{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,31]],"date-time":"2026-07-31T17:59:32Z","timestamp":1785520772275,"version":"3.56.0"},"reference-count":21,"publisher":"International Union of Crystallography (IUCr)","issue":"12","license":[{"start":{"date-parts":[[2024,11,20]],"date-time":"2024-11-20T00:00:00Z","timestamp":1732060800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2024,11,20]],"date-time":"2024-11-20T00:00:00Z","timestamp":1732060800000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"accepted":{"date-parts":[[2024,11,4]]},"published-print":{"date-parts":[[2024,12,1]]},"abstract":"<jats:p>A new crystalline compound, <jats:italic>catena<\/jats:italic>-poly[hexa-\u03bc-acetato-(acetic acid)-\u03bc<jats:sub>3<\/jats:sub>-oxido-<jats:italic>triangulo<\/jats:italic>-triiron(III)]-\u03bc-acetato], [Fe<jats:sub>3<\/jats:sub>(C<jats:sub>2<\/jats:sub>H<jats:sub>3<\/jats:sub>O<jats:sub>2<\/jats:sub>)<jats:sub>7<\/jats:sub>O(C<jats:sub>2<\/jats:sub>H<jats:sub>4<\/jats:sub>O<jats:sub>2<\/jats:sub>)]<jats:sub>\n                     <jats:italic>n<\/jats:italic>\n                  <\/jats:sub>, incorporating the basic ferric acetate unit, has been obtained from an acetic anhydride solution of hydrated iron(III) nitrate. The crystals have the composition Fe<jats:sub>3<\/jats:sub>O(OAc)<jats:sub>7<\/jats:sub>(HOAc) (HOAc is acetic acid) and include the well-known [Fe<jats:sub>3<\/jats:sub>O(OAc)<jats:sub>6<\/jats:sub>]<jats:sup>+<\/jats:sup> unit, in which the Fe<jats:sup>III<\/jats:sup> centres are linked to a central coplanar \u03bc<jats:sub>3<\/jats:sub>-oxido ligand. Acetate ions provide bridges between pairs of Fe<jats:sup>III<\/jats:sup> centres. These individual [Fe<jats:sub>3<\/jats:sub>O(OAc)<jats:sub>6<\/jats:sub>]<jats:sup>+<\/jats:sup> units are linked by additional bridging acetate anions to form zigzag chains. The bridging acetate ions coordinate to a position <jats:italic>trans<\/jats:italic> to the oxido group on two of the Fe<jats:sup>III<\/jats:sup> centres. Remarkably, the <jats:italic>trans<\/jats:italic> site on the third Fe<jats:sup>III<\/jats:sup> centre is occupied by the carbonyl group of an acetic acid molecule. This is the first reported case of an acetic acid molecule coordinating to an Fe<jats:sup>III<\/jats:sup> centre. Not surprisingly, the acetic acid molecule is only weakly coordinating, resulting in a short Fe\u2014O(oxido) bond <jats:italic>trans<\/jats:italic> to the carbonyl group. The <jats:italic>trans<\/jats:italic> influence apparent in this structure provides an interesting contrast with the structurally similar Mn<jats:sup>III<\/jats:sup> analogue, in which the corresponding pair of <jats:italic>trans<\/jats:italic> bonds are both elongated because of the Jahn\u2013Teller effect.<\/jats:p>","DOI":"10.1107\/s2053229624010672","type":"journal-article","created":{"date-parts":[[2024,11,20]],"date-time":"2024-11-20T13:26:49Z","timestamp":1732109209000},"page":"787-791","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["A polymeric form of basic iron(III) acetate with an acetic acid ligand"],"prefix":"10.1107","volume":"80","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-2957-860X","authenticated-orcid":true,"given":"Brendan F.","family":"Abrahams","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Richard","family":"Robson","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8319-4765","authenticated-orcid":true,"given":"Christopher J.","family":"Commons","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2024,11,20]]},"reference":[{"key":"jx3089_bb1","doi-asserted-by":"crossref","first-page":"5320","DOI":"10.1039\/D2TA08934C","volume":"11","author":"Ab\u00e1nades L\u00e1zaro","year":"2023","journal-title":"J. Mater. Chem. A"},{"key":"jx3089_bb2","doi-asserted-by":"crossref","first-page":"1265","DOI":"10.1021\/ic960960f","volume":"36","author":"Anson","year":"1987","journal-title":"Inorg. Chem."},{"key":"jx3089_bb3","doi-asserted-by":"crossref","first-page":"120292","DOI":"10.1016\/j.ica.2021.120292","volume":"520","author":"Bali\u0107","year":"2021","journal-title":"Inorg. Chim. Acta"},{"key":"jx3089_bb4","doi-asserted-by":"crossref","unstructured":"Cotton, F. A., Murillo, C. A. & Walton, R. A. (2005). In Multiple Bonds Between Metal Atoms. Boston, MA: Springer.","DOI":"10.1007\/b136230"},{"key":"jx3089_bb5","doi-asserted-by":"crossref","first-page":"339","DOI":"10.1107\/S0021889808042726","volume":"42","author":"Dolomanov","year":"2009","journal-title":"J. Appl. Cryst."},{"key":"jx3089_bb6","doi-asserted-by":"crossref","first-page":"694","DOI":"10.1038\/205694a0","volume":"205","author":"Figgis","year":"1965","journal-title":"Nature"},{"key":"jx3089_bb7","doi-asserted-by":"crossref","first-page":"171","DOI":"10.1107\/S2052520616003954","volume":"72","author":"Groom","year":"2016","journal-title":"Acta Cryst. B"},{"key":"jx3089_bb8","doi-asserted-by":"crossref","first-page":"545","DOI":"10.1002\/recl.19690880505","volume":"88","author":"Hessel","year":"1969","journal-title":"Recl Trav. Chim. Pays Bas"},{"key":"jx3089_bb9","doi-asserted-by":"crossref","first-page":"921","DOI":"10.1021\/ja01082a046","volume":"87","author":"Lawton","year":"1965","journal-title":"J. Am. Chem. Soc."},{"key":"jx3089_bb10","unstructured":"Nieger, M. (2016). CSD Communication (refcode GIZSEO01). CCDC, Cambridge, England."},{"key":"jx3089_bb11","doi-asserted-by":"crossref","first-page":"227","DOI":"10.1107\/S0365110X53000715","volume":"6","author":"Niekerk","year":"1953","journal-title":"Acta Cryst."},{"key":"jx3089_bb12","doi-asserted-by":"crossref","first-page":"215341","DOI":"10.1016\/j.ccr.2023.215341","volume":"494","author":"Nikolaou","year":"2023","journal-title":"Coord. Chem. Rev."},{"key":"jx3089_bb13","unstructured":"Palmer, D. (2020). CrystalMaker. CrystalMaker Software, Bicester, England."},{"key":"jx3089_bb14","doi-asserted-by":"crossref","first-page":"340","DOI":"10.1073\/pnas.20.6.340","volume":"20","author":"Pauling","year":"1934","journal-title":"Proc. Natl Acad. Sci. USA"},{"key":"jx3089_bb15","unstructured":"Rigaku OD (2023). CrysAlis PRO. Rigaku Oxford Diffraction Ltd, Yarnton, Oxfordshire, England."},{"key":"jx3089_bb16","doi-asserted-by":"crossref","first-page":"3450","DOI":"10.1021\/ja953038y","volume":"118","author":"Sato","year":"1996","journal-title":"J. Am. Chem. Soc."},{"key":"jx3089_bb17","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. A"},{"key":"jx3089_bb18","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"jx3089_bb19","first-page":"917","volume":"39","author":"Shova","year":"1998","journal-title":"Zh. Strukt. Khim. (Russ.) (J. Struct. Chem.)"},{"key":"jx3089_bb20","doi-asserted-by":"crossref","first-page":"16013","DOI":"10.1002\/anie.202007221","volume":"59","author":"Wei","year":"2020","journal-title":"Angew. Chem. Int. Ed."},{"key":"jx3089_bb21","first-page":"148","volume":"49","author":"Wyart","year":"1926","journal-title":"Bull. Soc. Fr. Miner."}],"container-title":["Acta Crystallographica Section C Structural Chemistry"],"original-title":[],"link":[{"URL":"https:\/\/journals.iucr.org\/c\/issues\/2024\/12\/00\/jx3089\/jx3089.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/journals.iucr.org\/c\/issues\/2024\/12\/00\/jx3089\/jx3089.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2024,12,5]],"date-time":"2024-12-05T15:05:29Z","timestamp":1733411129000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2053229624010672"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,11,20]]},"references-count":21,"journal-issue":{"issue":"12","published-online":{"date-parts":[[2024,12]]}},"alternative-id":["S2053229624010672"],"URL":"https:\/\/doi.org\/10.1107\/s2053229624010672","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2053229624010672\/jx3089sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2053229624010672\/jx3089Isup2.hkl","asserted-by":"subject"}]},"ISSN":["2053-2296"],"issn-type":[{"value":"2053-2296","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,11,20]]},"assertion":[{"value":"Acta Crystallographica Section C: Structural Chemistry","order":0,"name":"journal","label":"Publication","explanation":{"URL":"https:\/\/journals.iucr.org\/c"},"group":{"name":"general","label":"General"}},{"value":"research papers","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/c\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"https:\/\/scripts.iucr.org\/cgi-bin\/citedin?jx3089","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"20 September 2024","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"4 November 2024","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"20 November 2024","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?jx3089"}},{"value":"\u00a9 Abrahams et al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licensing","label":"Copyright and licencing"}},{"value":"IUCr licence to publish","order":1,"name":"license","label":"Licence","explanation":{"URL":"https:\/\/journals.iucr.org\/copyright\/licencetopublish.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}