{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,30]],"date-time":"2026-07-30T17:07:57Z","timestamp":1785431277368,"version":"3.56.0"},"reference-count":33,"publisher":"International Union of Crystallography (IUCr)","issue":"5","license":[{"start":{"date-parts":[[2026,4,7]],"date-time":"2026-04-07T00:00:00Z","timestamp":1775520000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2026,4,7]],"date-time":"2026-04-07T00:00:00Z","timestamp":1775520000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"accepted":{"date-parts":[[2026,3,30]]},"published-print":{"date-parts":[[2026,5,1]]},"abstract":"<jats:p>\n                    Zero-dimensional (0D) perovskites are promising materials due to their structures comprising isolated metal halide octahedra or clusters, which impart remarkable optoelectronic properties. The synthesis, crystal structure and Hirshfeld surface analysis of the title compound, 1,4-diazoniabicyclo[2.2.2]octane hexabromidostannate(IV) hemihydrate, (C\n                    <jats:sub>6<\/jats:sub>\n                    H\n                    <jats:sub>14<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    )[SnBr\n                    <jats:sub>6<\/jats:sub>\n                    ]\u00b70.5H\n                    <jats:sub>2<\/jats:sub>\n                    O or (DABCO)[SnBr\n                    <jats:sub>6<\/jats:sub>\n                    ]\u00b70.5H\n                    <jats:sub>2<\/jats:sub>\n                    O, are reported. The compound crystallizes in the monoclinic space group\n                    <jats:italic>P<\/jats:italic>\n                    2\n                    <jats:sub>1<\/jats:sub>\n                    \/\n                    <jats:italic>n<\/jats:italic>\n                    . Dominant H...Br\/Br...H interactions (90.5%) are observed, with smaller contributions from H...H (5.1%), Br...Br (4.2%) and O...Br\/Br...O (0.1%) contacts. These structural features underline the role of hydrogen bonding in stabilizing the 0D framework, highlighting its potential for light-emitting and photonic applications.\n                  <\/jats:p>","DOI":"10.1107\/s2053229626003323","type":"journal-article","created":{"date-parts":[[2026,4,7]],"date-time":"2026-04-07T13:20:06Z","timestamp":1775568006000},"page":"199-203","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structure and Hirshfeld surface analysis of the zero-dimensional hybrid perovskite 1,4-diazoniabicyclo[2.2.2]octane hexabromidostannate(IV)"],"prefix":"10.1107","volume":"82","author":[{"ORCID":"https:\/\/orcid.org\/0009-0009-2919-7322","authenticated-orcid":true,"given":"Pakidame","family":"Boundja","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ayi Djifa","family":"Hounsi","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nicolas","family":"Claiser","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/017je3b10","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7807-5182","authenticated-orcid":true,"given":"Emmanuel","family":"Wenger","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/017je3b10","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6021-3599","authenticated-orcid":true,"given":"Milohum Mikesokpo","family":"Dzagli","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Claude","family":"Lecomte","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/017je3b10","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,4,7]]},"reference":[{"key":"ux3014_bb1","doi-asserted-by":"crossref","first-page":"4353","DOI":"10.1039\/C6TA00334F","volume":"4","author":"Albero","year":"2016","journal-title":"J. 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