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The phase purity of the bulk sample was confirmed using synchrotron powder X-ray diffraction. The organic ligands form a 2D layer, where cobalt and molybdenum are found, with sodium cations located between the layers. There are four crystallographically distinct sodium sites: three exhibit a distorted octahedral coordination geometry, while the remaining site is seven-coordinate. The cobalt has trigonal bipyramidal coordination geometry and molybdenum exhibits a tetrahedral coordination geometry. Half the sodium cations in the structure forms 1D column-like motifs\n                    <jats:italic>via<\/jats:italic>\n                    shared oxygen edges along the crystallographic\n                    <jats:italic>c<\/jats:italic>\n                    axis, which are cross-linked in\n                    <jats:italic>b<\/jats:italic>\n                    by the cobalt and molybdenum sites\n                    <jats:italic>via<\/jats:italic>\n                    bridging O atoms, while the other half of the sodium cations form 2D ribbons in the\n                    <jats:italic>ac<\/jats:italic>\n                    plane, propagating along\n                    <jats:italic>c<\/jats:italic>\n                    , linked by sharing oxygen edges and faces. The optical properties of UOW-10 were investigated through the use of UV\u2013Vis spectroscopy, showing a bandgap of 1.8\u2005eV. Deconvolution of the features in the visible-light region reveals that four peaks are present, which can all be ascribed to the\n                    <jats:italic>d\u2013d<\/jats:italic>\n                    transitions from the trigonal bipyramidal cobalt. By means of thermogravimetric analysis (TGA) and variable-temperature powder X-ray diffraction (VT-PXRD), it is demonstrated that the material has thermal stability to 410\u2005\u00b0C, after which structure collapse occurs, leading to a mixture of Na\n                    <jats:sub>2<\/jats:sub>\n                    MoO\n                    <jats:sub>4<\/jats:sub>\n                    , CoO and Co\n                    <jats:sub>3<\/jats:sub>\n                    Mo above 900\u2005\u00b0C.\n                  <\/jats:p>","DOI":"10.1107\/s205322962600077x","type":"journal-article","created":{"date-parts":[[2026,1,27]],"date-time":"2026-01-27T10:30:11Z","timestamp":1769509811000},"page":"102-109","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Structure and optical properties of a trimetallic cobalt\u2013molybdenum\u2013sodium metal\u2013organic framework"],"prefix":"10.1107","volume":"82","author":[{"given":"Benjamin J.","family":"Moore","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jeremiah P.","family":"Tidey","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2699-1725","authenticated-orcid":true,"given":"Craig I.","family":"Hiley","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9706-2774","authenticated-orcid":true,"given":"Richard I.","family":"Walton","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2026,2,9]]},"reference":[{"key":"qf3071_bb1","doi-asserted-by":"crossref","first-page":"11867","DOI":"10.1039\/D4DT01100G","volume":"53","author":"Ahmed","year":"2024","journal-title":"Dalton Trans."},{"key":"qf3071_bb2","doi-asserted-by":"crossref","first-page":"380","DOI":"10.1107\/S0108768110012048","volume":"66","author":"Allen","year":"2010","journal-title":"Acta Cryst. 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