{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T16:55:36Z","timestamp":1791219336718,"version":"4.1.0"},"reference-count":21,"publisher":"International Union of Crystallography (IUCr)","issue":"10","license":[{"start":{"date-parts":[[2026,9,5]],"date-time":"2026-09-05T00:00:00Z","timestamp":1788566400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},{"start":{"date-parts":[[2026,9,5]],"date-time":"2026-09-05T00:00:00Z","timestamp":1788566400000},"content-version":"tdm","delay-in-days":0,"URL":"https:\/\/journals.iucr.org\/services\/copyrightpolicy.html#TDM"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr C Struct Chem","Acta Crystallogr C","Acta Crystallogr C Cryst Struct Commun","Acta Cryst C","Acta Cryst C Struct Chem","Acta Cryst Sect C","Acta Cryst Sect C Struct Chem","Acta Crystallogr Sect C","Acta Crystallogr Sect C Struct Chem","Acta Crystallogr Sect C Cryst Struct Commun"],"accepted":{"date-parts":[[2026,8,19]]},"published-print":{"date-parts":[[2026,10,1]]},"abstract":"<jats:p>\n                    The crystal structure of a sodium iron\u2013sulfur nitrosyl cluster salt, namely,\n                    <jats:italic>catena<\/jats:italic>\n                    -poly[[[diaquasodium(I)]-di-\u03bc-aqua-[diaquasodium(I)]-di-\u03bc-aqua] bis{heptanitrosyltri-\u03bc\n                    <jats:sub>3<\/jats:sub>\n                    -sulfido-tetrairon(3\n                    <jats:italic>Fe<\/jats:italic>\n                    \u2014\n                    <jats:italic>Fe<\/jats:italic>\n                    )] dihydrate], {[Na\n                    <jats:sub>2<\/jats:sub>\n                    (H\n                    <jats:sub>2<\/jats:sub>\n                    O)\n                    <jats:sub>8<\/jats:sub>\n                    ][Fe\n                    <jats:sub>4<\/jats:sub>\n                    S\n                    <jats:sub>3<\/jats:sub>\n                    (NO)\n                    <jats:sub>7<\/jats:sub>\n                    ]\n                    <jats:sub>2<\/jats:sub>\n                    \u00b72H\n                    <jats:sub>2<\/jats:sub>\n                    O}\n                    <jats:sub>\n                      <jats:italic>n<\/jats:italic>\n                    <\/jats:sub>\n                    , was determined by single-crystal X-ray diffraction. The crystal belongs to the orthorhombic system, space group\n                    <jats:italic>Pna<\/jats:italic>\n                    2\n                    <jats:sub>1<\/jats:sub>\n                    . The structure retains the typical [Fe\n                    <jats:sub>4<\/jats:sub>\n                    S\n                    <jats:sub>3<\/jats:sub>\n                    (NO)\n                    <jats:sub>7<\/jats:sub>\n                    ]\n                    <jats:sup>\u2212<\/jats:sup>\n                    incomplete cubane-type core skeleton and its geometric configuration is similar to those of reported alkali metal Roussin's black salts, such as the caesium salt. Owing to the strong hydration effect of Na\n                    <jats:sup>+<\/jats:sup>\n                    , one-dimensional polymeric hydrated sodium chains extending along the\n                    <jats:italic>a<\/jats:italic>\n                    axis and a supramolecular network are formed\n                    <jats:italic>via<\/jats:italic>\n                    coordination and O\u2014H...O hydrogen bonds with the water molecules. The crystal packing is primarily driven by this hydrogen-bonded network, accompanied by localized positional disorder of the lattice water molecules and a 60\u00b0 rotational disorder of the anions around a pseudo-threefold axis. By introducing an inversion twin model and applying appropriate geometric and displacement parameter restraints, these crystallographic disorders were properly handled during the refinement.\n                  <\/jats:p>","DOI":"10.1107\/s2053229626008594","type":"journal-article","created":{"date-parts":[[2026,8,24]],"date-time":"2026-08-24T10:13:41Z","timestamp":1787566421000},"page":"671-675","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Synthesis and crystal structure characterization of Na[Fe\n                    <sub>4<\/sub>\n                    S\n                    <sub>3<\/sub>\n                    (NO)\n                    <sub>7<\/sub>\n                    ]\u00b75H\n                    <sub>2<\/sub>\n                    O"],"prefix":"10.1107","volume":"82","author":[{"given":"Wangyan","family":"Zhang","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yezi","family":"Zhang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tiantian","family":"Lei","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xueru","family":"Liu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanxia","family":"Zhao","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenhua","family":"Xu","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9306-3227","authenticated-orcid":true,"given":"Ying","family":"Yang","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2026,9,5]]},"reference":[{"key":"ef3077_bb1","unstructured":"Bruker (2016). 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