{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,11,9]],"date-time":"2025-11-09T07:48:28Z","timestamp":1762674508892,"version":"3.33.0"},"reference-count":33,"publisher":"International Union of Crystallography (IUCr)","issue":"11","license":[{"start":{"date-parts":[[2021,10,27]],"date-time":"2021-10-27T00:00:00Z","timestamp":1635292800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2021,10,27]],"date-time":"2021-10-27T00:00:00Z","timestamp":1635292800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"funder":[{"DOI":"10.13039\/501100001843","name":"Science and Engineering Research Board","doi-asserted-by":"publisher","award":["CRG\/2019\/000040"],"award-info":[{"award-number":["CRG\/2019\/000040"]}],"id":[{"id":"10.13039\/501100001843","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100006952","name":"Louisiana Board of Regents","doi-asserted-by":"publisher","award":["LEQSF(2002-03)-ENH-TR-67"],"award-info":[{"award-number":["LEQSF(2002-03)-ENH-TR-67"]}],"id":[{"id":"10.13039\/100006952","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"accepted":{"date-parts":[[2021,10,15]]},"published-print":{"date-parts":[[2021,11,1]]},"abstract":"<jats:p>The novel hemilabile ferrocenylbisphosphane 1,1\u2032-bis(bis{2-[(dimethylamino)methyl]phenyl}phosphanyl)ferrocene, [Fe{C<jats:sub>5<\/jats:sub>H<jats:sub>4<\/jats:sub>P(C<jats:sub>6<\/jats:sub>H<jats:sub>4<\/jats:sub>CH<jats:sub>2<\/jats:sub>NMe<jats:sub>2<\/jats:sub>-<jats:italic>o<\/jats:italic>)<jats:sub>2<\/jats:sub>}<jats:sub>2<\/jats:sub>] (<jats:bold>1<\/jats:bold>), was synthesized by reacting bis(dichlorophosphanyl)ferrocene, [Fe{C<jats:sub>5<\/jats:sub>H<jats:sub>4<\/jats:sub>(PCl<jats:sub>2<\/jats:sub>)}<jats:sub>2<\/jats:sub>] with LiC<jats:sub>6<\/jats:sub>H<jats:sub>4<\/jats:sub>CH<jats:sub>2<\/jats:sub>NMe<jats:sub>2<\/jats:sub>-<jats:italic>o<\/jats:italic>. Treatment of <jats:bold>1<\/jats:bold> with gray selenium and anhydrous ZnCl<jats:sub>2<\/jats:sub> yielded, respectively, the bisselenide (ferrocene-1,1\u2032-diyl)bis(bis{2-[(dimethylamino)methyl]phenyl}phosphine selenide), [Fe(C<jats:sub>23<\/jats:sub>H<jats:sub>28<\/jats:sub>N<jats:sub>2<\/jats:sub>PSe)<jats:sub>2<\/jats:sub>] (<jats:bold>2<\/jats:bold>), and the dizinc complex [\u03bc-1,1\u2032-bis(bis{2-[(dimethylamino)methyl]phenyl}phosphanyl)ferrocene-\u03ba<jats:sup>2<\/jats:sup>\n                  <jats:italic>N<\/jats:italic>,<jats:italic>P<\/jats:italic>:\u03ba<jats:sup>2<\/jats:sup>\n                  <jats:italic>N<\/jats:italic>\u2032,<jats:italic>P<\/jats:italic>\u2032]bis[dichloridozinc(II)] dichloromethane monosolvate, [FeZn<jats:sub>2<\/jats:sub>Cl<jats:sub>4<\/jats:sub>(C<jats:sub>23<\/jats:sub>H<jats:sub>28<\/jats:sub>N<jats:sub>2<\/jats:sub>P)<jats:sub>2<\/jats:sub>]\u00b7CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub> (<jats:bold>3<\/jats:bold>), and both have been structurally characterized. Both compounds crystallized with the asymmetric unit containing half a molecule and with the Fe atom on an inversion centre. A Hirshfeld surface analysis indicated that the most significant contributions to the crystal packing of <jats:bold>2<\/jats:bold> are from H...H (76.7%), C...H\/H...C (13.2%) and Se...H\/H...Se (7.1%) contacts, while those for <jats:bold>3<\/jats:bold> are from H...H (62.3%), Cl...H\/H...Cl (24.4%) and C...H\/H...C (10.9%) contacts.<\/jats:p>","DOI":"10.1107\/s205322962101072x","type":"journal-article","created":{"date-parts":[[2021,10,27]],"date-time":"2021-10-27T15:16:50Z","timestamp":1635347810000},"page":"725-733","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":3,"title":["Synthesis, structural, characterization and Hirshfeld analysis of a bisselenide and a zinc complex of a new hemilabile ferrocenylbisphosphane, [Fe{C<sub>5<\/sub>H<sub>4<\/sub>P(C<sub>6<\/sub>H<sub>4<\/sub>CH<sub>2<\/sub>NMe<sub>2<\/sub>-<i>o<\/i>)<sub>2<\/sub>}<sub>2<\/sub>]"],"prefix":"10.1107","volume":"77","author":[{"given":"Harish S.","family":"Kunchur","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Dipanjan","family":"Mondal","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sowmya","family":"Rao","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3488-1945","authenticated-orcid":true,"given":"Joel T.","family":"Mague","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Maravanji S.","family":"Balakrishna","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2021,10,27]]},"reference":[{"key":"zo3012_bb1","doi-asserted-by":"crossref","first-page":"150","DOI":"10.1016\/j.ccr.2017.08.004","volume":"355","author":"Adams","year":"2018","journal-title":"Coord. 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