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The assembly of symmetric 2,5-bis(pyridin-3-yl)-1,3,4-oxadiazole (<jats:bold>L1<\/jats:bold>) and asymmetric<jats:bold>L5<\/jats:bold>with AgCO<jats:sub>2<\/jats:sub>CF<jats:sub>3<\/jats:sub>in solution yielded two novel Ag<jats:sup>I<\/jats:sup>complexes, namely<jats:italic>catena<\/jats:italic>-poly[[di-\u03bc-trifluoroacetato-disilver(I)]-bis[\u03bc-2,5-bis(pyridin-3-yl)-1,3,4-oxadiazole]], [Ag<jats:sub>2<\/jats:sub>(C<jats:sub>2<\/jats:sub>F<jats:sub>3<\/jats:sub>O<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>(C<jats:sub>12<\/jats:sub>H<jats:sub>8<\/jats:sub>N<jats:sub>4<\/jats:sub>O)<jats:sub>2<\/jats:sub>]<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>or [Ag<jats:sub>2<\/jats:sub>(\u03bc<jats:sub>2<\/jats:sub>-O<jats:sub>2<\/jats:sub>CCF<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>(<jats:bold>L1<\/jats:bold>)<jats:sub>2<\/jats:sub>]<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>(<jats:bold>1<\/jats:bold>), and bis(\u03bc<jats:sub>3<\/jats:sub>-5-{3-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]phenyl}-2-(pyridin-3-yl)-1,3,4-oxadiazole)tetra-\u03bc<jats:sub>3<\/jats:sub>-trifluoroacetato-tetrasilver(I) dichloromethane monosolvate, [Ag<jats:sub>4<\/jats:sub>(C<jats:sub>2<\/jats:sub>F<jats:sub>3<\/jats:sub>O<jats:sub>2<\/jats:sub>)<jats:sub>4<\/jats:sub>(C<jats:sub>22<\/jats:sub>H<jats:sub>15<\/jats:sub>N<jats:sub>5<\/jats:sub>O<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>]\u00b7CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>or [Ag<jats:sub>2<\/jats:sub>(\u03bc<jats:sub>3<\/jats:sub>-O<jats:sub>2<\/jats:sub>CCF<jats:sub>3<\/jats:sub>)<jats:sub>2<\/jats:sub>(<jats:bold>L5<\/jats:bold>)]<jats:sub>2<\/jats:sub>\u00b7CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>(<jats:bold>2<\/jats:bold>). Complex<jats:bold>1<\/jats:bold>displays a one-dimensional ring\u2013chain motif, where dinuclear Ag<jats:sub>2<\/jats:sub>(CF<jats:sub>3<\/jats:sub>CO<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>units alternate with Ag<jats:sub>2<\/jats:sub>(<jats:bold>L1<\/jats:bold>)<jats:sub>2<\/jats:sub>macrocycles. This structure is different from previously reported Ag\u2013<jats:bold>L1<\/jats:bold>complexes with different anions. Complex<jats:bold>2<\/jats:bold>features a tetranuclear supramolecular macrocycle, in which each ligand adopts a tridentate coordination mode with the oxadiazole ring next to the<jats:italic>p<\/jats:italic>-tolyl ring coordinated and that next to the pyridyl ring free. Two<jats:bold>L5<\/jats:bold>ligands are bound to two Ag1 centres through two oxadiazole N and two pyridyl N atoms to form a macrocycle. The other two oxadiazole N atoms coordinate to the two Ag2 centres of the Ag<jats:sub>2<\/jats:sub>(O<jats:sub>2<\/jats:sub>CCF<jats:sub>3<\/jats:sub>)<jats:sub>4<\/jats:sub>dimer. Each CF<jats:sub>3<\/jats:sub>CO<jats:sub>2<\/jats:sub><jats:sup>\u2212<\/jats:sup>anion adopts a \u03bc<jats:sub>3<\/jats:sub>-coordination mode, bridging the Ag1 and Ag2 centres to form a tetranuclear silver(I) complex. This study indicates that the donor ability of the bridging oxadiazole rings can be tuned by electron-withdrawing and -donating substituents. The emission properties of ligands<jats:bold>L1<\/jats:bold>and<jats:bold>L5<\/jats:bold>and complexes<jats:bold>1<\/jats:bold>and<jats:bold>2<\/jats:bold>were also investigated in the solid state.<\/jats:p>","DOI":"10.1107\/s2053229619011744","type":"journal-article","created":{"date-parts":[[2019,9,6]],"date-time":"2019-09-06T12:47:48Z","timestamp":1567774068000},"page":"1327-1335","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Syntheses and characterization of dinuclear and tetranuclear Ag<sup>I<\/sup>supramolecular complexes generated from symmetric and asymmetric molecular clips containing oxadiazole rings"],"prefix":"10.1107","volume":"75","author":[{"given":"Guoxia","family":"Jin","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yuqi","family":"Ji","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Teng","family":"Wang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yanyan","family":"Sun","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yulong","family":"Li","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Guiying","family":"Zhu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5300-3307","authenticated-orcid":true,"given":"Jianping","family":"Ma","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2019,9,6]]},"reference":[{"key":"yf3187_bb1","doi-asserted-by":"crossref","first-page":"7812","DOI":"10.1021\/acs.inorgchem.9b00454","volume":"58","author":"Chang","year":"2019","journal-title":"Inorg. 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