{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,4,14]],"date-time":"2025-04-14T07:44:04Z","timestamp":1744616644463,"version":"3.33.0"},"reference-count":24,"publisher":"International Union of Crystallography (IUCr)","issue":"2","license":[{"start":{"date-parts":[[2019,1,29]],"date-time":"2019-01-29T00:00:00Z","timestamp":1548720000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2019,1,29]],"date-time":"2019-01-29T00:00:00Z","timestamp":1548720000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"accepted":{"date-parts":[[2019,1,19]]},"published-print":{"date-parts":[[2019,2,1]]},"abstract":"<jats:p>A novel two-dimensional (2D) Zn<jats:sup>II<\/jats:sup> coordination framework, poly[[\u03bc-1,3-bis(2-methyl-1<jats:italic>H<\/jats:italic>-imidazol-1-yl)benzene](\u03bc-5-nitrobenzene-1,3-dicarboxylato)zinc(II)], [Zn(C<jats:sub>8<\/jats:sub>H<jats:sub>3<\/jats:sub>NO<jats:sub>6<\/jats:sub>)(C<jats:sub>14<\/jats:sub>H<jats:sub>14<\/jats:sub>N<jats:sub>4<\/jats:sub>)]<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub> or [Zn(NO<jats:sub>2<\/jats:sub>-BDC)(1,3-BMIB)]<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub> [1,3-BMIB is 1,3-bis(2-methyl-1<jats:italic>H<\/jats:italic>-imidazol-1-yl)benzene and NO<jats:sub>2<\/jats:sub>-H<jats:sub>2<\/jats:sub>BDC is 5-nitrobenzene-1,3-dicarboxylic acid], has been prepared and characterized by IR, elemental analysis, thermal analysis and single-crystal X-ray diffraction. Single-crystal X-ray diffraction analysis revealed that the compound is a new 2D polymer with a 6<jats:sup>3<\/jats:sup> topology parallel to the (10\\overline{2}) crystal planes based on left-handed helices, right-handed helical NO<jats:sub>2<\/jats:sub>-BDC\u2013Zn chains and [Zn<jats:sub>2<\/jats:sub>(1,3-BMIB)<jats:sub>2<\/jats:sub>]<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub> clusters. In the crystal, adjacent layers are further connected by C\u2014H...O hydrogen bonds, C\u2014H...\u03c0 interactions, C\u2014O...\u03c0 interactions and N\u2014O...\u03c0 interactions to form a three-dimensional structure in the solid state. In addition, the compound exhibits strong fluorescence emissions in the solid state at room temperature.<\/jats:p>","DOI":"10.1107\/s2053229619000986","type":"journal-article","created":{"date-parts":[[2019,1,29]],"date-time":"2019-01-29T17:19:41Z","timestamp":1548782381000},"page":"196-199","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":3,"title":["A new two-dimensional Zn<sup>II<\/sup> coordination polymer based on 1,3-bis(2-methyl-1<i>H<\/i>-imidazol-1-yl)benzene and 5-nitrobenzene-1,3-dicarboxylic acid: synthesis, crystal structure and physical properties"],"prefix":"10.1107","volume":"75","author":[{"given":"Ning-Ning","family":"Chen","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jian-Ning","family":"Ni","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jun","family":"Wang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jian-Qing","family":"Tao","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2019,1,29]]},"reference":[{"key":"qs3078_bb1","doi-asserted-by":"crossref","first-page":"1330","DOI":"10.1039\/b802352m","volume":"38","author":"Allendorf","year":"2009","journal-title":"Chem. 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