{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T08:49:23Z","timestamp":1736844563708,"version":"3.33.0"},"reference-count":15,"publisher":"International Union of Crystallography (IUCr)","issue":"1","license":[{"start":{"date-parts":[[2015,1,1]],"date-time":"2015-01-01T00:00:00Z","timestamp":1420070400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2015,1,1]],"date-time":"2015-01-01T00:00:00Z","timestamp":1420070400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2015,1,1]]},"abstract":"<jats:p>In the neutral complex molecule of the title compound,<jats:italic>fac<\/jats:italic>-[CrCl<jats:sub>3<\/jats:sub>(tpa)] [tpa is tris(pyridin-2-yl)amine; C<jats:sub>15<\/jats:sub>H<jats:sub>12<\/jats:sub>N<jats:sub>4<\/jats:sub>], the Cr<jats:sup>III<\/jats:sup>ion is bonded to three N atoms that are constrained to a<jats:italic>facial<\/jats:italic>arrangement by the tpa ligand and by three chloride ligands, leading to a distorted octahedral coordination sphere. The average Cr\u2014N and Cr\u2014Cl bond lengths are 2.086\u2005(5) and 2.296\u2005(4)\u2005\u00c5, respectively. The complex molecule is located on a mirror plane. In the crystal, a combination of C\u2014H...N and C\u2014H...Cl hydrogen-bonding interactions connect the molecules into a three-dimensional network.<\/jats:p>","DOI":"10.1107\/s2056989014027066","type":"journal-article","created":{"date-parts":[[2014,12,16]],"date-time":"2014-12-16T09:28:27Z","timestamp":1418722107000},"page":"73-75","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structure of<i>fac<\/i>-trichlorido[tris(pyridin-2-yl-<i>N<\/i>)amine]chromium(III)"],"prefix":"10.1107","volume":"71","author":[{"given":"Yukiko","family":"Yamaguchi-Terasaki","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Takashi","family":"Fujihara","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Akira","family":"Nagasawa","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sumio","family":"Kaizaki","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2015,1,1]]},"reference":[{"key":"wm5095_bb1","unstructured":"Bruker (2014). 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