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In this context, luminescent MOFs as fluorescence sensors have recently received significant attention for the sensing of ionic species and small molecules. In this work, a new luminescent heterometallic zinc(II)\u2013barium(II)-based anionic metal\u2013organic framework, namely poly[imidazolium [triaqua(\u03bc<jats:sub>6<\/jats:sub>-benzene-1,3,5-tricarboxylato)bariumtrizinc] tetrahydrate], {(C<jats:sub>3<\/jats:sub>H<jats:sub>4<\/jats:sub>N<jats:sub>2<\/jats:sub>)[BaZn<jats:sub>3<\/jats:sub>(C<jats:sub>9<\/jats:sub>H<jats:sub>3<\/jats:sub>O<jats:sub>6<\/jats:sub>)<jats:sub>3<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>3<\/jats:sub>]\u00b74H<jats:sub>2<\/jats:sub>O}<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub> (<jats:bold>1<\/jats:bold>), was synthesized under hydrothermal conditions and characterized. Compound <jats:bold>1<\/jats:bold> presents a three-dimensional framework with an unprecedented (3,5)-connected topology of the point symbol (3.9<jats:sup>2<\/jats:sup>).(3<jats:sup>3<\/jats:sup>.4<jats:sup>2<\/jats:sup>.5.9<jats:sup>3<\/jats:sup>.10), and exhibits `turn-off' luminescence responses for the Cu<jats:sup>2+<\/jats:sup> and Fe<jats:sup>3+<\/jats:sup> ions in aqueous solution based on significantly different quenching mechanisms.<\/jats:p>","DOI":"10.1107\/s2053229619011987","type":"journal-article","created":{"date-parts":[[2019,9,6]],"date-time":"2019-09-06T12:47:48Z","timestamp":1567774068000},"page":"1372-1380","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":10,"title":["A new luminescent anionic metal\u2013organic framework based on heterometallic zinc(II)\u2013barium(II) for selective detection of Fe<sup>3+<\/sup> and Cu<sup>2+<\/sup> ions in aqueous solution"],"prefix":"10.1107","volume":"75","author":[{"given":"Natthakorn","family":"Phadungsak","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1785-3889","authenticated-orcid":true,"given":"Filip","family":"Kielar","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Winya","family":"Dungkaew","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mongkol","family":"Sukwattanasinitt","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yan","family":"Zhou","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1486-9164","authenticated-orcid":true,"given":"Kittipong","family":"Chainok","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2019,9,6]]},"reference":[{"key":"qp3030_bb1","doi-asserted-by":"crossref","first-page":"1330","DOI":"10.1039\/b802352m","volume":"38","author":"Allendorf","year":"2009","journal-title":"Chem. 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