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In the crystal structures, various transition metals of <jats:italic>d<\/jats:italic>-elements occupy symmetrically independent crystallographic positions with different coordination geometries. In the crystal structure of Na<jats:sub>2<\/jats:sub>NiCu(PO<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>, NiO<jats:sub>6<\/jats:sub> and CuO<jats:sub>6<\/jats:sub> octahedra share edges to form chains that PO<jats:sub>4<\/jats:sub> groups link into a framework with cavities filled with Na atoms. Layered cationic fragments formed from dimers of MnO<jats:sub>5<\/jats:sub> trigonal bipyramids and CuO<jats:sub>4<\/jats:sub> square planes, sharing vertices, are connected through PO<jats:sub>4<\/jats:sub> tetrahedra into a 3-periodic Mn<jats:sub>2<\/jats:sub>Cu(PO<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub> crystal structure. Structural correlations between Na<jats:sub>2<\/jats:sub>NiCu(PO<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub> and NaCuPO<jats:sub>4<\/jats:sub> are discussed, and crystal\u2013chemical details of the currently known exclusively synthetic mixed Mn\/Cu and Ni\/Cu phosphates are presented.<\/jats:p>","DOI":"10.1107\/s2053229622003692","type":"journal-article","created":{"date-parts":[[2022,4,11]],"date-time":"2022-04-11T13:14:46Z","timestamp":1649682886000},"page":"287-294","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Novel first-row transition-metal phosphates: hydrothermal synthesis and crystal structures"],"prefix":"10.1107","volume":"78","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4311-0130","authenticated-orcid":true,"given":"Galina V.","family":"Kiriukhina","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7495-8460","authenticated-orcid":true,"given":"Olga V.","family":"Yakubovich","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Polina A.","family":"Verchenko","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Anatoly S.","family":"Volkov","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Olga V.","family":"Dimitrova","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2022,4,11]]},"reference":[{"key":"ov3158_bb1","doi-asserted-by":"crossref","first-page":"1349","DOI":"10.1039\/DT9840001349","author":"Addison","year":"1984","journal-title":"J. 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