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The structure is maximally disordered since all the sites are occupied by statistical mixtures of atoms. The Tb\/Nd mixture of atoms occupies the 6<jats:italic>c<\/jats:italic> site (site symmetry 3<jats:italic>m<\/jats:italic>). The statistical mixtures Ni\/Zn consisting of more Ni atoms are located in the 6<jats:italic>c<\/jats:italic> and 9<jats:italic>d<\/jats:italic> (symmetry .2\/<jats:italic>m<\/jats:italic>) sites. In the following 18<jats:italic>f<\/jats:italic> (site symmetry .2) and 18<jats:italic>h<\/jats:italic> (site symmetry <jats:italic>.m<\/jats:italic>) sites are located Zn\/Ni statistical mixtures which consist of more Zn atoms. Zn\/Ni atoms form three-dimensional networks with hexagonal channels that fill statistical mixtures of Tb\/Nd and Ni\/Zn. The Tb<jats:sub>2\u2013<jats:italic>x<\/jats:italic>\n                  <\/jats:sub>Nd<jats:sub>\n                     <jats:italic>x<\/jats:italic>\n                  <\/jats:sub>Zn<jats:sub>17\u2013<jats:italic>y<\/jats:italic>\n                  <\/jats:sub>Ni<jats:sub>\n                     <jats:italic>y<\/jats:italic>\n                  <\/jats:sub> compound belongs to the family of intermetallic phases capable of absorbing hydrogen. In the structure, there are three types of voids, namely, 9<jats:italic>e<\/jats:italic> (site symmetry .2\/<jats:italic>m<\/jats:italic>), 3<jats:italic>b<\/jats:italic> (site symmetry \\overline{3}<jats:italic>m<\/jats:italic>) and 36<jats:italic>i<\/jats:italic> (site symmetry 1), in which hydrogen can be inserted, and the maximum total absorption capacity can reach 1.21\u2005wt% H<jats:sub>2<\/jats:sub>. Electrochemical hydrogenation shows that the phase absorbs 1.03% of H<jats:sub>2<\/jats:sub>, which indicates partial filling of the voids with H atoms.<\/jats:p>","DOI":"10.1107\/s2053229623004369","type":"journal-article","created":{"date-parts":[[2023,5,23]],"date-time":"2023-05-23T07:22:29Z","timestamp":1684826549000},"page":"257-262","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Tb<sub>2\u2013<i>x<\/i>\n                  <\/sub>Nd<sub>\n                     <i>x<\/i>\n                  <\/sub>Zn<sub>17\u2013<i>y<\/i>\n                  <\/sub>Ni<sub>\n                     <i>y<\/i>\n                  <\/sub> (<i>x<\/i>\u00a0= 0.5, <i>y<\/i>\u00a0= 4.83): a new intermetallic with a maximum disordered structure and its hydrogen storage properties"],"prefix":"10.1107","volume":"79","author":[{"given":"Vitalii","family":"Nytka","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Vasyl","family":"Kordan","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5166-5633","authenticated-orcid":true,"given":"Andrij","family":"Stetskiv","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1893-2706","authenticated-orcid":true,"given":"Volodymyr","family":"Pavlyuk","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2023,5,24]]},"reference":[{"key":"yp3229_bb1","doi-asserted-by":"crossref","unstructured":"Besenhard, J. 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