{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,2]],"date-time":"2026-10-02T10:54:27Z","timestamp":1790938467788,"version":"4.1.0"},"reference-count":27,"publisher":"International Union of Crystallography (IUCr)","issue":"9","license":[{"start":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T00:00:00Z","timestamp":1785888000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2026,8,5]],"date-time":"2026-08-05T00:00:00Z","timestamp":1785888000000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"accepted":{"date-parts":[[2026,7,16]]},"published-print":{"date-parts":[[2026,9,1]]},"abstract":"<jats:p>\n                    The title novel phosphonium-based manganese(II) hybrid crystal, {(C\n                    <jats:sub>24<\/jats:sub>\n                    H\n                    <jats:sub>26<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    P)\n                    <jats:sub>2<\/jats:sub>\n                    [MnCl\n                    <jats:sub>4<\/jats:sub>\n                    ]}\n                    <jats:sub>\n                      <jats:italic>n<\/jats:italic>\n                    <\/jats:sub>\n                    or (TBTP)\n                    <jats:sub>2<\/jats:sub>\n                    [MnCl\n                    <jats:sub>4<\/jats:sub>\n                    ], was synthesized\n                    <jats:italic>via<\/jats:italic>\n                    slow evaporation. Single-crystal X-ray diffraction reveals that it crystallizes in the monoclinic space group\n                    <jats:italic>P<\/jats:italic>\n                    2\n                    <jats:sub>1<\/jats:sub>\n                    \/\n                    <jats:italic>n<\/jats:italic>\n                    , featuring discrete slightly distorted tetrahedral [MnCl\n                    <jats:sub>4<\/jats:sub>\n                    ]\n                    <jats:sup>2\u2212<\/jats:sup>\n                    anions and bulky (TBTP)\n                    <jats:sup>+<\/jats:sup>\n                    cations [(TBTP)\n                    <jats:sup>+<\/jats:sup>\n                    is (\n                    <jats:italic>tert<\/jats:italic>\n                    -butoxycarbonyl)methyltriphenylphosphonium] with weak C\u2014H...Cl interactions. The material exhibits green luminescence centred at 515\u2005nm with a millisecond-scale lifetime (2.83\u2005ms), which is unequivocally assigned to the long-lived spin-forbidden Mn\n                    <jats:sup>2+ 4<\/jats:sup>\n                    <jats:italic>T<\/jats:italic>\n                    <jats:sub>1<\/jats:sub>\n                    \u2192\n                    <jats:sup>6<\/jats:sup>\n                    <jats:italic>A<\/jats:italic>\n                    <jats:sub>1<\/jats:sub>\n                    <jats:italic>d<\/jats:italic>\n                    \u2013\n                    <jats:italic>d<\/jats:italic>\n                    transition. Electronic structure calculations reveal a direct band gap (with the noted underestimation typical of the PBE functional) and, more importantly, a clear spatial separation of the frontier orbitals between the inorganic and organic components. This orbital separation, likely aiding in the isolation of the luminescent [MnCl\n                    <jats:sub>4<\/jats:sub>\n                    ]\n                    <jats:sup>2\u2212<\/jats:sup>\n                    centres, is consistent with the observed long emission lifetime. This work enriches the family of phosphonium-based hybrid metal halides and provides insights into the structure\u2013property relationships governing Mn\n                    <jats:sup>2+<\/jats:sup>\n                    emission in such systems.\n                  <\/jats:p>","DOI":"10.1107\/s205322962600731x","type":"journal-article","created":{"date-parts":[[2026,7,23]],"date-time":"2026-07-23T16:08:53Z","timestamp":1784822933000},"page":"534-541","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis, crystal structure and green luminescence of a novel manganese(II)-based hybrid: bis[(\n                    <i>tert<\/i>\n                    -butoxycarbonyl)methyltriphenylphosphonium] tetrachloridomanganate(II)"],"prefix":"10.1107","volume":"82","author":[{"given":"Chan","family":"Jiao","sequence":"first","affiliation":[{"id":[{"id":"https:\/\/ror.org\/012nfwd22","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qianqian","family":"Liu","sequence":"additional","affiliation":[{"id":[{"id":"https:\/\/ror.org\/012nfwd22","id-type":"ROR","asserted-by":"publisher"}]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tao","family":"Dong","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,8,5]]},"reference":[{"key":"son3006_bb1","doi-asserted-by":"crossref","first-page":"326","DOI":"10.1002\/cptc.202000112","volume":"5","author":"Ben-Akacha","year":"2021","journal-title":"ChemPhotoChem"},{"key":"son3006_bb2","unstructured":"Bruker (2016). 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