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A new copper porphyrin, namely poly[[\u03bc-chlorido-[\u03bc<jats:sub>5<\/jats:sub>-5,10,15,20-tetrakis(pyridin-4-yl)-21<jats:italic>H<\/jats:italic>,23<jats:italic>H<\/jats:italic>-porphine]tricopper(I)] [aquadichloridocopper(II)]], {[Cu<jats:sub>3<\/jats:sub>(C<jats:sub>40<\/jats:sub>H<jats:sub>24<\/jats:sub>N<jats:sub>8<\/jats:sub>)Cl][CuCl<jats:sub>2<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)]}<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub> (<jats:bold>1<\/jats:bold>), was synthesized by the self-assembly of copper chloride with 5,10,15,20-tetrakis(pyridin-4-yl)-21<jats:italic>H<\/jats:italic>,23<jats:italic>H<\/jats:italic>-porphine under solvothermal conditions. The structure of this copper porphyrin was characterized by single-crystal X-ray crystallography and elemental analysis. The porphyrin macrocycle shows a distorted saddle geometry, with the four pyrrole rings slightly distorted in an alternating mode either upwards or downwards. The copper ions show three-coordinated triangular and four-coordinated square-planar geometries. Every copper\u2013porphyrin unit connects to 12 others <jats:italic>via<\/jats:italic> four \u03bc<jats:sub>4<\/jats:sub>-bridging Cu<jats:sub>2<\/jats:sub>Cl moieties to complete the three-dimensional framework of compound <jats:bold>1<\/jats:bold>, with isolated CuCl<jats:sub>2<\/jats:sub>(H<jats:sub>2<\/jats:sub>O) units located in the voids. This copper porphyrin displays a red photoluminescence. Electrochemical measurements showed that compound <jats:bold>1<\/jats:bold> has two redox waves (<jats:italic>E<\/jats:italic>\n                  <jats:sub>1\/2<\/jats:sub>\u00a0= \u2212160 and 91\u2005mV).<\/jats:p>","DOI":"10.1107\/s2053229619017273","type":"journal-article","created":{"date-parts":[[2020,1,16]],"date-time":"2020-01-16T11:49:19Z","timestamp":1579175359000},"page":"133-138","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":8,"title":["Structure and photophysical and electrochemical properties of a copper porphyrin complex with a three-dimensional framework"],"prefix":"10.1107","volume":"76","author":[{"given":"Wen-Tong","family":"Chen","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2020,1,16]]},"reference":[{"key":"zo3002_bb1","doi-asserted-by":"crossref","first-page":"12353","DOI":"10.1039\/C8DT02151A","volume":"47","author":"Anjali","year":"2018","journal-title":"Dalton Trans."},{"key":"zo3002_bb2","doi-asserted-by":"crossref","first-page":"3815","DOI":"10.1080\/00268976.2015.1067335","volume":"113","author":"Arkan","year":"2015","journal-title":"Mol. 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