{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,25]],"date-time":"2026-08-25T21:22:40Z","timestamp":1787692960311,"version":"build-2784847793"},"reference-count":48,"publisher":"International Union of Crystallography (IUCr)","issue":"8","license":[{"start":{"date-parts":[[2026,7,20]],"date-time":"2026-07-20T00:00:00Z","timestamp":1784505600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"},{"start":{"date-parts":[[2026,7,20]],"date-time":"2026-07-20T00:00:00Z","timestamp":1784505600000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/legalcode"}],"funder":[{"name":"Program for Innovative Research Team from the University of Henan Province","award":["24IRTSTHN005"],"award-info":[{"award-number":["24IRTSTHN005"]}]}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"accepted":{"date-parts":[[2026,7,2]]},"published-print":{"date-parts":[[2026,8,1]]},"abstract":"<jats:p>\n                    Exploring orange-light-emitting lead-free halides with high photoluminescence quantum yields (PLQYs) is a significant challenge in luminescent materials research. Herein, a zero-dimensional organic\u2013inorganic hybrid halide, namely, 4,4\u2032-(ethane-1,2-diyl)dipyridin-1-ium pentachloridoantimonate(III), (C\n                    <jats:sub>12<\/jats:sub>\n                    H\n                    <jats:sub>14<\/jats:sub>\n                    N\n                    <jats:sub>2<\/jats:sub>\n                    )[SbCl\n                    <jats:sub>5<\/jats:sub>\n                    ] or [H\n                    <jats:sub>2<\/jats:sub>\n                    bpa][SbCl\n                    <jats:sub>5<\/jats:sub>\n                    ], where bpa is 1,2-bis(pyridin-4-yl)ethane, was synthesized\n                    <jats:italic>via<\/jats:italic>\n                    acid solution evaporation. The compound crystallizes in the triclinic space group\n                    <jats:italic>P<\/jats:italic>\n                    <jats:overline>1<\/jats:overline>\n                    . The asymmetric unit consists of an [SbCl\n                    <jats:sub>5<\/jats:sub>\n                    ]\n                    <jats:sup>2\u2212<\/jats:sup>\n                    anion and two half [H\n                    <jats:sub>2<\/jats:sub>\n                    bpa]\n                    <jats:sup>2+<\/jats:sup>\n                    cations. The [SbCl\n                    <jats:sub>5<\/jats:sub>\n                    ]\n                    <jats:sup>2\u2212<\/jats:sup>\n                    anion and [H\n                    <jats:sub>2<\/jats:sub>\n                    bpa]\n                    <jats:sup>2+<\/jats:sup>\n                    cations are linked\n                    <jats:italic>via<\/jats:italic>\n                    intermolecular hydrogen bonds and \u03c0\u2013\u03c0 interactions to form a three-dimensional supramolecular architecture. Significantly, this halide exhibits highly efficient orange-light emission centred at 600\u2005nm, with a PLQY of 65.57%.\n                  <\/jats:p>","DOI":"10.1107\/s2053229626006935","type":"journal-article","created":{"date-parts":[[2026,7,10]],"date-time":"2026-07-10T11:18:21Z","timestamp":1783682301000},"page":"453-458","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis, structure and orange-light emission of a zero-dimensional antimony(III) halide with the 4,4\u2032-(ethane-1,2-diyl)dipyridin-1-ium cation"],"prefix":"10.1107","volume":"82","author":[{"given":"Ting","family":"Li","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/029man787","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yan-Hong","family":"Li","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/029man787","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jia-Yi","family":"Han","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/029man787","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yi-Tong","family":"Wang","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/04qr5t414","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Min-Le","family":"Han","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/029man787","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,7,20]]},"reference":[{"key":"son3007_bb1","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.poly.2015.05.041","volume":"98","author":"Adonin","year":"2015","journal-title":"Polyhedron"},{"key":"son3007_bb2","doi-asserted-by":"crossref","first-page":"5529","DOI":"10.1039\/C5NJ00889A","volume":"39","author":"Adonin","year":"2015","journal-title":"New J. 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