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In complex<jats:bold>3<\/jats:bold>, the thio-ligand coordinates in a neutral form to the Cu atom through its S-donor atom, and in complex<jats:bold>4<\/jats:bold>, the anionic thio-ligand chelates to the Ni atom through N- and S-donor atoms. The geometry of complex<jats:bold>3<\/jats:bold>is distorted tetrahedral [bond angles 99.70\u2005(5)\u2013123.23\u2005(5)\u00b0], with the P\u2014Cu\u2014P bond angle being the largest, while that of complex<jats:bold>4<\/jats:bold>is square planar, with<jats:italic>trans<\/jats:italic>-S\u2014Ni\u2014S and N\u2014Ni\u2014N bond angles of 180\u00b0.<\/jats:p>","DOI":"10.1107\/s205322962101319x","type":"journal-article","created":{"date-parts":[[2021,12,20]],"date-time":"2021-12-20T12:54:04Z","timestamp":1640004844000},"page":"30-35","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structures of 3\/4-pyridyl-based thiosemicarbazones and related Cu and Ni coordination compounds"],"prefix":"10.1107","volume":"78","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-5658-6317","authenticated-orcid":true,"given":"Tarlok Singh","family":"Lobana","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mani","family":"Kaushal","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Robin","family":"Bhatia","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ritu","family":"Bala","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2770-7076","authenticated-orcid":true,"given":"Ray J.","family":"Butcher","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jerry P.","family":"Jasinksi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2022,1,1]]},"reference":[{"key":"yd3022_bb1","doi-asserted-by":"crossref","first-page":"4967","DOI":"10.1021\/ja01154a501","volume":"73","author":"Anderson","year":"1951","journal-title":"J. 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