{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,12]],"date-time":"2026-02-12T10:21:50Z","timestamp":1770891710401,"version":"3.50.1"},"reference-count":33,"publisher":"International Union of Crystallography (IUCr)","issue":"9","license":[{"start":{"date-parts":[[2020,8,28]],"date-time":"2020-08-28T00:00:00Z","timestamp":1598572800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2020,8,28]],"date-time":"2020-08-28T00:00:00Z","timestamp":1598572800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"funder":[{"DOI":"10.13039\/501100004396","name":"Thailand Research Fund","doi-asserted-by":"crossref","award":["BRG6180008"],"award-info":[{"award-number":["BRG6180008"]}],"id":[{"id":"10.13039\/501100004396","id-type":"DOI","asserted-by":"crossref"}]},{"name":"The National Science Technology and Innovation Policy Office for Integrated Research and Innovation Plan","award":["256113A3050001"],"award-info":[{"award-number":["256113A3050001"]}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"accepted":{"date-parts":[[2020,8,25]]},"published-print":{"date-parts":[[2020,9,1]]},"abstract":"<jats:p>Two conformational polymorphs of (<jats:italic>N<\/jats:italic>,<jats:italic>N<\/jats:italic>-dibutyldithiocarbamato-\u03ba<jats:sup>2<\/jats:sup>\n                  <jats:italic>S<\/jats:italic>,<jats:italic>S<\/jats:italic>\u2032)[tris(3,5-diphenylpyrazol-1-yl-\u03ba<jats:italic>N<\/jats:italic>\n                  <jats:sup>2<\/jats:sup>)hydroborato]cobalt(II), [Co(C<jats:sub>45<\/jats:sub>H<jats:sub>34<\/jats:sub>BN<jats:sub>6<\/jats:sub>)(C<jats:sub>9<\/jats:sub>H<jats:sub>18<\/jats:sub>NS<jats:sub>2<\/jats:sub>)] or [Tp<jats:sup>Ph2<\/jats:sup>Co(S<jats:sub>2<\/jats:sub>CNBu<jats:sub>2<\/jats:sub>)], <jats:bold>1<\/jats:bold>, are accessible by recrystallization from dichloromethane\u2013methanol to give orthorhombic polymorph <jats:bold>1a<\/jats:bold>, while slow evaporation from acetonitrile produces triclinic polymorph <jats:bold>1b<\/jats:bold>. The two polymorphs have been characterized by IR spectroscopy and single-crystal X-ray crystallography at 150\u2005K. Polymorphs <jats:bold>1a<\/jats:bold> and <jats:bold>1b<\/jats:bold> crystallize in the orthorhombic space group <jats:italic>Pbca<\/jats:italic> and the triclinic space group <jats:italic>P<\/jats:italic>-1, respectively. The polymorphs have a <jats:italic>trans<\/jats:italic> (<jats:bold>1a<\/jats:bold>) and <jats:italic>cis<\/jats:italic> (<jats:bold>1b<\/jats:bold>) orientation of the butyl groups with respect to the S<jats:sub>2<\/jats:sub>CN plane of the dithiocarbamate ligand, which results in an intermediate five-coordinate geometry for <jats:bold>1a<\/jats:bold> and a square-pyramidal geometry for <jats:bold>1b<\/jats:bold>. Hirshfeld surface analysis reveals minor differences between the two polymorphs, with <jats:bold>1a<\/jats:bold> exhibiting stronger C\u2014H...S interactions and <jats:bold>1b<\/jats:bold> favouring C\u2014H...\u03c0 interactions.<\/jats:p>","DOI":"10.1107\/s205322962001164x","type":"journal-article","created":{"date-parts":[[2020,8,28]],"date-time":"2020-08-28T09:26:55Z","timestamp":1598606815000},"page":"921-926","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Conformational polymorphism in a cobalt(II) dithiocarbamate complex"],"prefix":"10.1107","volume":"76","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8033-8818","authenticated-orcid":true,"given":"Jetnipat","family":"Songkerdthong","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Phimphaka","family":"Harding","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8866-2401","authenticated-orcid":true,"given":"David J.","family":"Harding","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2020,8,28]]},"reference":[{"key":"yp3208_bb1","doi-asserted-by":"crossref","first-page":"1349","DOI":"10.1039\/DT9840001349","author":"Addison","year":"1984","journal-title":"J. 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