{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T21:21:07Z","timestamp":1740172867287,"version":"3.37.3"},"reference-count":27,"publisher":"International Union of Crystallography (IUCr)","issue":"4","license":[{"start":{"date-parts":[[2019,3,26]],"date-time":"2019-03-26T00:00:00Z","timestamp":1553558400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2019,3,26]],"date-time":"2019-03-26T00:00:00Z","timestamp":1553558400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21771120"],"award-info":[{"award-number":["21771120"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"accepted":{"date-parts":[[2019,3,18]]},"published-print":{"date-parts":[[2019,4,1]]},"abstract":"<jats:p>Three new one- (1D) and two-dimensional (2D) Cu<jats:sup>II<\/jats:sup> coordination polymers, namely poly[[bis{\u03bc<jats:sub>2<\/jats:sub>-4-amino-3-(pyridin-2-yl)-5-[(pyridin-3-ylmethyl)sulfanyl]-1,2,4-triazole}copper(II)] bis(methanesulfonate) tetrahydrate], {[Cu(C<jats:sub>13<\/jats:sub>H<jats:sub>12<\/jats:sub>N<jats:sub>5<\/jats:sub>S)<jats:sub>2<\/jats:sub>](CH<jats:sub>3<\/jats:sub>SO<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>\u00b74H<jats:sub>2<\/jats:sub>O}<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub> (<jats:bold>1<\/jats:bold>), <jats:italic>catena<\/jats:italic>-poly[[copper(II)-bis{\u03bc<jats:sub>2<\/jats:sub>-4-amino-3-(pyridin-2-yl)-5-[(pyridin-4-ylmethyl)sulfanyl]-1,2,4-triazole}] dinitrate methanol disolvate], {[Cu(C<jats:sub>13<\/jats:sub>H<jats:sub>12<\/jats:sub>N<jats:sub>5<\/jats:sub>S)<jats:sub>2<\/jats:sub>](NO<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>\u00b72CH<jats:sub>3<\/jats:sub>OH}<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub> (<jats:bold>2<\/jats:bold>), and <jats:italic>catena<\/jats:italic>-poly[[copper(II)-bis{\u03bc<jats:sub>2<\/jats:sub>-4-amino-3-(pyridin-2-yl)-5-[(pyridin-4-ylmethyl)sulfanyl]-1,2,4-triazole}] bis(perchlorate) monohydrate], {[Cu(C<jats:sub>13<\/jats:sub>H<jats:sub>12<\/jats:sub>N<jats:sub>5<\/jats:sub>S)<jats:sub>2<\/jats:sub>](ClO<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>\u00b7H<jats:sub>2<\/jats:sub>O}<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub> (<jats:bold>3<\/jats:bold>), were obtained from 4-amino-3-(pyridin-2-yl)-5-[(pyridin-3-ylmethyl)sulfanyl]-1,2,4-triazole with pyridin-3-yl terminal groups and from 4-amino-3-(pyridin-2-yl)-5-[(pyridin-4-ylmethyl)sulfanyl]-1,2,4-triazole with pyridin-4-yl terminal groups. Compound <jats:bold>1<\/jats:bold> displays a 2D net-like structure. The 2D layers are further linked through hydrogen bonds between methanesulfonate anions and amino groups on the framework and guest H<jats:sub>2<\/jats:sub>O molecules in the lattice to form a three-dimensional (3D) structure. Compound <jats:bold>2<\/jats:bold> and <jats:bold>3<\/jats:bold> exhibit 1D chain structures, in which the complicated hydrogen-bonding interactions play an important role in the formation of the 3D network. These experimental results indicate that the coordination orientation of the heteroatoms on the ligands has a great influence on the polymeric structures. Moreover, the selection of different counter-anions, together with the inclusion of different guest solvent molecules, would also have a great effect on the hydrogen-bonding systems in the crystal structures.<\/jats:p>","DOI":"10.1107\/s2053229619003747","type":"journal-article","created":{"date-parts":[[2019,3,25]],"date-time":"2019-03-25T16:27:23Z","timestamp":1553531243000},"page":"443-450","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["The effect of the coordination orientation of N atoms on polymeric structures: synthesis and characterization of one- and two-dimensional Cu<sup>II<\/sup> coordination polymers based on 4-amino-3-(pyridin-2-yl)-5-[(pyridin-3-ylmethyl)sulfanyl]-1,2,4-triazole"],"prefix":"10.1107","volume":"75","author":[{"given":"Guiying","family":"Zhu","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yang","family":"Lu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Guoxia","family":"Jin","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xuan","family":"Ji","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5300-3307","authenticated-orcid":true,"given":"Jianping","family":"Ma","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2019,3,26]]},"reference":[{"key":"yp3177_bb1","doi-asserted-by":"crossref","first-page":"C593","DOI":"10.1107\/S0108767311084984","volume":"67","author":"Bourhis","year":"2011","journal-title":"Acta Cryst. A"},{"key":"yp3177_bb2","doi-asserted-by":"crossref","first-page":"2184","DOI":"10.1021\/jp908202s","volume":"114","author":"Culp","year":"2010","journal-title":"J. Phys. Chem. C"},{"key":"yp3177_bb3","doi-asserted-by":"crossref","first-page":"339","DOI":"10.1107\/S0021889808042726","volume":"42","author":"Dolomanov","year":"2009","journal-title":"J. Appl. Cryst."},{"key":"yp3177_bb4","doi-asserted-by":"crossref","first-page":"789","DOI":"10.1021\/cg049808b","volume":"5","author":"Dong","year":"2005","journal-title":"Cryst. Growth Des."},{"key":"yp3177_bb5","doi-asserted-by":"crossref","first-page":"5521","DOI":"10.1039\/b509875k","author":"Du","year":"2005","journal-title":"Chem. Commun."},{"key":"yp3177_bb6","doi-asserted-by":"crossref","first-page":"2281","DOI":"10.1016\/j.ccr.2010.03.003","volume":"254","author":"Dul","year":"2010","journal-title":"Coord. Chem. Rev."},{"key":"yp3177_bb7","doi-asserted-by":"crossref","first-page":"122","DOI":"10.1016\/j.ica.2012.02.002","volume":"386","author":"Ishikawa","year":"2012","journal-title":"Inorg. Chim. Acta"},{"key":"yp3177_bb8","doi-asserted-by":"crossref","first-page":"9284","DOI":"10.1021\/ic200540c","volume":"50","author":"Li","year":"2011","journal-title":"Inorg. Chem."},{"key":"yp3177_bb9","doi-asserted-by":"crossref","first-page":"6011","DOI":"10.1039\/C4CS00094C","volume":"43","author":"Liu","year":"2014","journal-title":"Chem. Soc. Rev."},{"key":"yp3177_bb10","doi-asserted-by":"crossref","first-page":"4112","DOI":"10.1002\/adma.201000197","volume":"22","author":"Liu","year":"2010","journal-title":"Adv. Mater."},{"key":"yp3177_bb11","doi-asserted-by":"crossref","first-page":"1039","DOI":"10.1021\/acsmacrolett.6b00567","volume":"5","author":"Ma","year":"2016","journal-title":"ACS Macro Lett."},{"key":"yp3177_bb12","doi-asserted-by":"crossref","first-page":"304","DOI":"10.1039\/C3CE41886C","volume":"16","author":"Ma","year":"2014","journal-title":"CrystEngComm"},{"key":"yp3177_bb13","doi-asserted-by":"crossref","first-page":"786","DOI":"10.1107\/S0021889807029238","volume":"40","author":"Palatinus","year":"2007","journal-title":"J. Appl. Cryst."},{"key":"yp3177_bb14","doi-asserted-by":"crossref","first-page":"2891","DOI":"10.1039\/c2ce06581a","volume":"14","author":"Qin","year":"2012","journal-title":"CrystEngComm"},{"key":"yp3177_bb15","doi-asserted-by":"crossref","first-page":"m147","DOI":"10.1107\/S0108270112017659","volume":"68","author":"Qin","year":"2012","journal-title":"Acta Cryst. C"},{"key":"yp3177_bb16","unstructured":"Rigaku OD (2015). CrysAlis PRO. Rigaku Oxford Diffraction Ltd, Yarnton, Oxfordshire, England."},{"key":"yp3177_bb17","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","volume":"64","author":"Sheldrick","year":"2008","journal-title":"Acta Cryst. A"},{"key":"yp3177_bb18","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"yp3177_bb19","doi-asserted-by":"crossref","first-page":"4179","DOI":"10.1039\/C5CE00411J","volume":"17","author":"Wang","year":"2015","journal-title":"CrystEngComm"},{"key":"yp3177_bb20","doi-asserted-by":"crossref","first-page":"3955","DOI":"10.1039\/C8CE00820E","volume":"20","author":"Wu","year":"2018","journal-title":"CrystEngComm"},{"key":"yp3177_bb21","doi-asserted-by":"crossref","first-page":"5864","DOI":"10.1039\/C7CE01379E","volume":"19","author":"Wu","year":"2017","journal-title":"CrystEngComm"},{"key":"yp3177_bb22","doi-asserted-by":"crossref","first-page":"1677","DOI":"10.1039\/C1CS15196G","volume":"41","author":"Xuan","year":"2012","journal-title":"Chem. Soc. Rev."},{"key":"yp3177_bb23","doi-asserted-by":"crossref","first-page":"5401","DOI":"10.1039\/c1ce05396e","volume":"13","author":"Yang","year":"2011","journal-title":"CrystEngComm"},{"key":"yp3177_bb24","doi-asserted-by":"crossref","first-page":"33","DOI":"10.1021\/ic0348244","volume":"43","author":"Yi","year":"2004","journal-title":"Inorg. Chem."},{"key":"yp3177_bb25","first-page":"2345","volume":"33","author":"Yu","year":"2017","journal-title":"Chin. J. Inorg. Chem."},{"key":"yp3177_bb26","doi-asserted-by":"crossref","first-page":"8107","DOI":"10.1039\/C7NJ01072A","volume":"41","author":"Zhang","year":"2017","journal-title":"New J. Chem."},{"key":"yp3177_bb27","doi-asserted-by":"crossref","first-page":"410","DOI":"10.1039\/C6DT04059D","volume":"46","author":"Zhang","year":"2017","journal-title":"Dalton Trans."}],"container-title":["Acta Crystallographica Section C Structural Chemistry"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/c\/issues\/2019\/04\/00\/yp3177\/yp3177.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/c\/issues\/2019\/04\/00\/yp3177\/yp3177.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T10:24:26Z","timestamp":1736763866000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2053229619003747"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2019,3,26]]},"references-count":27,"journal-issue":{"issue":"4","published-online":{"date-parts":[[2019,4]]}},"alternative-id":["S2053229619003747"],"URL":"https:\/\/doi.org\/10.1107\/s2053229619003747","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2053229619003747\/yp3177sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2053229619003747\/yp3177exp_2488sup2.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2053229619003747\/yp3177exp_2484sup3.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2053229619003747\/yp3177exp_2623sup4.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2053229619003747\/yp3177sup5.pdf","asserted-by":"subject"}]},"ISSN":["2053-2296"],"issn-type":[{"type":"electronic","value":"2053-2296"}],"subject":[],"published":{"date-parts":[[2019,3,26]]},"assertion":[{"value":"Acta Crystallographica Section C: Structural Chemistry","order":0,"name":"journal","label":"Publication","explanation":{"URL":"http:\/\/journals.iucr.org\/c"},"group":{"name":"general","label":"General"}},{"value":"research papers","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/c\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"http:\/\/scripts.iucr.org\/cgi-bin\/citedin?yp3177","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"1 February 2019","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"18 March 2019","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"26 March 2019","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"http:\/\/scripts.iucr.org\/cgi-bin\/sendsup?yp3177"}},{"value":"\u00a9 2019 International Union of Crystallography","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licensing","label":"Copyright and licencing"}}]}}