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Both salts were characterized using single-crystal X-ray diffraction analysis and IR spectroscopy. Moreover, the NMR (<jats:sup>1<\/jats:sup>H and <jats:sup>13<\/jats:sup>C) spectra of <jats:bold>1<\/jats:bold> were obtained. Salts <jats:bold>1<\/jats:bold> and <jats:bold>2<\/jats:bold> have triclinic symmetry (space group <jats:italic>P<\/jats:italic>-1) and their supramolecular structures are stabilized by hydrogen bonding and offset \u03c0\u2013\u03c0 interactions. In hydrated salt <jats:bold>2<\/jats:bold>, the noncovalent interactions yield pseudo-nanotubes filled with chloride anions and water molecules, which were modelled in the refinement with substitutional and positional disorder.<\/jats:p>","DOI":"10.1107\/s2053229620002508","type":"journal-article","created":{"date-parts":[[2020,3,6]],"date-time":"2020-03-06T11:25:33Z","timestamp":1583493933000},"page":"322-327","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis and crystallographic studies of two new 1,3,5-triazines"],"prefix":"10.1107","volume":"76","author":[{"given":"Emmanuel Blas","family":"Patricio-Rangel","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Margarita","family":"Tlahuextl","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hugo","family":"Tlahuext","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Antonio Rafael","family":"Tapia-Benavides","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2020,3,5]]},"reference":[{"key":"sk3746_bb1","unstructured":"Agilent (2014). 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