{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T16:18:46Z","timestamp":1785428326137,"version":"3.56.0"},"reference-count":22,"publisher":"International Union of Crystallography (IUCr)","issue":"11","license":[{"start":{"date-parts":[[2022,10,27]],"date-time":"2022-10-27T00:00:00Z","timestamp":1666828800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2022,10,27]],"date-time":"2022-10-27T00:00:00Z","timestamp":1666828800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"funder":[{"name":"NSF-MRI","award":["CHE 1827313"],"award-info":[{"award-number":["CHE 1827313"]}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"accepted":{"date-parts":[[2022,10,12]]},"published-print":{"date-parts":[[2022,11,1]]},"abstract":"<jats:p>\n                    The title compound, alternatively called (4-bromophenyl)dihydrido(triphenylphosphanyl)boron, C\n                    <jats:sub>24<\/jats:sub>\n                    H\n                    <jats:sub>21<\/jats:sub>\n                    BBrP, crystallizes in the space group\n                    <jats:italic>P<\/jats:italic>\n                    \\overline{1} with one symmetry-independent molecule in the asymmetric unit. The B and P atoms both adopt the expected tetrahedral geometry. A possible intramolecular B\u2014H\n                    <jats:sup>\u03b4\u2212<\/jats:sup>\n                    ...\n                    <jats:sup>\u03b4+<\/jats:sup>\n                    H\u2014C dihydrogen bond exists between an arene group on phosphorus and the borane center. In the solid state, the title molecule is connected to its neighbors by intermolecular C\u2014H...\u03c0 interactions, with the arene rings on the P atom acting as hydrogen-bond donors and the arene ring of the borane acting as the acceptor. Hirshfeld analysis supports the existence of these interactions, as well as weak Br...Br interactions between neighboring molecules.\n                  <\/jats:p>","DOI":"10.1107\/s2053229622010002","type":"journal-article","created":{"date-parts":[[2022,10,28]],"date-time":"2022-10-28T08:22:18Z","timestamp":1666945338000},"page":"681-684","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis, crystal structure and Hirshfeld analysis of triphenylphosphine\u2013(4-bromophenyl)borane"],"prefix":"10.1107","volume":"78","author":[{"given":"Caleb J.","family":"Allen","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/002g57a93","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alex M.","family":"Olden","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/002g57a93","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"James L.","family":"Yates","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/002g57a93","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6752-7542","authenticated-orcid":true,"given":"Kraig A.","family":"Wheeler","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04j9d0s43","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eric R.","family":"Abbey","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/002g57a93","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2022,10,27]]},"reference":[{"key":"zo3028_bb1","doi-asserted-by":"crossref","first-page":"189","DOI":"10.1016\/S1472-7862(02)00030-8","volume":"1","author":"Barbour","year":"2001","journal-title":"J. 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