{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,6]],"date-time":"2025-10-06T18:51:57Z","timestamp":1759776717742,"version":"3.33.0"},"reference-count":23,"publisher":"International Union of Crystallography (IUCr)","issue":"10","license":[{"start":{"date-parts":[[2019,9,27]],"date-time":"2019-09-27T00:00:00Z","timestamp":1569542400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2019,9,27]],"date-time":"2019-09-27T00:00:00Z","timestamp":1569542400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"funder":[{"DOI":"10.13039\/501100001659","name":"Deutsche Forschungsgemeinschaft","doi-asserted-by":"publisher","award":["HE2890\/7\u20131","HE2890\/7\u20132"],"award-info":[{"award-number":["HE2890\/7\u20131","HE2890\/7\u20132"]}],"id":[{"id":"10.13039\/501100001659","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"accepted":{"date-parts":[[2019,8,21]]},"published-print":{"date-parts":[[2019,10,1]]},"abstract":"<jats:p>The complexes {bis[(2-diphenylphosphanyl)phenyl] ether-\u03ba<jats:sup>2<\/jats:sup>\n                  <jats:italic>P<\/jats:italic>,<jats:italic>P<\/jats:italic>\u2032}(\u03b7<jats:sup>4<\/jats:sup>-norbornadiene)rhodium(I) tetrafluoridoborate, [Rh(C<jats:sub>7<\/jats:sub>H<jats:sub>8<\/jats:sub>)(C<jats:sub>36<\/jats:sub>H<jats:sub>28<\/jats:sub>OP<jats:sub>2<\/jats:sub>)]BF<jats:sub>4<\/jats:sub>, and {bis[(2-diphenylphosphanyl)phenyl] ether-\u03ba<jats:sup>2<\/jats:sup>\n                  <jats:italic>P<\/jats:italic>,<jats:italic>P<\/jats:italic>\u2032}[\u03b7<jats:sup>4<\/jats:sup>-(<jats:italic>Z<\/jats:italic>,<jats:italic>Z<\/jats:italic>)-cycloocta-1,5-diene]rhodium(I) tetrafluoridoborate dichloromethane monosolvate, [Rh(C<jats:sub>8<\/jats:sub>H<jats:sub>12<\/jats:sub>)(C<jats:sub>36<\/jats:sub>H<jats:sub>28<\/jats:sub>OP<jats:sub>2<\/jats:sub>)]BF<jats:sub>4<\/jats:sub>\u00b7CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>, are applied as precatalysts in redox-neutral atomic-economic propargylic CH activation [Lumbroso <jats:italic>et al.<\/jats:italic> (2013). <jats:italic>Angew. Chem. Int. Ed.<\/jats:italic> \n                  <jats:bold>52<\/jats:bold>, 1890\u20131932]. In addition, the catalytically inactive pentacoordinated 18-electron complex {bis[(2-diphenylphosphanyl)phenyl] ether-\u03ba<jats:sup>2<\/jats:sup>\n                  <jats:italic>P<\/jats:italic>,<jats:italic>P<\/jats:italic>\u2032}chlorido(\u03b7<jats:sup>4<\/jats:sup>-norbornadiene)rhodium(I), [RhCl(C<jats:sub>7<\/jats:sub>H<jats:sub>8<\/jats:sub>)(C<jats:sub>36<\/jats:sub>H<jats:sub>28<\/jats:sub>OP<jats:sub>2<\/jats:sub>)], was synthesized, which can form in the presence of chloride in the reaction system.<\/jats:p>","DOI":"10.1107\/s205322961901163x","type":"journal-article","created":{"date-parts":[[2019,9,27]],"date-time":"2019-09-27T12:40:59Z","timestamp":1569588059000},"page":"1434-1438","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":3,"title":["Two precatalysts for application in propargylic CH activation"],"prefix":"10.1107","volume":"75","author":[{"given":"Saskia","family":"M\u00f6ller","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hans-Joachim","family":"Drexler","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Detlef","family":"Heller","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2019,9,27]]},"reference":[{"key":"ov3130_bb1","unstructured":"Bruker (2013). 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