{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T12:41:32Z","timestamp":1785415292687,"version":"3.56.0"},"reference-count":66,"publisher":"International Union of Crystallography (IUCr)","issue":"2","license":[{"start":{"date-parts":[[2026,1,31]],"date-time":"2026-01-31T00:00:00Z","timestamp":1769817600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2026,1,31]],"date-time":"2026-01-31T00:00:00Z","timestamp":1769817600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"funder":[{"DOI":"10.13039\/501100006334","name":"Jan Kochanowski University","doi-asserted-by":"crossref","award":["SUPB RN 24.214"],"award-info":[{"award-number":["SUPB RN 24.214"]}],"id":[{"id":"10.13039\/501100006334","id-type":"DOI","asserted-by":"crossref"}]},{"name":"ILT&SR PAS","award":["2019\/5"],"award-info":[{"award-number":["2019\/5"]}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"accepted":{"date-parts":[[2026,1,20]]},"published-print":{"date-parts":[[2026,2,1]]},"abstract":"<jats:p>\n                    This article presents a comprehensive investigation involving the synthesis and characterization of three complexes obtained in an efficient one-pot synthesis using zero-valent cobalt and the proligand 1-hydroxymethyl-3,5-dimethylpyrazole (L\n                    <jats:sup>0<\/jats:sup>\n                    ) as one of the substrates. The isolated complexes, namely, [bromido\/nitrato(1.81\/0.19)][tris(3,5-dimethylpyrazol-1-ylmethyl-\u03ba\n                    <jats:italic>N<\/jats:italic>\n                    <jats:sup>2<\/jats:sup>\n                    )amine-\u03ba\n                    <jats:italic>N<\/jats:italic>\n                    ][cadmium\/cobalt(0.96\/0.04)], [Cd\n                    <jats:sub>0.96<\/jats:sub>\n                    Co\n                    <jats:sub>0.04<\/jats:sub>\n                    Br\n                    <jats:sub>1.81<\/jats:sub>\n                    (NO\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>0.19<\/jats:sub>\n                    (C\n                    <jats:sub>18<\/jats:sub>\n                    H\n                    <jats:sub>27<\/jats:sub>\n                    N\n                    <jats:sub>7<\/jats:sub>\n                    )] or [Cd\n                    <jats:sub>0.96<\/jats:sub>\n                    Co\n                    <jats:sub>0.04<\/jats:sub>\n                    L\n                    <jats:sup>S<\/jats:sup>\n                    Br\n                    <jats:sub>1.81<\/jats:sub>\n                    (NO\n                    <jats:sub>3<\/jats:sub>\n                    )\n                    <jats:sub>0.19<\/jats:sub>\n                    ],\n                    <jats:bold>1<\/jats:bold>\n                    , bis{(nitrato-\u03ba\n                    <jats:italic>O<\/jats:italic>\n                    )[tris(3,5-dimethylpyrazol-1-ylmethyl-\u03ba\n                    <jats:italic>N<\/jats:italic>\n                    <jats:sup>2<\/jats:sup>\n                    )amine-\u03ba\n                    <jats:italic>N<\/jats:italic>\n                    ]cobalt(II)} tetrabromidocadmate(II), [Co(NO\n                    <jats:sub>3<\/jats:sub>\n                    )(C\n                    <jats:sub>18<\/jats:sub>\n                    H\n                    <jats:sub>27<\/jats:sub>\n                    N\n                    <jats:sub>7<\/jats:sub>\n                    )]\n                    <jats:sub>2<\/jats:sub>\n                    [CdBr\n                    <jats:sub>4<\/jats:sub>\n                    ] or [CoL\n                    <jats:sup>S<\/jats:sup>\n                    NO\n                    <jats:sub>3<\/jats:sub>\n                    ]\n                    <jats:sub>2<\/jats:sub>\n                    [CdBr\n                    <jats:sub>4<\/jats:sub>\n                    ],\n                    <jats:bold>2<\/jats:bold>\n                    , and (nitrato-\u03ba\n                    <jats:italic>O<\/jats:italic>\n                    )[tris(3,5-dimethylpyrazol-1-ylmethyl-\u03ba\n                    <jats:italic>N<\/jats:italic>\n                    <jats:sup>2<\/jats:sup>\n                    )amine-\u03ba\n                    <jats:italic>N<\/jats:italic>\n                    ]cobalt(II) nitrate, [Co(NO\n                    <jats:sub>3<\/jats:sub>\n                    )(C\n                    <jats:sub>18<\/jats:sub>\n                    H\n                    <jats:sub>27<\/jats:sub>\n                    N\n                    <jats:sub>7<\/jats:sub>\n                    )]NO\n                    <jats:sub>3<\/jats:sub>\n                    or [CoL\n                    <jats:sup>S<\/jats:sup>\n                    NO\n                    <jats:sub>3<\/jats:sub>\n                    ]NO\n                    <jats:sub>3<\/jats:sub>\n                    ,\n                    <jats:bold>3<\/jats:bold>\n                    , all contain the\n                    <jats:italic>N<\/jats:italic>\n                    -scorpionate ligand\n                    <jats:italic>N<\/jats:italic>\n                    ,\n                    <jats:italic>N<\/jats:italic>\n                    ,\n                    <jats:italic>N<\/jats:italic>\n                    -tris(3,5-dimethylpyrazol-1-ylmethyl)amine (L\n                    <jats:sup>S<\/jats:sup>\n                    ) obtained\n                    <jats:italic>in situ<\/jats:italic>\n                    from L\n                    <jats:sup>0<\/jats:sup>\n                    . Compound\n                    <jats:bold>1<\/jats:bold>\n                    crystallizes in the monoclinic space group\n                    <jats:italic>P<\/jats:italic>\n                    2\n                    <jats:sub>1<\/jats:sub>\n                    \/\n                    <jats:italic>n<\/jats:italic>\n                    , and some positional disorder is observed at the metal ions and inorganic ligands. In contrast to\n                    <jats:bold>1<\/jats:bold>\n                    , compounds\n                    <jats:bold>2<\/jats:bold>\n                    and\n                    <jats:bold>3<\/jats:bold>\n                    form ionic crystals and crystallize in the same type of space group (No. 15) but in different settings,\n                    <jats:italic>i.e. C<\/jats:italic>\n                    2\/\n                    <jats:italic>c<\/jats:italic>\n                    and\n                    <jats:italic>I<\/jats:italic>\n                    2\/\n                    <jats:italic>a<\/jats:italic>\n                    , respectively. The synthesized compounds were characterized by X-ray diffraction, elemental analysis and FT\u2013IR spectroscopy. All the complexes presented here have good biological activity against cancer cells. Among the complexes studied,\n                    <jats:bold>2<\/jats:bold>\n                    and\n                    <jats:bold>3<\/jats:bold>\n                    are the most interesting. The interactions of isolated complexes\n                    <jats:bold>2<\/jats:bold>\n                    and\n                    <jats:bold>3<\/jats:bold>\n                    with CT-DNA were investigated using UV\u2013Vis absorption spectroscopy and circular dichroism (CD). Isolated complexes\n                    <jats:bold>2<\/jats:bold>\n                    and\n                    <jats:bold>3<\/jats:bold>\n                    interact with CT-DNA\n                    <jats:italic>via<\/jats:italic>\n                    nonintercalatory binding modes. The results show that complex\n                    <jats:bold>2<\/jats:bold>\n                    combines high anticancer potency with selective action towards\n                    <jats:italic>colorectal adenocarcinoma<\/jats:italic>\n                    cells and is more effective than complex\n                    <jats:bold>3<\/jats:bold>\n                    and the anticancer drug cisplatin. These properties make complex\n                    <jats:bold>2<\/jats:bold>\n                    an interesting candidate for further investigation of specific anticancer mechanisms.\n                  <\/jats:p>","DOI":"10.1107\/s2053229626000525","type":"journal-article","created":{"date-parts":[[2026,1,27]],"date-time":"2026-01-27T08:36:33Z","timestamp":1769502993000},"page":"81-93","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structures, cytotoxicity studies and interactions with DNA of novel\n                    <i>in situ<\/i>\n                    -formed complexes containing\n                    <i>N<\/i>\n                    -scorpionate ligands and nitrate ions"],"prefix":"10.1107","volume":"82","author":[{"given":"Anna","family":"Adach","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/00krbh354","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7945-1039","authenticated-orcid":true,"given":"Ma\u0142gorzata","family":"Tyszka-Czochara","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/03bqmcz70","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Agnieszka","family":"Gilewska","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/00krbh354","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1619-6146","authenticated-orcid":true,"given":"Marek","family":"Daszkiewicz","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/01dr6c206","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,1,31]]},"reference":[{"key":"ef3071_bb1","doi-asserted-by":"crossref","first-page":"757","DOI":"10.1080\/00958972.2017.1278572","volume":"70","author":"Adach","year":"2017","journal-title":"J. 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