{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,11,1]],"date-time":"2025-11-01T08:18:11Z","timestamp":1761985091419,"version":"build-2065373602"},"reference-count":18,"publisher":"International Union of Crystallography (IUCr)","issue":"2","license":[{"start":{"date-parts":[[2015,1,10]],"date-time":"2015-01-10T00:00:00Z","timestamp":1420848000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2015,1,10]],"date-time":"2015-01-10T00:00:00Z","timestamp":1420848000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2015,2,1]]},"abstract":"<jats:p>The title compound, [Ru(C<jats:sub>10<\/jats:sub>H<jats:sub>8<\/jats:sub>N<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>(C<jats:sub>16<\/jats:sub>H<jats:sub>12<\/jats:sub>N<jats:sub>4<\/jats:sub>O)](BF<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>\u00b73CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>, crystallizes with one complex dication, two BF<jats:sub>4<\/jats:sub><jats:sup>\u2212<\/jats:sup>counter-anions and three dichloromethane solvent molecules in the asymmetric unit. The central Ru<jats:sup>II<\/jats:sup>atom adopts a distorted octahedral coordination sphere with two 2,2\u2032-bipyridine (bpy) and one quinoline-2-carbaldehyde (pyridine-2-carbonyl)hydrazone (H<jats:italic>L<\/jats:italic>) ligand. The hydrazone ligand has a<jats:italic>Z<\/jats:italic>form and coordinates to the Ru<jats:sup>II<\/jats:sup>atom<jats:italic>via<\/jats:italic>the amide-O and imine-N atoms, affording a planar five-membered chelate ring, while its pyridine-N and quinoline-N donor atoms in the substituents are non-coordinating. The hydrazone N\u2014H group forms an intramolecular hydrogen bond with the quinoline-N atom. In the crystal, the quinoline moiety of H<jats:italic>L<\/jats:italic>shows the shortest \u03c0\u2013\u03c0 stacking interaction with the pyridine substituent of H<jats:italic>L<\/jats:italic>in a neighbouring complex, the centroid-to-centroid distance being 3.793\u2005(3)\u2005\u00c5.<\/jats:p>","DOI":"10.1107\/s2056989015000122","type":"journal-article","created":{"date-parts":[[2015,1,9]],"date-time":"2015-01-09T09:31:14Z","timestamp":1420795874000},"page":"142-145","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Crystal structure of bis(2,2\u2032-bipyridine)[<i>N<\/i>\u2032-(quinolin-2-ylmethylidene)pyridine-2-carbohydrazide]ruthenium(II) bis(tetrafluoridoborate) dichloromethane trisolvate"],"prefix":"10.1107","volume":"71","author":[{"given":"Asami","family":"Mori","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Takayoshi","family":"Suzuki","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Kiyohiko","family":"Nakajima","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2015,1,10]]},"reference":[{"key":"wm5107_bb1","doi-asserted-by":"crossref","first-page":"3232","DOI":"10.1039\/b704102k","author":"Bernhardt","year":"2007","journal-title":"Dalton Trans."},{"key":"wm5107_bb2","doi-asserted-by":"crossref","first-page":"381","DOI":"10.1107\/S002188980403225X","volume":"38","author":"Burla","year":"2005","journal-title":"J. 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