25T13:01:40Z","timestamp":1548421300000},"page":"178-188","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":21,"title":["The role of \u03c0\u2013\u03c0 stacking and hydrogen-bonding interactions in the assembly of a series of isostructural group IIB coordination compounds"],"prefix":"10.1107","volume":"75","author":[{"given":"Taraneh","family":"Hajiashrafi","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Roghayeh","family":"Zekriazadeh","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1656-3177","authenticated-orcid":true,"given":"Keith J.","family":"Flanagan","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Farnoush","family":"Kia","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Antonio","family":"Bauz\u00e1","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Antonio","family":"Frontera","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7467-1654","authenticated-orcid":true,"given":"Mathias O.","family":"Senge","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2019,1,25]]},"reference":[{"key":"sk3704_bb1","doi-asserted-by":"crossref","first-page":"165","DOI":"10.1016\/0009-2614(89)85118-8","volume":"162","author":"Ahlrichs","year":"1989","journal-title":"Chem. 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