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The geometrical and electronic properties are also discussed in relation to other reported Co\n                    <jats:sup>II<\/jats:sup>\n                    dimers having analogous structures (compounds\n                    <jats:bold>II<\/jats:bold>\n                    \u2013\n                    <jats:bold>IV<\/jats:bold>\n                    and\n                    <jats:bold>VI<\/jats:bold>\n                    ). Interestingly,\n                    <jats:bold>I<\/jats:bold>\n                    was found to possess quite similar structural features compared with the five other reported analogues (\n                    <jats:bold>II<\/jats:bold>\n                    \u2013\n                    <jats:bold>VI<\/jats:bold>\n                    ). The similarly elongated coordinate bond lengths in\n                    <jats:bold>I<\/jats:bold>\n                    \u2013\n                    <jats:bold>VI<\/jats:bold>\n                    further implied a consistency in their spin states at the metal centres. By analogy to a report on\n                    <jats:bold>V<\/jats:bold>\n                    , all these compounds were suggested to possess a high-spin septet state (\n                    <jats:italic>S<\/jats:italic>\n                    \u00a0= 3), previously evidenced for\n                    <jats:bold>V<\/jats:bold>\n                    by measuring its magnetic susceptibility data. The validity of these considerations was also confirmed by examining the density functional theory (DFT)-based structures, together with the energies of three possible spin states (\n                    <jats:italic>S<\/jats:italic>\n                    \u00a0= 3, 1 and 0).\n                  <\/jats:p>","DOI":"10.1107\/s2053229625008538","type":"journal-article","created":{"date-parts":[[2025,10,1]],"date-time":"2025-10-01T11:08:27Z","timestamp":1759316907000},"page":"620-627","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Geometrical and electronic properties of a family of high-spin cobalt(II) dimers bridged by 3,5-bis(pyridin-2-yl)pyrazolate and 3,5-bis(pyridin-2-yl)triazole ligands: insights into their catalysis in two-electron one-step CO\n                    <sub>2<\/sub>\n                    reduction"],"prefix":"10.1107","volume":"81","author":[{"given":"Fumika","family":"Sueyoshi","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Takumi","family":"Tsumagari","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ken","family":"Sakai","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2025,10,8]]},"reference":[{"key":"wv3020_bb1","doi-asserted-by":"crossref","first-page":"3808","DOI":"10.1039\/C4EE01709A","volume":"7","author":"Artero","year":"2014","journal-title":"Energy Environ. 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