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The title heteroleptic cuprous polymer solvate,\n                    <jats:italic>catena<\/jats:italic>\n                    -poly[[[(9,9-dimethyl-9\n                    <jats:italic>H<\/jats:italic>\n                    -xanthene-4,5-diyl)bis(diphenylphosphane)-\u03ba\n                    <jats:sup>2<\/jats:sup>\n                    <jats:italic>P<\/jats:italic>\n                    ,\n                    <jats:italic>P<\/jats:italic>\n                    \u2032](\u03bc-pyridine-3-carbonitrile-\u03ba\n                    <jats:sup>2<\/jats:sup>\n                    <jats:italic>N<\/jats:italic>\n                    <jats:sup>1<\/jats:sup>\n                    :\n                    <jats:italic>N<\/jats:italic>\n                    <jats:sup>3<\/jats:sup>\n                    )copper(I)] hexafluorophosphate dichloromethane trisolvate], {[Cu(C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    )(C\n                    <jats:sub>39<\/jats:sub>\n                    H\n                    <jats:sub>32<\/jats:sub>\n                    OP\n                    <jats:sub>2<\/jats:sub>\n                    )]PF\n                    <jats:sub>6<\/jats:sub>\n                    \u00b73CH\n                    <jats:sub>2<\/jats:sub>\n                    Cl\n                    <jats:sub>2<\/jats:sub>\n                    }\n                    <jats:sub>\n                      <jats:italic>n<\/jats:italic>\n                    <\/jats:sub>\n                    , conventionally abbreviated as {[Cu(3-PyCN)(Xantphos)]PF\n                    <jats:sub>6<\/jats:sub>\n                    \u00b73CH\n                    <jats:sub>2<\/jats:sub>\n                    Cl\n                    <jats:sub>2<\/jats:sub>\n                    }\n                    <jats:sub>\n                      <jats:italic>n<\/jats:italic>\n                    <\/jats:sub>\n                    , where Xantphos and 3-PyCN represent (9,9-dimethyl-9\n                    <jats:italic>H<\/jats:italic>\n                    -xanthene-4,5-diyl)bis(diphenylphosphane) and pyridine-3-carbonitrile, respectively, has been described. In this polymer solvate, the asymmetric unit consists of three dichloromethane solvent molecules, a hexafluorophosphate anion and a polymeric heteroleptic cuprous complex cation, in which the cuprous centre is in a CuP\n                    <jats:sub>2<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    tetrahedral coordination and is coordinated by two P atoms from the Xantphos ligand and two N atoms from two 3-PyCN ligands (the pyridyl and cyano N atoms). It is through the connection of the \u03bc\n                    <jats:sub>2<\/jats:sub>\n                    -bridging 3-PyCN ligand that these cuprous centres are linked into a one-dimensional helical chain structure. The chains are further assembled through C\u2014H...\u03c0 interactions to form a supramolecular metal\u2013organic framework containing solvent-accessible channels. The UV\u2013Vis absorption and photoluminescence properties of this heteroleptic cuprous polymer have been studied on as-synthesized samples. Its luminescence emission should mainly originate from the metal-to-ligand charge transfer excited state.\n                  <\/jats:p>","DOI":"10.1107\/s2053229622009809","type":"journal-article","created":{"date-parts":[[2022,10,28]],"date-time":"2022-10-28T08:22:18Z","timestamp":1666945338000},"page":"685-692","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["A new heteroleptic cuprous polymer constructed by a cyanopyridine ligand exhibiting a supramolecular framework structure and luminescence"],"prefix":"10.1107","volume":"78","author":[{"given":"Yu-Jie","family":"Kong","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jian-Teng","family":"Wang","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/030d08e08","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Li","family":"Song","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2022,10,28]]},"reference":[{"key":"ov3163_bb1","unstructured":"Agilent (2011). 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