{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,19]],"date-time":"2025-10-19T18:25:19Z","timestamp":1760898319353,"version":"3.33.0"},"reference-count":14,"publisher":"International Union of Crystallography (IUCr)","issue":"2","license":[{"start":{"date-parts":[[2015,1,17]],"date-time":"2015-01-17T00:00:00Z","timestamp":1421452800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2015,1,17]],"date-time":"2015-01-17T00:00:00Z","timestamp":1421452800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2015,2,1]]},"abstract":"<jats:p>In the title complex, [Hg(NCS)<jats:sub>2<\/jats:sub>(CH<jats:sub>4<\/jats:sub>N<jats:sub>2<\/jats:sub>S)<jats:sub>2<\/jats:sub>], the Hg<jats:sup>II<\/jats:sup>atom is four-coordinated having an irregular four-coordinate geometry composed of four thione S atoms of two thiocyanate groups and two thiourea groups. The S\u2014Hg\u2014S angles are 172.02\u2005(9)\u00b0 for the<jats:italic>trans<\/jats:italic>-thiocyanate S atoms and 90.14\u2005(5)\u00b0 for the<jats:italic>cis<\/jats:italic>-thiourea S atoms. The molecular structure is stabilized by an intramolecular N\u2014H...S hydrogen bond, which forms an<jats:italic>S<\/jats:italic>(6) ring motif. In the crystal, molecules are linked by a number of N\u2014H...N and N\u2014H...S hydrogen bonds, forming a three-dimensional framework. The first report of the crystal structure of this compound appeared in 1966 [Korczynski (1966).<jats:italic>Rocz. Chem.<\/jats:italic><jats:bold>40<\/jats:bold>, 547\u2013569] with an extremely high<jats:italic>R<\/jats:italic>factor of 17.2%, and no mention of how the data were collected.<\/jats:p>","DOI":"10.1107\/s2056989015000584","type":"journal-article","created":{"date-parts":[[2015,1,16]],"date-time":"2015-01-16T09:23:59Z","timestamp":1421400239000},"page":"m28-m29","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":3,"title":["Crystal structure of bis(thiocyanato-\u03ba<i>S<\/i>)bis(thiourea-\u03ba<i>S<\/i>)mercury(II)"],"prefix":"10.1107","volume":"71","author":[{"given":"A.","family":"Baskaran","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"K.","family":"Rajarajan","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"M.","family":"NizamMohideen","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"P.","family":"Sagayaraj","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2015,1,17]]},"reference":[{"key":"su5058_bb1","doi-asserted-by":"crossref","first-page":"130","DOI":"10.1016\/S0020-1693(01)00448-0","volume":"319","author":"Bell","year":"2001","journal-title":"Inorg. 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