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These are dichloridobis(3,5-dimethyl-1\n                    <jats:italic>H<\/jats:italic>\n                    -pyrazole-\u03ba\n                    <jats:italic>N<\/jats:italic>\n                    <jats:sup>1<\/jats:sup>\n                    )cobalt\/zinc(0.2\/0.8), [Co\n                    <jats:sub>0.20<\/jats:sub>\n                    Zn\n                    <jats:sub>0.80<\/jats:sub>\n                    Cl\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>5<\/jats:sub>\n                    H\n                    <jats:sub>8<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    ] or [Co\n                    <jats:sub>0.2<\/jats:sub>\n                    Zn\n                    <jats:sub>0.8<\/jats:sub>\n                    Cl\n                    <jats:sub>2<\/jats:sub>\n                    (3,5-dmp)\n                    <jats:sub>2<\/jats:sub>\n                    ] (\n                    <jats:bold>1<\/jats:bold>\n                    ), and bis(\u03bc-3,5-dimethyl-1\n                    <jats:italic>H<\/jats:italic>\n                    -pyrazole)-\u03ba\n                    <jats:sup>2<\/jats:sup>\n                    <jats:italic>N<\/jats:italic>\n                    <jats:sup>1<\/jats:sup>\n                    :\n                    <jats:italic>N<\/jats:italic>\n                    <jats:sup>2<\/jats:sup>\n                    ;\u03ba\n                    <jats:sup>2<\/jats:sup>\n                    <jats:italic>N<\/jats:italic>\n                    <jats:sup>2<\/jats:sup>\n                    :\n                    <jats:italic>N<\/jats:italic>\n                    <jats:sup>1<\/jats:sup>\n                    -bis[bromido\/chlorido(0.7\/0.3)bis(3,5-dimethyl-1\n                    <jats:italic>H<\/jats:italic>\n                    -pyrazole-\u03ba\n                    <jats:italic>N<\/jats:italic>\n                    <jats:sup>1<\/jats:sup>\n                    )cobalt\/zinc(0.1\/0.9)], [Co\n                    <jats:sub>0.20<\/jats:sub>\n                    Zn\n                    <jats:sub>1.80<\/jats:sub>\n                    Br\n                    <jats:sub>1.40<\/jats:sub>\n                    Cl\n                    <jats:sub>0.60<\/jats:sub>\n                    (C\n                    <jats:sub>5<\/jats:sub>\n                    H\n                    <jats:sub>7<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    (C\n                    <jats:sub>5<\/jats:sub>\n                    H\n                    <jats:sub>8<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    )\n                    <jats:sub>2<\/jats:sub>\n                    ] or [Co\n                    <jats:sub>0.1<\/jats:sub>\n                    Zn\n                    <jats:sub>0.9<\/jats:sub>\n                    Br\n                    <jats:sub>0.7<\/jats:sub>\n                    Cl\n                    <jats:sub>0.3<\/jats:sub>\n                    (\u03bc-3,5-dmp)(3,5-dmp)]\n                    <jats:sub>2<\/jats:sub>\n                    (\n                    <jats:bold>2<\/jats:bold>\n                    ). The isolated complexes contain 3,5-dimethylpyrazole (3,5-dmp) ligands formed\n                    <jats:italic>in situ<\/jats:italic>\n                    from the decomposition of 1-hydroxymethyl-3,5-dimethylpyrazole. In both isolated complexes, some positional disorder is observed at the metal ions and halogen ligands. The molecular crystals of\n                    <jats:bold>1<\/jats:bold>\n                    and\n                    <jats:bold>2<\/jats:bold>\n                    are centrosymmetric, with the space groups\n                    <jats:italic>C<\/jats:italic>\n                    2\/\n                    <jats:italic>c<\/jats:italic>\n                    and\n                    <jats:italic>P<\/jats:italic>\n                    -1, respectively. Additionally, in the dinuclear complex, the pyrazole ring has a bridging coordination function with respect to the metal ions. Both complexes have good biological activities against cancer cells. The results of an\n                    <jats:italic>in vitro<\/jats:italic>\n                    cytotoxicity study indicated that compounds\n                    <jats:bold>1<\/jats:bold>\n                    and\n                    <jats:bold>2<\/jats:bold>\n                    showed significant cytotoxicity for cancer cell lines, including hepatic (HepG2 cells), lung (A549 cells) and colon cancer cells (SW\u2005480 and SW\u2005620). Based on the calculated IC\n                    <jats:sub>50<\/jats:sub>\n                    values against human cancer cell lines, it was found that both complexes demonstrated potent antiproliferative activity combined with great selectivity towards cancer cells. Complex\n                    <jats:bold>2<\/jats:bold>\n                    was a more effective cytotoxic agent which, at the same time, exhibited high cytocompatibility. The obtained data are very encouraging and could be useful for anticancer drug discovery.\n                  <\/jats:p>","DOI":"10.1107\/s2053229623010021","type":"journal-article","created":{"date-parts":[[2023,11,23]],"date-time":"2023-11-23T12:02:02Z","timestamp":1700740922000},"page":"520-529","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":3,"title":["An efficient one-pot synthesis of pyrazole complexes formed\n                    <i>in situ<\/i>\n                    : synthesis, crystal structure, Hirshfeld surface analysis and\n                    <i>in vitro<\/i>\n                    biological properties"],"prefix":"10.1107","volume":"79","author":[{"given":"Anna","family":"Adach","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/00krbh354","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7945-1039","authenticated-orcid":true,"given":"Ma\u0142gorzata","family":"Tyszka-Czochara","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/03bqmcz70","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1619-6146","authenticated-orcid":true,"given":"Marek","family":"Daszkiewicz","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/01dr6c206","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2023,11,30]]},"reference":[{"key":"dg3048_bb1","doi-asserted-by":"crossref","first-page":"757","DOI":"10.1080\/00958972.2017.1278572","volume":"70","author":"Adach","year":"2017","journal-title":"J. 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