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The X-ray crystallographic measurements revealed that the silver(I) compounds exhibit one-dimensional sinusoidal or helical molecular structures depending on the solvent used for crystallization. Self-assembly in a methanol\/chloroform mixture produces the sinusoidal molecular strand, whereas recrystallization from acetonitrile medium affords a racemic mixture of the helical strands. These compounds display a fluorescence emission arising from both the ligand-centred transition and the ligand-to-metal charge transfer (LMCT) in the solid state under ambient conditions.<\/jats:p>","DOI":"10.1107\/s2053229622004818","type":"journal-article","created":{"date-parts":[[2022,5,19]],"date-time":"2022-05-19T13:10:16Z","timestamp":1652965816000},"page":"360-365","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Solvent media as the driving force in the formation of one-dimensional silver(I) coordination polymers with 2-methylidene-1,3-bis(nicotinoyloxy)propane"],"prefix":"10.1107","volume":"78","author":[{"given":"Seong Min","family":"Jo","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Tae Hwan","family":"Noh","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2022,5,19]]},"reference":[{"key":"jx3070_bb1","unstructured":"Bruker (2013). 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