{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,2,21]],"date-time":"2025-02-21T21:21:40Z","timestamp":1740172900850,"version":"3.37.3"},"reference-count":40,"publisher":"International Union of Crystallography (IUCr)","issue":"11","license":[{"start":{"date-parts":[[2022,10,7]],"date-time":"2022-10-07T00:00:00Z","timestamp":1665100800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2022,10,7]],"date-time":"2022-10-07T00:00:00Z","timestamp":1665100800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"funder":[{"DOI":"10.13039\/501100001809","name":"Natural Science Foundation of China","doi-asserted-by":"crossref","award":["21671124"],"award-info":[{"award-number":["21671124"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"crossref"}]},{"name":"Taiyuan University","award":["21TYKQ20"],"award-info":[{"award-number":["21TYKQ20"]}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"accepted":{"date-parts":[[2022,9,26]]},"published-print":{"date-parts":[[2022,11,1]]},"abstract":"<jats:p>A new luminescent Cd<jats:sup>II<\/jats:sup> compound, poly[[\u03bc<jats:sub>2<\/jats:sub>-1,4-bis(1<jats:italic>H<\/jats:italic>-imidazol-1-yl)benzene]{\u03bc<jats:sub>2<\/jats:sub>-5-[(3-carboxylphenoxy)methyl]isophthalato}cadmium(II)], [Cd(C<jats:sub>16<\/jats:sub>H<jats:sub>10<\/jats:sub>O<jats:sub>7<\/jats:sub>)(C<jats:sub>12<\/jats:sub>H<jats:sub>10<\/jats:sub>N<jats:sub>4<\/jats:sub>)]<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub> or [Cd(H<jats:italic>L<\/jats:italic>)(1,4-bib)]<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub> {H<jats:sub>3<\/jats:sub>\n                  <jats:italic>L<\/jats:italic> is 5-[(3-carboxyphenoxy)methyl]isophthalic acid and 1,4-bib is 1,4-bis(1<jats:italic>H<\/jats:italic>-imidazol-1-yl)benzene}, <jats:bold>I<\/jats:bold>, has been synthesized successfully from Cd<jats:sup>II<\/jats:sup> and a semirigid tricarboxylic ligand under hydrothermal conditions. Structure analysis shows that <jats:bold>I<\/jats:bold> is a two-dimensional structure with the point symbol {4<jats:sup>4<\/jats:sup>.6<jats:sup>2<\/jats:sup>}. The three-dimensional framework is constructed by O\u2014H...O hydrogen bonds and \u03c0\u2013\u03c0 stacking interactions. Furthermore, the obtained Cd<jats:sup>II<\/jats:sup> compound displays high solvent stability and excellent thermal stability, as shown by powder X-ray diffraction and thermogravimetry measurements. Studies of the luminescence properties reveal that compound <jats:bold>I<\/jats:bold> can act as a promising luminescent sensor for detecting Fe<jats:sup>III<\/jats:sup> cations and Cr<jats:sup>VI<\/jats:sup> oxyanions with high selectivity and low detection limits (0.19\u2005\u00b5<jats:italic>M<\/jats:italic> for Fe<jats:sup>3+<\/jats:sup> and 1.13\u2005\u00b5<jats:italic>M<\/jats:italic> for Cr<jats:sub>2<\/jats:sub>O<jats:sub>7<\/jats:sub>\n                  <jats:sup>2\u2212<\/jats:sup>), and is additionally free from the interference of other ions. The mechanism of selective quenching was studied by measuring the UV\u2013Vis absorption of the host compound and the target analytes.<\/jats:p>","DOI":"10.1107\/s2053229622009445","type":"journal-article","created":{"date-parts":[[2022,10,7]],"date-time":"2022-10-07T12:17:29Z","timestamp":1665145049000},"page":"612-620","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Cd<sup>II<\/sup>-based compound as a multi-responsive fluorescent probe for sensing Fe<sup>III<\/sup> cations and Cr<sup>VI<\/sup> oxyanions"],"prefix":"10.1107","volume":"78","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0070-5417","authenticated-orcid":true,"given":"Yan-Yan","family":"An","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Li-Jun","family":"Su","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xin","family":"Zhao","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Juan-Zhi","family":"Yan","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2022,10,7]]},"reference":[{"key":"ef3033_bb1","doi-asserted-by":"crossref","first-page":"15788","DOI":"10.1039\/C4CC06225F","volume":"50","author":"Acharyya","year":"2014","journal-title":"Chem. 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