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The coordination geometry of the macrocycle is dependent on the stereoisomerism of CTMC. The packing of these complexes appears to be strongly influenced by extensive hydrogen-bonding interactions, which are in turn determined by the nature of the counter-anions (<jats:bold>1a<\/jats:bold><jats:italic>versus<\/jats:italic><jats:bold>1b<\/jats:bold>) and\/or the coordination geometry of the macrocycle (<jats:bold>1a\/1b<\/jats:bold><jats:italic>versus<\/jats:italic><jats:bold>2<\/jats:bold>). These observations are extended to related ferric<jats:italic>cis<\/jats:italic>- and<jats:italic>trans-<\/jats:italic>dichloro macrocyclic complexes.<\/jats:p>","DOI":"10.1107\/s205322962200849x","type":"journal-article","created":{"date-parts":[[2022,8,30]],"date-time":"2022-08-30T09:57:00Z","timestamp":1661853420000},"page":"507-514","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Geometric isomers of dichloridoiron(III) complexes of CTMC (5,7,12,14-tetramethyl-1,4,8,11-tetraazacyclotetradecane)"],"prefix":"10.1107","volume":"78","author":[{"given":"Stephanie S.","family":"DeLancey","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Reese A.","family":"Clendening","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3305-852X","authenticated-orcid":true,"given":"Matthias","family":"Zeller","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Tong","family":"Ren","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2022,8,30]]},"reference":[{"key":"lf3128_bb1","doi-asserted-by":"crossref","first-page":"5648","DOI":"10.1063\/1.464913","volume":"98","author":"Becke","year":"1993","journal-title":"J. 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