{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T08:48:26Z","timestamp":1736844506081,"version":"3.33.0"},"reference-count":41,"publisher":"International Union of Crystallography (IUCr)","issue":"1","license":[{"start":{"date-parts":[[2021,1,1]],"date-time":"2021-01-01T00:00:00Z","timestamp":1609459200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2021,1,1]],"date-time":"2021-01-01T00:00:00Z","timestamp":1609459200000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["21802090"],"award-info":[{"award-number":["21802090"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100007129","name":"Natural Science Foundation of Shandong Province","doi-asserted-by":"publisher","award":["ZR2018BB006"],"award-info":[{"award-number":["ZR2018BB006"]}],"id":[{"id":"10.13039\/501100007129","id-type":"DOI","asserted-by":"publisher"}]},{"name":"the Project of the Shandong Province Higher Educational Science and Technology Program","award":["J18KA066 and J18KA092"],"award-info":[{"award-number":["J18KA066 and J18KA092"]}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"accepted":{"date-parts":[[2020,12,10]]},"published-print":{"date-parts":[[2021,1,1]]},"abstract":"<jats:p>Semirigid organic ligands can adopt different conformations to construct coordination polymers with more diverse structures when compared to those constructed from rigid ligands. A new asymmetric semirigid organic ligand, 4-{2-[(pyridin-3-yl)methyl]-2<jats:italic>H<\/jats:italic>-tetrazol-5-yl}pyridine (<jats:bold>L<\/jats:bold>), has been prepared and used to synthesize three bimetallic macrocyclic complexes and one coordination polymer, namely, bis(\u03bc-4-{2-[(pyridin-3-yl)methyl]-2<jats:italic>H<\/jats:italic>-tetrazol-5-yl}pyridine)bis[dichloridozinc(II)] dichloromethane disolvate, [Zn<jats:sub>2<\/jats:sub>Cl<jats:sub>4<\/jats:sub>(C<jats:sub>12<\/jats:sub>H<jats:sub>10<\/jats:sub>N<jats:sub>6<\/jats:sub>)<jats:sub>2<\/jats:sub>]\u00b72CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>, (<jats:bold>I<\/jats:bold>), the analogous chloroform monosolvate, [Zn<jats:sub>2<\/jats:sub>Cl<jats:sub>4<\/jats:sub>(C<jats:sub>12<\/jats:sub>H<jats:sub>10<\/jats:sub>N<jats:sub>6<\/jats:sub>)<jats:sub>2<\/jats:sub>]\u00b7CHCl<jats:sub>3<\/jats:sub>, (<jats:bold>II<\/jats:bold>), bis(\u03bc-4-{2-[(pyridin-3-yl)methyl]-2<jats:italic>H<\/jats:italic>-tetrazol-5-yl}pyridine)bis[diiodidozinc(II)] dichloromethane disolvate, [Zn<jats:sub>2<\/jats:sub>I<jats:sub>4<\/jats:sub>(C<jats:sub>12<\/jats:sub>H<jats:sub>10<\/jats:sub>N<jats:sub>6<\/jats:sub>)<jats:sub>2<\/jats:sub>]\u00b72CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>, (<jats:bold>III<\/jats:bold>), and <jats:italic>catena<\/jats:italic>-poly[[[diiodidozinc(II)]-\u03bc-4-{2-[(pyridin-3-yl)methyl]-2<jats:italic>H<\/jats:italic>-tetrazol-5-yl}pyridine] chloroform monosolvate], {[ZnI<jats:sub>2<\/jats:sub>(C<jats:sub>12<\/jats:sub>H<jats:sub>10<\/jats:sub>N<jats:sub>6<\/jats:sub>)]\u00b7CHCl<jats:sub>3<\/jats:sub>}<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub>, (<jats:bold>IV<\/jats:bold>), by solution reaction with Zn<jats:italic>X<\/jats:italic>\n                  <jats:sub>2<\/jats:sub> (<jats:italic>X<\/jats:italic> = Cl and I) in a CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>\/CH<jats:sub>3<\/jats:sub>OH or CHCl<jats:sub>3<\/jats:sub>\/CH<jats:sub>3<\/jats:sub>OH mixed solvent system at room temperature. Complex (<jats:bold>I<\/jats:bold>) is isomorphic with complex (<jats:bold>III<\/jats:bold>) and has a bimetallic ring possessing similar coordination environments for both of the Zn<jats:sup>II<\/jats:sup> cations. Although complex (<jats:bold>II<\/jats:bold>) also contains a bimetallic ring, the two Zn<jats:sup>II<\/jats:sup> cations have different coordination environments. Under the influence of the I<jats:sup>\u2212<\/jats:sup> anion and guest CHCl<jats:sub>3<\/jats:sub> molecule, complex (<jats:bold>IV<\/jats:bold>) displays a significantly different structure with respect to complexes (<jats:bold>I<\/jats:bold>)\u2013(<jats:bold>III<\/jats:bold>). C\u2014H...Cl and C\u2014H...N hydrogen bonds, and \u03c0\u2013\u03c0 stacking or C\u2014Cl...\u03c0 interactions exist in complexes (<jats:bold>I<\/jats:bold>)\u2013(<jats:bold>IV<\/jats:bold>), and these weak interactions play an important role in the three-dimensional structures of (<jats:bold>I<\/jats:bold>)\u2013(<jats:bold>IV<\/jats:bold>) in the solid state. In addition, the fluorescence properties of <jats:bold>L<\/jats:bold> and complexes (<jats:bold>I<\/jats:bold>)\u2013(<jats:bold>IV<\/jats:bold>) were investigated.<\/jats:p>","DOI":"10.1107\/s2053229620016083","type":"journal-article","created":{"date-parts":[[2020,12,16]],"date-time":"2020-12-16T10:58:27Z","timestamp":1608116307000},"page":"29-39","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Syntheses and structures of three macrocyclic supramolecular complexes and one Zn<sup>II<\/sup>-containing coordination polymer generated from a semi-rigid multidentate N-containing ligand"],"prefix":"10.1107","volume":"77","author":[{"given":"Xiang-Long","family":"Niu","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8308-2395","authenticated-orcid":true,"given":"Lin","family":"Wei","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jian-Cheng","family":"Liu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Wan-He","family":"Jia","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5300-3307","authenticated-orcid":true,"given":"Jian-Ping","family":"Ma","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Lei","family":"Wang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jian-Cheng","family":"Wang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yu-Bin","family":"Dong","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2021,1,1]]},"reference":[{"key":"op3008_bb1","doi-asserted-by":"crossref","first-page":"5292","DOI":"10.1021\/acs.cgd.9b00734","volume":"19","author":"Benaissa","year":"2019","journal-title":"Cryst. Growth Des."},{"key":"op3008_bb2","unstructured":"Bruker (2012). APEX2, SMART, SAINT, SADABS, XPREP and SHELXTL. Bruker AXS Inc., Madison, Wisconsin, USA."},{"key":"op3008_bb3","doi-asserted-by":"crossref","first-page":"7812","DOI":"10.1021\/acs.inorgchem.9b00454","volume":"58","author":"Chang","year":"2019","journal-title":"Inorg. Chem."},{"key":"op3008_bb4","doi-asserted-by":"crossref","first-page":"504","DOI":"10.1107\/S2053229619004303","volume":"75","author":"Chen","year":"2019","journal-title":"Acta Cryst. C"},{"key":"op3008_bb5","doi-asserted-by":"crossref","first-page":"4322","DOI":"10.1021\/cm501657d","volume":"26","author":"Chen","year":"2014","journal-title":"Chem. Mater."},{"key":"op3008_bb6","doi-asserted-by":"crossref","first-page":"1126","DOI":"10.1021\/cr200101d","volume":"112","author":"Cui","year":"2012","journal-title":"Chem. Rev."},{"key":"op3008_bb7","doi-asserted-by":"crossref","first-page":"339","DOI":"10.1107\/S0021889808042726","volume":"42","author":"Dolomanov","year":"2009","journal-title":"J. Appl. Cryst."},{"key":"op3008_bb8","doi-asserted-by":"crossref","first-page":"3371","DOI":"10.1039\/D0CE00025F","volume":"22","author":"Hao","year":"2020","journal-title":"CrystEngComm"},{"key":"op3008_bb9","doi-asserted-by":"crossref","first-page":"2033","DOI":"10.1021\/acs.cgd.5b00229","volume":"15","author":"He","year":"2015","journal-title":"Cryst. Growth Des."},{"key":"op3008_bb10","doi-asserted-by":"crossref","first-page":"1108","DOI":"10.1107\/S0108270113022105","volume":"69","author":"Hou","year":"2013","journal-title":"Acta Cryst. C"},{"key":"op3008_bb11","doi-asserted-by":"crossref","first-page":"107540","DOI":"10.1016\/j.inoche.2019.107540","volume":"108","author":"Huang","year":"2019","journal-title":"Inorg. Chem. Commun."},{"key":"op3008_bb12","doi-asserted-by":"crossref","first-page":"8130","DOI":"10.1021\/acs.chemrev.9b00828","volume":"120","author":"Islamoglu","year":"2020","journal-title":"Chem. Rev."},{"key":"op3008_bb13","doi-asserted-by":"crossref","first-page":"2110","DOI":"10.1039\/c2cc16691g","volume":"48","author":"Jones","year":"2012","journal-title":"Chem. Commun."},{"key":"op3008_bb14","doi-asserted-by":"crossref","first-page":"4404","DOI":"10.1021\/acs.cgd.9b00202","volume":"19","author":"Li","year":"2019","journal-title":"Cryst. Growth Des."},{"key":"op3008_bb15","doi-asserted-by":"crossref","first-page":"5867","DOI":"10.1039\/C3CS60483G","volume":"43","author":"Lin","year":"2014","journal-title":"Chem. Soc. Rev."},{"key":"op3008_bb16","doi-asserted-by":"crossref","first-page":"2671","DOI":"10.1021\/acsenergylett.0c01148","volume":"5","author":"Liu","year":"2020","journal-title":"ACS Energy Lett."},{"key":"op3008_bb17","doi-asserted-by":"crossref","first-page":"5561","DOI":"10.1039\/C4CS00003J","volume":"43","author":"Lu","year":"2014","journal-title":"Chem. Soc. Rev."},{"key":"op3008_bb18","doi-asserted-by":"crossref","first-page":"2312","DOI":"10.1021\/cg301815w","volume":"13","author":"Luo","year":"2013","journal-title":"Cryst. Growth Des."},{"key":"op3008_bb19","doi-asserted-by":"crossref","first-page":"7223","DOI":"10.1021\/jacs.9b00733","volume":"141","author":"Pascanu","year":"2019","journal-title":"J. Am. Chem. Soc."},{"key":"op3008_bb20","unstructured":"Rigaku OD (2015). CrysAlis PRO. Rigaku Oxford Diffraction Ltd, Yarnton, Oxfordshire, England."},{"key":"op3008_bb21","doi-asserted-by":"crossref","first-page":"295","DOI":"10.1016\/j.arabjc.2016.01.003","volume":"12","author":"Seetharaj","year":"2019","journal-title":"Arab. J. Chem."},{"key":"op3008_bb22","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","volume":"64","author":"Sheldrick","year":"2008","journal-title":"Acta Cryst. A"},{"key":"op3008_bb23","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. A"},{"key":"op3008_bb24","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"op3008_bb25","doi-asserted-by":"crossref","first-page":"433","DOI":"10.1107\/S2053229619003115","volume":"75","author":"Vr\u00e1blov\u00e1","year":"2019","journal-title":"Acta Cryst. C"},{"key":"op3008_bb26","doi-asserted-by":"crossref","first-page":"10791","DOI":"10.1021\/ic5013186","volume":"53","author":"Wang","year":"2014","journal-title":"Inorg. Chem."},{"key":"op3008_bb27","doi-asserted-by":"crossref","first-page":"11502","DOI":"10.1021\/acscatal.9b03971","volume":"9","author":"Wang","year":"2019","journal-title":"ACS Catal."},{"key":"op3008_bb28","doi-asserted-by":"crossref","first-page":"8269","DOI":"10.1021\/ja5006866","volume":"136","author":"Wei","year":"2014","journal-title":"J. Am. Chem. Soc."},{"key":"op3008_bb29","doi-asserted-by":"crossref","first-page":"683","DOI":"10.1107\/S2053229615012929","volume":"71","author":"Wu","year":"2015","journal-title":"Acta Cryst. C"},{"key":"op3008_bb30","doi-asserted-by":"crossref","first-page":"285","DOI":"10.1107\/S205322961600348X","volume":"72","author":"Wu","year":"2016","journal-title":"Acta Cryst. C"},{"key":"op3008_bb31","doi-asserted-by":"crossref","first-page":"453","DOI":"10.1016\/j.jssc.2017.11.007","volume":"258","author":"Xu","year":"2018","journal-title":"J. Solid State Chem."},{"key":"op3008_bb32","doi-asserted-by":"crossref","first-page":"14938","DOI":"10.1039\/C9CC07045A","volume":"55","author":"Xu","year":"2019","journal-title":"Chem. Commun."},{"key":"op3008_bb33","doi-asserted-by":"crossref","first-page":"8047","DOI":"10.1039\/C4CE01032A","volume":"16","author":"Yang","year":"2014","journal-title":"CrystEngComm"},{"key":"op3008_bb34","doi-asserted-by":"crossref","first-page":"m176","DOI":"10.1107\/S0108270111016246","volume":"67","author":"Yang","year":"2011","journal-title":"Acta Cryst. C"},{"key":"op3008_bb35","doi-asserted-by":"crossref","first-page":"3578","DOI":"10.1021\/acs.inorgchem.8b03316","volume":"58","author":"Yao","year":"2019","journal-title":"Inorg. Chem."},{"key":"op3008_bb36","doi-asserted-by":"crossref","first-page":"5822","DOI":"10.1039\/C8CE01261J","volume":"20","author":"Yao","year":"2018","journal-title":"CrystEngComm"},{"key":"op3008_bb37","doi-asserted-by":"crossref","first-page":"7935","DOI":"10.1021\/acscatal.6b02228","volume":"6","author":"Zeng","year":"2016","journal-title":"ACS Catal."},{"key":"op3008_bb38","doi-asserted-by":"crossref","first-page":"10747","DOI":"10.1021\/ic902591s","volume":"49","author":"Zhang","year":"2010","journal-title":"Inorg. Chem."},{"key":"op3008_bb39","doi-asserted-by":"crossref","first-page":"93","DOI":"10.1016\/j.poly.2016.02.004","volume":"110","author":"Zhang","year":"2016","journal-title":"Polyhedron"},{"key":"op3008_bb40","doi-asserted-by":"crossref","first-page":"m324","DOI":"10.1107\/S0108270111032811","volume":"67","author":"Zhang","year":"2011","journal-title":"Acta Cryst. C"},{"key":"op3008_bb41","doi-asserted-by":"crossref","first-page":"1202","DOI":"10.1039\/C7DT03761A","volume":"47","author":"Zhang","year":"2018","journal-title":"Dalton Trans."}],"container-title":["Acta Crystallographica Section C Structural Chemistry"],"original-title":[],"link":[{"URL":"https:\/\/journals.iucr.org\/c\/issues\/2021\/01\/00\/op3008\/op3008.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/journals.iucr.org\/c\/issues\/2021\/01\/00\/op3008\/op3008.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T10:27:32Z","timestamp":1736764052000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2053229620016083"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2021,1,1]]},"references-count":41,"journal-issue":{"issue":"1","published-online":{"date-parts":[[2021,1]]}},"alternative-id":["S2053229620016083"],"URL":"https:\/\/doi.org\/10.1107\/s2053229620016083","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2053229620016083\/op3008sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2053229620016083\/op3008Lsup2.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2053229620016083\/op3008Isup3.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2053229620016083\/op3008IIsup4.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2053229620016083\/op3008IIIsup5.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2053229620016083\/op3008IVsup6.hkl","asserted-by":"subject"}]},"ISSN":["2053-2296"],"issn-type":[{"type":"electronic","value":"2053-2296"}],"subject":[],"published":{"date-parts":[[2021,1,1]]},"assertion":[{"value":"Acta Crystallographica Section C: Structural Chemistry","order":0,"name":"journal","label":"Publication","explanation":{"URL":"https:\/\/journals.iucr.org\/c"},"group":{"name":"general","label":"General"}},{"value":"research papers","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/c\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"https:\/\/scripts.iucr.org\/cgi-bin\/citedin?op3008","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"21 October 2020","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"10 December 2020","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"1 January 2021","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?op3008"}},{"value":"\u00a9 2021 International Union of Crystallography","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licensing","label":"Copyright and licencing"}}]}}