{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T10:11:37Z","timestamp":1736849497991,"version":"3.33.0"},"reference-count":45,"publisher":"International Union of Crystallography (IUCr)","issue":"4","license":[{"start":{"date-parts":[[2023,3,9]],"date-time":"2023-03-09T00:00:00Z","timestamp":1678320000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2023,3,9]],"date-time":"2023-03-09T00:00:00Z","timestamp":1678320000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"DOI":"10.13039\/501100004350","name":"Studienstiftung des Deutschen Volkes","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100004350","id-type":"DOI","asserted-by":"publisher"}]},{"name":"One Hundred-Talent Program of Shanxi Province"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"accepted":{"date-parts":[[2023,2,28]]},"published-print":{"date-parts":[[2023,4,1]]},"abstract":"<jats:p>The ditopic ligand 10-[4-(pyridin-4-yl)phenyl]-9-phospha-10-silatriptycene (TRIP-Py, C<jats:sub>29<\/jats:sub>H<jats:sub>20<\/jats:sub>NPSi) binds as a pyridine donor to Ni<jats:sup>II<\/jats:sup> and as a phosphatriptycene donor towards Pt<jats:sup>II<\/jats:sup>. The selectivity relies entirely on the Pearson character of the donor sites and the matching hardness of the respective metal cations. The product is the one-dimensional coordination polymer <jats:italic>catena<\/jats:italic>-poly[[[dichloridonickel(II)]-bis{\u03bc-10-[4-(pyridin-4-yl)phenyl]-9-phospha-10-silatriptycene}-bis[dichloridoplatinum(II)]-bis{\u03bc-10-[4-(pyridin-4-yl)phenyl]-9-phospha-10-silatriptycene}] dichloromethane pentasolvate ethanol icosasolvate], {[NiPt<jats:sub>2<\/jats:sub>Cl<jats:sub>6<\/jats:sub>(TRIP-Py)<jats:sub>4<\/jats:sub>]\u00b75CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>\u00b720EtOH}<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub> (<jats:bold>1<\/jats:bold>), which retains large pores due to the inherent rigidity of the ligand. This is enabled by the caged triptycene scaffold which fixes the direction of the phosphorus donor with respect to the remaining molecule and especially the pyridyl moiety. In its crystal structure, which was determined from synchrotron data, the pores of the polymer are filled with dichloromethane and ethanol molecules. Finding a suitable model for the pore content is complicated as it is too disordered to give a reasonable atomic model but too ordered to be described by an electron gas solvent mask. This article presents an in-depth description of this polymer, as well as a discussion on the use of the bypass algorithm for solvent masks.<\/jats:p>","DOI":"10.1107\/s2053229623001845","type":"journal-article","created":{"date-parts":[[2023,3,5]],"date-time":"2023-03-05T21:03:56Z","timestamp":1678050236000},"page":"118-124","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["The heterometallic one-dimensional solvated coordination polymer [NiPt<sub>2<\/sub>Cl<sub>6<\/sub>(TRIP-Py)<sub>4<\/sub>]<sub>\n                     <i>n<\/i>\n                  <\/sub>"],"prefix":"10.1107","volume":"79","author":[{"given":"Hans","family":"Gildenast","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Lukas","family":"Gruszien","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2623-0061","authenticated-orcid":true,"given":"Ulli","family":"Englert","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2023,3,9]]},"reference":[{"key":"ef3041_bb2","doi-asserted-by":"crossref","first-page":"1028","DOI":"10.1246\/cl.2004.1028","volume":"33","author":"Agou","year":"2004","journal-title":"Chem. 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