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Commonly, multifunctional aromatic polycarboxylic acids and nitrogen-containing ligands are employed to construct MOFs with fascinating structures. 4,4\u2032,4\u2032\u2032-(1,3,5-Triazine-2,4,6-triyl)tribenzoic acid (H<jats:sub>3<\/jats:sub>TATB) and the bidentate nitrogen-containing ligand 1,3-bis[(imidazol-1-yl)methyl]benzene (bib) were selected to prepare a novel Zn<jats:sup>II<\/jats:sup>-MOF under solvothermal conditions, namely poly[[tris{\u03bc-1,3-bis[(imidazol-1-yl)methyl]benzene}bis[\u03bc<jats:sub>3<\/jats:sub>-4,4\u2032,4\u2032\u2032-(1,3,5-triazine-2,4,6-triyl)tribenzoato]trizinc(II)] dimethylformamide disolvate trihydrate], {[Zn<jats:sub>3<\/jats:sub>(C<jats:sub>24<\/jats:sub>H<jats:sub>12<\/jats:sub>N<jats:sub>3<\/jats:sub>O<jats:sub>6<\/jats:sub>)<jats:sub>2<\/jats:sub>(C<jats:sub>14<\/jats:sub>H<jats:sub>14<\/jats:sub>N<jats:sub>4<\/jats:sub>)<jats:sub>3<\/jats:sub>]\u00b72C<jats:sub>3<\/jats:sub>H<jats:sub>7<\/jats:sub>NO\u00b73H<jats:sub>2<\/jats:sub>O}<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub> (<jats:bold>1<\/jats:bold>). The structure of <jats:bold>1<\/jats:bold> was characterized by single-crystal X-ray diffraction, IR spectroscopy and powder X-ray diffraction. The properties of <jats:bold>1<\/jats:bold> were investigated by thermogravimetric and fluorescence analysis. Single-crystal X-ray diffraction shows that <jats:bold>1<\/jats:bold> belongs to the monoclinic space group <jats:italic>Pc<\/jats:italic>. The asymmetric unit contains three crystallographically independent Zn<jats:sup>II<\/jats:sup> centres, two 4,4\u2032,4\u2032\u2032-(1,3,5-triazine-2,4,6-triyl)tribenzoate (TATB<jats:sup>3\u2212<\/jats:sup>) anions, three complete bib ligands, one and a half free dimethylformamide molecules and three guest water molecules. Each Zn<jats:sup>II<\/jats:sup> centre is four-coordinated and displays a distorted tetrahedral coordination geometry. The Zn<jats:sup>II<\/jats:sup> centres are connected by TATB<jats:sup>3\u2212<\/jats:sup> anions to form an angled ladder chain with large windows. Simultaneously, the bib ligands link Zn<jats:sup>II<\/jats:sup> centres to give a helical Zn\u2013bib\u2013Zn chain. Furthermore, adjacent ladders are bridged by Zn\u2013bib\u2013Zn chains to form a fascinating three-dimensional self-penetrated framework with the short Schl\u00e4fli symbol 6<jats:sup>5<\/jats:sup>\u00b77\u00b78<jats:sup>13<\/jats:sup>\u00b79\u00b710. In addition, the luminescence properties of <jats:bold>1<\/jats:bold> in the solid state and the fluorescence sensing of metal ions in suspension were studied. Significantly, compound <jats:bold>1<\/jats:bold> shows potential application as a fluorescent sensor with sensing properties for Zr<jats:sup>4+<\/jats:sup> and Cu<jats:sup>2+<\/jats:sup> ions.<\/jats:p>","DOI":"10.1107\/s2053229619015547","type":"journal-article","created":{"date-parts":[[2019,12,6]],"date-time":"2019-12-06T12:41:20Z","timestamp":1575636080000},"page":"10-16","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["A self-penetrated three-dimensional zinc(II) coordination framework based on 4,4\u2032,4\u2032\u2032-(1,3,5-triazine-2,4,6-triyl)tribenzoic acid and 1,3-bis[(imidazol-1-yl)methyl]benzene ligands: synthesis, structure and properties"],"prefix":"10.1107","volume":"76","author":[{"given":"Saier","family":"Wang","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Rong","family":"Bi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jiadi","family":"Liu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ying","family":"Shi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Kuaibing","family":"Wang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Feifei","family":"Mao","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hua","family":"Wu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2020,1,1]]},"reference":[{"key":"qf3030_bb2","doi-asserted-by":"crossref","first-page":"5448","DOI":"10.1021\/acs.cgd.6b00912","volume":"16","author":"Ar\u0131c\u0131","year":"2016","journal-title":"Cryst. 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