{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,6,29]],"date-time":"2026-06-29T06:30:20Z","timestamp":1782714620003,"version":"3.54.5"},"reference-count":34,"publisher":"International Union of Crystallography (IUCr)","issue":"5","license":[{"start":{"date-parts":[[2019,4,8]],"date-time":"2019-04-08T00:00:00Z","timestamp":1554681600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2019,4,8]],"date-time":"2019-04-08T00:00:00Z","timestamp":1554681600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"crossref","award":["21671082"],"award-info":[{"award-number":["21671082"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]},{"name":"Ministry of Education and the State Administration of Foreign Experts Affairs for the 111 Project","award":["B13025"],"award-info":[{"award-number":["B13025"]}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"crossref","award":["JUSRP51725B"],"award-info":[{"award-number":["JUSRP51725B"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"crossref"}]},{"name":"Jiangsu Key Laboratory for Chemistry of Low-Dimensional Materials Foundation","award":["JSKC17004"],"award-info":[{"award-number":["JSKC17004"]}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"accepted":{"date-parts":[[2019,3,28]]},"published-print":{"date-parts":[[2019,5,1]]},"abstract":"<jats:p>The title coordination polymer, poly[bis[\u03bc3-4-(3,2\u2032:6\u2032,3\u2032\u2032-terpyridin-4\u2032-yl)benzoato]cadmium(II)], [Cd(C<jats:sub>22<\/jats:sub>H<jats:sub>14<\/jats:sub>N<jats:sub>3<\/jats:sub>O<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>]<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub> or [Cd(3-cptpy)<jats:sub>2<\/jats:sub>]<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub>, (I), has been synthesized solvothermally and characterized by IR spectroscopy, thermogravimetric analysis, and single-crystal and powder X-ray diffraction. The structure is composed of 3-cptpy<jats:sup>\u2212<\/jats:sup> ligands bridging Cd atoms, with each Cd atom coordinated by six ligands and each ligand coordinating to three Cd atoms. Each Cd atom is in a slightly distorted <jats:italic>trans<\/jats:italic>-N<jats:sub>2<\/jats:sub>O<jats:sub>4<\/jats:sub> octahedral environment, forming a two-dimensional layer structure with a (3,6)-connected topology. Layers are linked to each other by \u03c0\u2013\u03c0 stacking, resulting in a three-dimensional supramolecular framework. The strong luminescence and good thermal stability of (I) indicate that it can potentially be used as a luminescence sensor. The compound also shows a highly selective and sensitive response to 2,4,6-trinitrophenol through the luminescence quenching effect.<\/jats:p>","DOI":"10.1107\/s2053229619004248","type":"journal-article","created":{"date-parts":[[2019,4,8]],"date-time":"2019-04-08T15:32:37Z","timestamp":1554737557000},"page":"508-513","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":3,"title":["A 4\u2032-(4-carboxyphenyl)-3,2\u2032:6\u2032,3\u2032\u2032-terpyridine-based luminescent cadmium(II) coordination polymer for the detection of 2,4,6-trinitrophenol"],"prefix":"10.1107","volume":"75","author":[{"given":"Bin","family":"Xu","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fuming","family":"Luo","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guodong","family":"Tang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7944-332X","authenticated-orcid":true,"given":"Jinfang","family":"Zhang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2019,4,8]]},"reference":[{"key":"cu3138_bb1","doi-asserted-by":"crossref","first-page":"5499","DOI":"10.1021\/acs.cgd.7b01024","volume":"17","author":"Arici","year":"2017","journal-title":"Cryst. Growth Des."},{"key":"cu3138_bb2","unstructured":"Bruker (2012). APEX2 and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA."},{"key":"cu3138_bb3","doi-asserted-by":"crossref","first-page":"14556","DOI":"10.1021\/acs.inorgchem.7b02264","volume":"56","author":"Chakraborty","year":"2017","journal-title":"Inorg. Chem."},{"key":"cu3138_bb4","doi-asserted-by":"crossref","first-page":"3716","DOI":"10.1021\/cg400749m","volume":"13","author":"Chaudhari","year":"2013","journal-title":"Cryst. Growth Des."},{"key":"cu3138_bb5","doi-asserted-by":"crossref","first-page":"716","DOI":"10.1039\/C7DT04087C","volume":"47","author":"Chen","year":"2018","journal-title":"Dalton Trans."},{"key":"cu3138_bb6","doi-asserted-by":"crossref","first-page":"13476","DOI":"10.1021\/jacs.7b06459","volume":"139","author":"Chen","year":"2017","journal-title":"J. Am. Chem. Soc."},{"key":"cu3138_bb7","doi-asserted-by":"crossref","first-page":"2259","DOI":"10.1016\/j.ica.2007.11.032","volume":"361","author":"Cooke","year":"2008","journal-title":"Inorg. Chim. Acta"},{"key":"cu3138_bb8","doi-asserted-by":"crossref","first-page":"9954","DOI":"10.1039\/c3dt50532d","volume":"42","author":"Gai","year":"2013","journal-title":"Dalton Trans."},{"key":"cu3138_bb9","doi-asserted-by":"crossref","first-page":"6651","DOI":"10.1039\/C7CE01510K","volume":"19","author":"Gao","year":"2017","journal-title":"CrystEngComm"},{"key":"cu3138_bb10","doi-asserted-by":"crossref","first-page":"7314","DOI":"10.1021\/acs.inorgchem.8b00938","volume":"57","author":"He","year":"2018","journal-title":"Inorg. Chem."},{"key":"cu3138_bb11","doi-asserted-by":"crossref","first-page":"8382","DOI":"10.1021\/acs.inorgchem.8b01051","volume":"57","author":"Hu","year":"2018","journal-title":"Inorg. Chem."},{"key":"cu3138_bb12","doi-asserted-by":"crossref","first-page":"965","DOI":"10.1002\/chem.201405167","volume":"21","author":"Joarder","year":"2015","journal-title":"Chem. Eur. J."},{"key":"cu3138_bb13","doi-asserted-by":"crossref","first-page":"5797","DOI":"10.1039\/C7CE01176H","volume":"19","author":"Li","year":"2017","journal-title":"CrystEngComm"},{"key":"cu3138_bb14","doi-asserted-by":"crossref","first-page":"207","DOI":"10.1016\/j.poly.2012.10.005","volume":"49","author":"Li","year":"2013","journal-title":"Polyhedron"},{"key":"cu3138_bb15","doi-asserted-by":"crossref","first-page":"11710","DOI":"10.1021\/acs.inorgchem.7b01685","volume":"56","author":"Lu","year":"2017","journal-title":"Inorg. Chem."},{"key":"cu3138_bb16","doi-asserted-by":"crossref","first-page":"1133","DOI":"10.1107\/S205322961801269X","volume":"74","author":"Luo","year":"2018","journal-title":"Acta Cryst. C"},{"key":"cu3138_bb17","doi-asserted-by":"crossref","first-page":"2627","DOI":"10.1021\/acs.inorgchem.6b02810","volume":"56","author":"Parmar","year":"2017","journal-title":"Inorg. Chem."},{"key":"cu3138_bb18","doi-asserted-by":"crossref","first-page":"3128","DOI":"10.1021\/acs.cgd.7b00063","volume":"17","author":"Qiao","year":"2017","journal-title":"Cryst. Growth Des."},{"key":"cu3138_bb19","doi-asserted-by":"crossref","first-page":"3461","DOI":"10.1021\/jacs.8b00313","volume":"140","author":"Rieth","year":"2018","journal-title":"J. Am. Chem. Soc."},{"key":"cu3138_bb20","doi-asserted-by":"crossref","first-page":"16738","DOI":"10.1039\/C7DT02790G","volume":"46","author":"Sathish","year":"2017","journal-title":"Dalton Trans."},{"key":"cu3138_bb21","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","volume":"64","author":"Sheldrick","year":"2008","journal-title":"Acta Cryst. A"},{"key":"cu3138_bb22","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"cu3138_bb23","doi-asserted-by":"crossref","first-page":"515","DOI":"10.1016\/j.dyepig.2016.09.011","volume":"136","author":"Shen","year":"2017","journal-title":"Dyes Pigments"},{"key":"cu3138_bb24","doi-asserted-by":"crossref","first-page":"7009","DOI":"10.1039\/C7CE01453H","volume":"19","author":"Singh","year":"2017","journal-title":"CrystEngComm"},{"key":"cu3138_bb25","doi-asserted-by":"crossref","first-page":"920","DOI":"10.1107\/S0021889810022120","volume":"43","author":"Westrip","year":"2010","journal-title":"J. Appl. Cryst."},{"key":"cu3138_bb26","doi-asserted-by":"crossref","first-page":"6041","DOI":"10.1021\/acs.cgd.7b01155","volume":"17","author":"Wu","year":"2017","journal-title":"Cryst. Growth Des."},{"key":"cu3138_bb27","doi-asserted-by":"crossref","first-page":"13349","DOI":"10.1021\/jacs.7b05453","volume":"139","author":"Yan","year":"2017","journal-title":"J. Am. Chem. Soc."},{"key":"cu3138_bb28","doi-asserted-by":"crossref","first-page":"1460","DOI":"10.1039\/C3DT52500G","volume":"43","author":"Yang","year":"2014","journal-title":"Dalton Trans."},{"key":"cu3138_bb29","doi-asserted-by":"crossref","first-page":"8107","DOI":"10.1039\/C7NJ01072A","volume":"41","author":"Zhang","year":"2017","journal-title":"New J. Chem."},{"key":"cu3138_bb30","doi-asserted-by":"crossref","first-page":"1366","DOI":"10.1002\/zaac.201400595","volume":"641","author":"Zhang","year":"2015","journal-title":"Z. Anorg. Allg. Chem."},{"key":"cu3138_bb31","doi-asserted-by":"crossref","first-page":"7465","DOI":"10.1002\/slct.201701253","volume":"2","author":"Zhang","year":"2017","journal-title":"ChemistrySelect"},{"key":"cu3138_bb32","doi-asserted-by":"crossref","first-page":"166","DOI":"10.1016\/j.snb.2018.05.121","volume":"272","author":"Zhang","year":"2018","journal-title":"Sens. Actuators B"},{"key":"cu3138_bb33","doi-asserted-by":"crossref","first-page":"193","DOI":"10.1039\/C5CE01917F","volume":"18","author":"Zhang","year":"2016","journal-title":"CrystEngComm"},{"key":"cu3138_bb34","doi-asserted-by":"crossref","first-page":"193","DOI":"10.1039\/C5CE01917F","volume":"18","author":"Zhang","year":"2016","journal-title":"CrystEngComm"}],"container-title":["Acta Crystallographica Section C Structural Chemistry"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/c\/issues\/2019\/05\/00\/cu3138\/cu3138.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/c\/issues\/2019\/05\/00\/cu3138\/cu3138.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T10:25:59Z","timestamp":1736763959000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2053229619004248"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2019,4,8]]},"references-count":34,"journal-issue":{"issue":"5","published-online":{"date-parts":[[2019,5]]}},"alternative-id":["S2053229619004248"],"URL":"https:\/\/doi.org\/10.1107\/s2053229619004248","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2053229619004248\/cu3138sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2053229619004248\/cu3138Isup2.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2053229619004248\/cu3138sup3.pdf","asserted-by":"subject"}]},"ISSN":["2053-2296"],"issn-type":[{"value":"2053-2296","type":"electronic"}],"subject":[],"published":{"date-parts":[[2019,4,8]]},"assertion":[{"value":"Acta Crystallographica Section C: Structural Chemistry","order":0,"name":"journal","label":"Publication","explanation":{"URL":"http:\/\/journals.iucr.org\/c"},"group":{"name":"general","label":"General"}},{"value":"research papers","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/c\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"http:\/\/scripts.iucr.org\/cgi-bin\/citedin?cu3138","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"25 January 2019","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"28 March 2019","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"8 April 2019","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"http:\/\/scripts.iucr.org\/cgi-bin\/sendsup?cu3138"}},{"value":"\u00a9 2019 International Union of Crystallography","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licensing","label":"Copyright and licencing"}}]}}