{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,25]],"date-time":"2026-09-25T07:05:19Z","timestamp":1790319919106,"version":"4.1.0"},"reference-count":0,"publisher":"International Union of Crystallography (IUCr)","issue":"3","license":[{"start":{"date-parts":[[2019,2,12]],"date-time":"2019-02-12T00:00:00Z","timestamp":1549929600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2019,2,12]],"date-time":"2019-02-12T00:00:00Z","timestamp":1549929600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21071156"],"award-info":[{"award-number":["21071156"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100005230","name":"Natural Science Foundation of Chongqing","doi-asserted-by":"crossref","award":["CSTC2015JCYJA50007 and CSTC2014GJHZ0030"],"award-info":[{"award-number":["CSTC2015JCYJA50007 and CSTC2014GJHZ0030"]}],"id":[{"id":"10.13039\/501100005230","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"accepted":{"date-parts":[[2019,1,31]]},"published-print":{"date-parts":[[2019,3,1]]},"abstract":"<jats:p>The assembly of metal\u2013organic frameworks (MOFs) with metal ions and organic ligands is currently attracting considerable attention in crystal engineering and materials science due to their intriguing architectures and potential applications. A new three-dimensional MOF, namely poly[[diaqua(\u03bc<jats:sub>8<\/jats:sub>-<jats:italic>para<\/jats:italic>-terphenyl-3,3\u2032,5,5\u2032-tetracarboxylato)dizinc(II)] dimethylformamide disolvate monohydrate], {[Zn<jats:sub>2<\/jats:sub>(C<jats:sub>22<\/jats:sub>H<jats:sub>10<\/jats:sub>O<jats:sub>8<\/jats:sub>)(H<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub>]\u00b72C<jats:sub>3<\/jats:sub>H<jats:sub>7<\/jats:sub>NO\u00b7H<jats:sub>2<\/jats:sub>O}<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub>, was synthesized by the self-assembly of Zn(NO<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>\u00b76H<jats:sub>2<\/jats:sub>O and <jats:italic>para<\/jats:italic>-terphenyl-3,3\u2032,5,5\u2032-tetracarboxylic acid (H<jats:sub>4<\/jats:sub>TPTC) under solvothermal conditions. The compound was structurally characterized by FT\u2013IR spectroscopy, elemental analysis and single-crystal X-ray diffraction analysis. Each Zn<jats:sup>II<\/jats:sup> ion is located in a square-pyramidal geometry and is coordinated by four carboxylate O atoms from four different TPTC<jats:sup>4\u2212<\/jats:sup> ligands. Pairs of adjacent equivalent Zn<jats:sup>II<\/jats:sup> ions are bridged by four carboxylate groups, forming [Zn<jats:sub>2<\/jats:sub>(O<jats:sub>2<\/jats:sub>C<jats:italic>R<\/jats:italic>)<jats:sub>4<\/jats:sub>] (<jats:italic>R<\/jats:italic> = terphenyl) paddle-wheel units. One aqua ligand binds to each Zn<jats:sup>II<\/jats:sup> centre along the paddle-wheel axis. Each [Zn<jats:sub>2<\/jats:sub>(O<jats:sub>2<\/jats:sub>C<jats:italic>R<\/jats:italic>)<jats:sub>4<\/jats:sub>] paddle wheel is further linked to four terphenyl connectors to give a three-dimensional framework with NBO-type topology. The thermal stability and solid-state photoluminescence properties of the title compound have also been investigated.<\/jats:p>","DOI":"10.1107\/s205322961900189x","type":"journal-article","created":{"date-parts":[[2019,2,12]],"date-time":"2019-02-12T17:39:32Z","timestamp":1549993172000},"page":"277-282","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":6,"title":["Synthesis, crystal structure and photoluminescence of a three-dimensional zinc coordination compound with NBO-type topology"],"prefix":"10.1107","volume":"75","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-7343-3443","authenticated-orcid":true,"given":"Xi","family":"Liu","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bo","family":"Fu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lin","family":"Li","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yun-Fei","family":"Jian","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Si","family":"Shu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2019,2,12]]},"container-title":["Acta Crystallographica Section C Structural Chemistry"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/c\/issues\/2019\/03\/00\/sk3719\/sk3719.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/c\/issues\/2019\/03\/00\/sk3719\/sk3719.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T10:26:49Z","timestamp":1736764009000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S205322961900189X"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2019,2,12]]},"references-count":0,"journal-issue":{"issue":"3","published-online":{"date-parts":[[2019,3]]}},"alternative-id":["S205322961900189X"],"URL":"https:\/\/doi.org\/10.1107\/s205322961900189x","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S205322961900189X\/sk3719sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S205322961900189X\/sk3719Isup2.hkl","asserted-by":"subject"}]},"ISSN":["2053-2296"],"issn-type":[{"value":"2053-2296","type":"electronic"}],"subject":[],"published":{"date-parts":[[2019,2,12]]},"assertion":[{"value":"Acta Crystallographica Section C: Structural Chemistry","order":0,"name":"journal","label":"Publication","explanation":{"URL":"http:\/\/journals.iucr.org\/c"},"group":{"name":"general","label":"General"}},{"value":"research papers","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/c\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"http:\/\/scripts.iucr.org\/cgi-bin\/citedin?sk3719","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"10 January 2019","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"31 January 2019","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"12 February 2019","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"http:\/\/scripts.iucr.org\/cgi-bin\/sendsup?sk3719"}},{"value":"\u00a9 2019 International Union of Crystallography","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licensing","label":"Copyright and licencing"}}]}}