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In this work, the Cadogan ring-closure reaction between the benzene moiety of thieno[3,2-<jats:italic>b<\/jats:italic>]indole and 5,6-dinitrobenzo[<jats:italic>c<\/jats:italic>][1,2,5]thiadiazole was employed to prepare the novel decacyclic <jats:italic>S<\/jats:italic>,<jats:italic>N<\/jats:italic>-heteroacene 15,16-dibutyl-14,17-didodecyldithieno[2\u2032\u2032,3\u2032\u2032:2\u2032,3\u2032]indolo[6\u2032,7\u2032:4,5]pyrrolo[3,2-<jats:italic>e<\/jats:italic>:2\u2032,3\u2032-<jats:italic>g<\/jats:italic>][2,1,3]benzothiadiazole (<jats:bold>TIP<\/jats:bold>), C<jats:sub>58<\/jats:sub>H<jats:sub>76<\/jats:sub>N<jats:sub>6<\/jats:sub>S<jats:sub>3<\/jats:sub>. The conjugated backbone of <jats:bold>TIP<\/jats:bold> is extended in comparison with its octacyclic analogue as the central unit within Y6-type molecular acceptors, a family of overwhelming electron acceptors in polymer solar-cell research. The single-crystal X-ray diffraction (SC-XRD) characterization indicated the existence of \u03c0\u2013\u03c0 and C(<jats:italic>sp<\/jats:italic>\n                  <jats:sup>2<\/jats:sup>)\u2014H...\u03c0 interactions among <jats:bold>TIP<\/jats:bold> molecules. The electrochemical and optical properties of <jats:bold>TIP<\/jats:bold> were also characterized. As a novel <jats:italic>S<\/jats:italic>,<jats:italic>N<\/jats:italic>-heteroacene building block, <jats:bold>TIP<\/jats:bold> is anticipated to be of potential use in the construction of promising electronic materials.<\/jats:p>","DOI":"10.1107\/s2053229622003291","type":"journal-article","created":{"date-parts":[[2022,3,28]],"date-time":"2022-03-28T16:18:27Z","timestamp":1648484307000},"page":"250-256","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis and properties of a novel decacyclic <i>S<\/i>,<i>N<\/i>-heteroacene"],"prefix":"10.1107","volume":"78","author":[{"given":"Gongchun","family":"Li","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Wei","family":"Wang","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Chun","family":"Zhan","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Shengqiang","family":"Xiao","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2022,3,28]]},"reference":[{"key":"yp3223_bb1","doi-asserted-by":"crossref","first-page":"4450","DOI":"10.1021\/ol901806q","volume":"11","author":"Balaji","year":"2009","journal-title":"Org. 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