{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T17:54:30Z","timestamp":1785434070106,"version":"3.56.0"},"reference-count":26,"publisher":"International Union of Crystallography (IUCr)","issue":"12","license":[{"start":{"date-parts":[[2025,11,28]],"date-time":"2025-11-28T00:00:00Z","timestamp":1764288000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2025,11,28]],"date-time":"2025-11-28T00:00:00Z","timestamp":1764288000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"funder":[{"DOI":"10.13039\/501100006769","name":"Russian Science Foundation","doi-asserted-by":"publisher","award":["23-13-00045"],"award-info":[{"award-number":["23-13-00045"]}],"id":[{"id":"10.13039\/501100006769","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004285","name":"Saint Petersburg State University","doi-asserted-by":"publisher","award":["125021702335-5"],"award-info":[{"award-number":["125021702335-5"]}],"id":[{"id":"10.13039\/501100004285","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"accepted":{"date-parts":[[2025,11,11]]},"published-print":{"date-parts":[[2025,12,1]]},"abstract":"<jats:p>\n                    Two benzamide-based derivatives were synthesized and their structures solved for the first time. The successful syntheses of\n                    <jats:italic>N<\/jats:italic>\n                    -ethyl-4-iodobenzamide (C\n                    <jats:sub>9<\/jats:sub>\n                    H\n                    <jats:sub>10<\/jats:sub>\n                    INO, NE4IBA) and\n                    <jats:italic>N<\/jats:italic>\n                    -ethyl-4-ethynylbenzamide (C\n                    <jats:sub>11<\/jats:sub>\n                    H\n                    <jats:sub>11<\/jats:sub>\n                    NO, NE4EBA) were achieved\n                    <jats:italic>via<\/jats:italic>\n                    a simple synthetic route. The molecules of NE4IBA in the crystal form one-dimensional double chains with strong hydrogen bonding and weak I...I halogen interactions, while NE4EBA forms two-dimensional hydrogen-bonded layers, including acetylene moieties engaging in C\u2014H...O interactions within a rigid planar layer packing arrangement. Intermolecular N\u2014H...O interactions between the amide groups dominate in both crystal structures. The strong exothermal effect of acetylene-group polymerization was detected immediately after melting NE4EBA using a simultaneous thermal analysis.\n                  <\/jats:p>","DOI":"10.1107\/s2053229625010083","type":"journal-article","created":{"date-parts":[[2025,11,17]],"date-time":"2025-11-17T11:54:04Z","timestamp":1763380444000},"page":"736-742","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structures, thermal properties and intermolecular interactions of new benzamide-based derivatives"],"prefix":"10.1107","volume":"81","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0564-0755","authenticated-orcid":true,"given":"Rajakumar","family":"Kanthapazham","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/03sfk2504","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Artyom A.","family":"Osipov","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/03sfk2504","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andrey N.","family":"Efremov","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/03sfk2504","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Vladislav S.","family":"Senchurin","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/03sfk2504","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sergey A.","family":"Naifert","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/03sfk2504","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dar'ya V.","family":"Spiridonova","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dmitry A.","family":"Zherebtsov","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/03sfk2504","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2025,11,28]]},"reference":[{"key":"vx3020_bb1","doi-asserted-by":"crossref","first-page":"805","DOI":"10.1021\/ar7002489","volume":"41","author":"Ahn","year":"2008","journal-title":"Acc. Chem. Res."},{"key":"vx3020_bb2","doi-asserted-by":"crossref","first-page":"22357","DOI":"10.1021\/acsomega.1c03078","volume":"6","author":"Ashfaq","year":"2021","journal-title":"ACS Omega"},{"key":"vx3020_bb3","doi-asserted-by":"crossref","first-page":"441","DOI":"10.1021\/j100785a001","volume":"68","author":"Bondi","year":"1964","journal-title":"J. Phys. Chem."},{"key":"vx3020_bb4","doi-asserted-by":"crossref","first-page":"59","DOI":"10.1107\/S2053273314022207","volume":"71","author":"Bourhis","year":"2015","journal-title":"Acta Cryst. A"},{"key":"vx3020_bb5","doi-asserted-by":"crossref","first-page":"2478","DOI":"10.1021\/acs.chemrev.5b00484","volume":"116","author":"Cavallo","year":"2016","journal-title":"Chem. Rev."},{"key":"vx3020_bb6","doi-asserted-by":"crossref","first-page":"e202116650","DOI":"10.1002\/ange.202116650","volume":"134","author":"Dhaka","year":"2022","journal-title":"Angew. Chem."},{"key":"vx3020_bb7","doi-asserted-by":"crossref","first-page":"339","DOI":"10.1107\/S0021889808042726","volume":"42","author":"Dolomanov","year":"2009","journal-title":"J. Appl. Cryst."},{"key":"vx3020_bb8","doi-asserted-by":"crossref","first-page":"127630","DOI":"10.1016\/j.molstruc.2019.127630","volume":"1205","author":"Guerrab","year":"2020","journal-title":"J. Mol. Struct."},{"key":"vx3020_bb9","doi-asserted-by":"crossref","first-page":"1575","DOI":"10.1039\/B211268J","volume":"13","author":"Iwase","year":"2003","journal-title":"J. Mater. Chem."},{"key":"vx3020_bb10","doi-asserted-by":"crossref","first-page":"15878","DOI":"10.1021\/jacs.7b08800","volume":"139","author":"Jordan","year":"2017","journal-title":"J. Am. Chem. Soc."},{"key":"vx3020_bb11","doi-asserted-by":"crossref","first-page":"1853","DOI":"10.1002\/pola.1989.080270606","volume":"27","author":"Kato","year":"1989","journal-title":"J. Polym. Sci. A Polym. Chem."},{"key":"vx3020_bb12","doi-asserted-by":"crossref","first-page":"9513","DOI":"10.1021\/la0493417","volume":"20","author":"Lee","year":"2004","journal-title":"Langmuir"},{"key":"vx3020_bb13","doi-asserted-by":"crossref","first-page":"18093","DOI":"10.1021\/jacs.0c07657","volume":"142","author":"Li","year":"2020","journal-title":"J. Am. Chem. Soc."},{"key":"vx3020_bb14","doi-asserted-by":"crossref","first-page":"634","DOI":"10.1021\/ja806663h","volume":"131","author":"Li","year":"2009","journal-title":"J. Am. Chem. Soc."},{"key":"vx3020_bb15","doi-asserted-by":"crossref","first-page":"755","DOI":"10.1021\/cg060773k","volume":"7","author":"McKinnon","year":"2007","journal-title":"Cryst. Growth Des."},{"key":"vx3020_bb16","doi-asserted-by":"crossref","first-page":"5","DOI":"10.1107\/S205225251303491X","volume":"1","author":"Metrangolo","year":"2014","journal-title":"IUCrJ"},{"key":"vx3020_bb17","doi-asserted-by":"crossref","first-page":"1358","DOI":"10.1021\/ol200051m","volume":"13","author":"N\u00e9abo","year":"2011","journal-title":"Org. Lett."},{"key":"vx3020_bb18","doi-asserted-by":"crossref","first-page":"45","DOI":"10.1080\/15421400600786306","volume":"456","author":"Okuno","year":"2006","journal-title":"Mol. Cryst. Liq. Cryst."},{"key":"vx3020_bb20","doi-asserted-by":"crossref","first-page":"273","DOI":"10.1007\/s10870-020-00852-3","volume":"51","author":"Ramalingam","year":"2021","journal-title":"J. Chem. Crystallogr."},{"key":"vx3020_bb21","unstructured":"Rigaku OD (2021). CrysAlis PRO. Rigaku Oxford Diffraction Ltd, Yarnton, Oxfordshire, England."},{"key":"vx3020_bb22","doi-asserted-by":"crossref","first-page":"2680","DOI":"10.1039\/c3tc00917c","volume":"1","author":"Rondeau-Gagn\u00e9","year":"2013","journal-title":"J. Mater. Chem. C"},{"key":"vx3020_bb23","doi-asserted-by":"crossref","first-page":"7384","DOI":"10.1021\/jp953141+","volume":"100","author":"Rowland","year":"1996","journal-title":"J. Phys. Chem."},{"key":"vx3020_bb24","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. A"},{"key":"vx3020_bb25","doi-asserted-by":"crossref","first-page":"1006","DOI":"10.1107\/S1600576721002910","volume":"54","author":"Spackman","year":"2021","journal-title":"J. Appl. Cryst."},{"key":"vx3020_bb26","doi-asserted-by":"crossref","first-page":"4088","DOI":"10.1039\/D1MA01180D","volume":"3","author":"Weston","year":"2022","journal-title":"Mater. Adv."},{"key":"vx3020_bb27","first-page":"368","volume":"10","author":"Wood","year":"2008","journal-title":"CrystEngComm"}],"container-title":["Acta Crystallographica Section C Structural Chemistry"],"original-title":[],"link":[{"URL":"https:\/\/journals.iucr.org\/c\/issues\/2025\/12\/00\/vx3020\/vx3020.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/journals.iucr.org\/c\/issues\/2025\/12\/00\/vx3020\/vx3020.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,12,4]],"date-time":"2025-12-04T15:03:54Z","timestamp":1764860634000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2053229625010083"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,11,28]]},"references-count":26,"journal-issue":{"issue":"12","published-online":{"date-parts":[[2025,12]]}},"alternative-id":["S2053229625010083"],"URL":"https:\/\/doi.org\/10.1107\/s2053229625010083","relation":{"is-supplemented-by":[{"id-type":"doi","id":"10.1107\/S2053229625010083\/vx3020sup1.cif","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2053229625010083\/vx3020NE4IBAsup2.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2053229625010083\/vx3020NE4IBAsup3.hkl","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2053229625010083\/vx3020NE4IBAsup4.cml","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2053229625010083\/vx3020NE4EBAsup5.cml","asserted-by":"subject"},{"id-type":"doi","id":"10.1107\/S2053229625010083\/vx3020sup6.pdf","asserted-by":"subject"}]},"ISSN":["2053-2296"],"issn-type":[{"value":"2053-2296","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,11,28]]},"assertion":[{"value":"Acta Crystallographica Section C: Structural Chemistry","order":0,"name":"journal","label":"Publication","explanation":{"URL":"https:\/\/journals.iucr.org\/c"},"group":{"name":"general","label":"General"}},{"value":"research papers","order":1,"name":"content_type","label":"Content type","explanation":{"URL":"https:\/\/journals.iucr.org\/c\/services\/notesforauthors.html"},"group":{"name":"general","label":"General"}},{"value":"Available","URL":"https:\/\/scripts.iucr.org\/cgi-bin\/citedin?vx3020","order":2,"name":"article_metrics","label":"Article metrics","group":{"name":"general","label":"General"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"9 October 2025","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"11 November 2025","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"28 November 2025","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"https:\/\/scripts.iucr.org\/cgi-bin\/sendsup?vx3020"}},{"value":"\u00a9 Rajakumar\n                      et al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licensing","label":"Copyright and licencing"}},{"value":"IUCr licence to publish","order":1,"name":"license","label":"Licence","explanation":{"URL":"https:\/\/journals.iucr.org\/copyright\/licencetopublish.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}