{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T08:49:32Z","timestamp":1736844572135,"version":"3.33.0"},"reference-count":15,"publisher":"International Union of Crystallography (IUCr)","issue":"3","license":[{"start":{"date-parts":[[2015,2,18]],"date-time":"2015-02-18T00:00:00Z","timestamp":1424217600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2015,2,18]],"date-time":"2015-02-18T00:00:00Z","timestamp":1424217600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2015,3,1]]},"abstract":"<jats:p>The mixed-metal thiophosphate, Nb<jats:sub>1.18<\/jats:sub>V<jats:sub>0.82<\/jats:sub>PS<jats:sub>10<\/jats:sub>(niobium vanadium phosphorus decasulfide), has been prepared though solid state reactions using an alkali-metal halide flux. The title compound is isostructural with two-dimensional Nb<jats:sub>2<\/jats:sub>PS<jats:sub>10<\/jats:sub>. [<jats:italic>M<\/jats:italic><jats:sub>2<\/jats:sub>S<jats:sub>12<\/jats:sub>] (<jats:italic>M<\/jats:italic>= Nb or V) dimers built up from two bicapped trigonal prisms and tetrahedral [PS<jats:sub>4<\/jats:sub>] units share sulfur atoms to construct<jats:sup>1<\/jats:sup><jats:sub>\u221e<\/jats:sub>[<jats:italic>M<\/jats:italic><jats:sub>2<\/jats:sub>PS<jats:sub>10<\/jats:sub>] chains along the<jats:italic>a<\/jats:italic>axis. These chains are linked through the disulfide bonds between [PS<jats:sub>4<\/jats:sub>] units in adjacent chains to form layers parallel to the<jats:italic>ab<\/jats:italic>plane. These layers then stack on top of each other to complete the three-dimensional structure with van der Waals gaps. The<jats:italic>M<\/jats:italic>sites are occupied by 59% of Nb and 41% of V and the average<jats:italic>M<\/jats:italic>\u2014S and<jats:italic>M<\/jats:italic>\u2014<jats:italic>M<\/jats:italic>distances in the title compound are in between those of V<jats:sub>2<\/jats:sub>PS<jats:sub>10<\/jats:sub>and Nb<jats:sub>2<\/jats:sub>PS<jats:sub>10<\/jats:sub>. The classical charge balance of the title compound can be represented by [(Nb\/V)<jats:sup>4+<\/jats:sup>]<jats:sub>2<\/jats:sub>[P<jats:sup>5+<\/jats:sup>][S<jats:sup>2\u2212<\/jats:sup>]<jats:sub>3<\/jats:sub>[S<jats:sup>\u2212<\/jats:sup>]<jats:sub>7<\/jats:sub>.<\/jats:p>","DOI":"10.1107\/s2056989015003072","type":"journal-article","created":{"date-parts":[[2015,2,17]],"date-time":"2015-02-17T12:47:44Z","timestamp":1424177264000},"page":"278-280","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structure of the mixed-metal thiophosphate Nb<sub>1.18<\/sub>V<sub>0.82<\/sub>PS<sub>10<\/sub>"],"prefix":"10.1107","volume":"71","author":[{"given":"Joobin","family":"Sun","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jiyun","family":"Heo","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hoseop","family":"Yun","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2015,2,18]]},"reference":[{"key":"pj2018_bb1","doi-asserted-by":"crossref","first-page":"55","DOI":"10.1006\/jssc.2000.8739","volume":"153","author":"Angenault","year":"2000","journal-title":"J. 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