{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,11,1]],"date-time":"2025-11-01T08:20:43Z","timestamp":1761985243555,"version":"build-2065373602"},"reference-count":24,"publisher":"International Union of Crystallography (IUCr)","issue":"3","license":[{"start":{"date-parts":[[2015,2,21]],"date-time":"2015-02-21T00:00:00Z","timestamp":1424476800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2015,2,21]],"date-time":"2015-02-21T00:00:00Z","timestamp":1424476800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2015,3,1]]},"abstract":"<jats:p>The structure of the title compound, [CrCl(C<jats:sub>12<\/jats:sub>H<jats:sub>8<\/jats:sub>N<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)][ZnCl<jats:sub>4<\/jats:sub>]\u00b7H<jats:sub>2<\/jats:sub>O, has been determined from synchrotron data. The Cr<jats:sup>III<\/jats:sup>ion is bonded to four N atoms from two 1,10-phenanthroline (phen) ligands, one water molecule and a Cl atom in a<jats:italic>cis<\/jats:italic>arrangement, displaying an overall distorted octahedral coordination environment. The Cr\u2014N(phen) bond lengths are in the range of 2.0495\u2005(18) to 2.0831\u2005(18)\u2005\u00c5, while the Cr\u2014Cl and Cr\u2014(OH<jats:sub>2<\/jats:sub>) bond lengths are 2.2734\u2005(7) and 1.9986\u2005(17)\u2005\u00c5, respectively. The tetrahedral [ZnCl<jats:sub>4<\/jats:sub>]<jats:sup>2\u2212<\/jats:sup>anion is slightly distorted owing to its involvement in O\u2014H...Cl hydrogen bonding with coordinating and non-coordinating water molecules. The two types of water molecules also interact through O\u2014H...O hydrogen bonds. The observed hydrogen-bonding pattern leads to the formation of a three-dimensional network structure.<\/jats:p>","DOI":"10.1107\/s2056989015003266","type":"journal-article","created":{"date-parts":[[2015,2,20]],"date-time":"2015-02-20T10:18:56Z","timestamp":1424427536000},"page":"288-290","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":2,"title":["Crystal structure of<i>cis<\/i>-aquachloridobis(1,10-phenanthroline-\u03ba<sup>2<\/sup><i>N<\/i>,<i>N<\/i>\u2032)chromium(III) tetrachloridozincate monohydrate from synchrotron data"],"prefix":"10.1107","volume":"71","author":[{"given":"Dohyun","family":"Moon","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jong-Ha","family":"Choi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2015,2,21]]},"reference":[{"key":"wm5123_bb1","unstructured":"Arvai, A. J. & Nielsen, C. (1983). ADSC Quantum-210 ADX. Area Detector System Corporation, Poway, CA, USA."},{"key":"wm5123_bb2","doi-asserted-by":"crossref","first-page":"m121","DOI":"10.1107\/S1600536810000127","volume":"66","author":"Birk","year":"2010","journal-title":"Acta Cryst. E"},{"key":"wm5123_bb3","doi-asserted-by":"crossref","first-page":"m369","DOI":"10.1107\/S1600536808001153","volume":"64","author":"Birk","year":"2008","journal-title":"Acta Cryst. E"},{"key":"wm5123_bb4","doi-asserted-by":"crossref","first-page":"4231","DOI":"10.1016\/j.ica.2009.05.024","volume":"362","author":"Choi","year":"2009","journal-title":"Inorg. Chim. Acta"},{"key":"wm5123_bb5","doi-asserted-by":"crossref","first-page":"796","DOI":"10.1016\/j.saa.2007.01.002","volume":"68","author":"Choi","year":"2007","journal-title":"Spectrochim. Acta Part A"},{"key":"wm5123_bb6","doi-asserted-by":"crossref","first-page":"m1186","DOI":"10.1107\/S1600536808026081","volume":"64","author":"Choi","year":"2008","journal-title":"Acta Cryst. E"},{"key":"wm5123_bb7","doi-asserted-by":"crossref","first-page":"84","DOI":"10.1016\/j.molstruc.2009.05.048","volume":"932","author":"Choi","year":"2009","journal-title":"J. Mol. Struct."},{"key":"wm5123_bb8","doi-asserted-by":"crossref","first-page":"325","DOI":"10.1016\/j.molstruc.2013.12.008","volume":"1059","author":"Choi","year":"2014","journal-title":"J. Mol. Struct."},{"key":"wm5123_bb9","doi-asserted-by":"crossref","first-page":"7","DOI":"10.1016\/j.chemphys.2003.09.037","volume":"297","author":"Choi","year":"2004","journal-title":"Chem. Phys."},{"key":"wm5123_bb10","doi-asserted-by":"crossref","first-page":"39","DOI":"10.1016\/j.molstruc.2004.01.034","volume":"694","author":"Choi","year":"2004","journal-title":"J. Mol. Struct."},{"key":"wm5123_bb11","doi-asserted-by":"crossref","first-page":"7842","DOI":"10.1021\/jp303512a","volume":"116","author":"Dreiser","year":"2012","journal-title":"J. Phys. Chem. A"},{"key":"wm5123_bb12","doi-asserted-by":"crossref","first-page":"6560","DOI":"10.1021\/ic981095x","volume":"37","author":"Ferreira","year":"1998","journal-title":"Inorg. Chem."},{"key":"wm5123_bb13","doi-asserted-by":"crossref","first-page":"m139","DOI":"10.1107\/S1600536810053845","volume":"67","author":"Gao","year":"2011","journal-title":"Acta Cryst. E"},{"key":"wm5123_bb14","doi-asserted-by":"crossref","first-page":"247","DOI":"10.3891\/acta.chem.scand.24-0247","volume":"24","author":"Glerup","year":"1970","journal-title":"Acta Chem. Scand."},{"key":"wm5123_bb15","doi-asserted-by":"crossref","first-page":"662","DOI":"10.1002\/anie.201306438","volume":"53","author":"Groom","year":"2014","journal-title":"Angew. Chem. Int. Ed."},{"key":"wm5123_bb16","doi-asserted-by":"crossref","first-page":"e238","DOI":"10.1107\/S0108270100006107","volume":"56","author":"Luck","year":"2000","journal-title":"Acta Cryst. C"},{"key":"wm5123_bb17","doi-asserted-by":"crossref","first-page":"774","DOI":"10.1016\/j.saa.2014.11.099","volume":"138","author":"Moon","year":"2015","journal-title":"Spectrochim. Acta A Part A"},{"key":"wm5123_bb18","unstructured":"Otwinowski, Z. & Minor, W. (1997). Methods in Enzymology, Vol. 276, Macromolecular Crystallography, Part A, edited by C. W. Carter Jr & R. M. Sweet, pp. 307-326. New York: Academic Press."},{"key":"wm5123_bb19","doi-asserted-by":"crossref","unstructured":"Powell, R. C. (1998). In Physics of Solid-State Laser Materials. New York: AIP Press.","DOI":"10.1007\/978-1-4612-0643-9"},{"key":"wm5123_bb20","unstructured":"Putz, H. & Brandenburg, K. (2014). DIAMOND. Crystal Impact GbR, Bonn, Germany."},{"key":"wm5123_bb21","doi-asserted-by":"crossref","first-page":"6969","DOI":"10.1021\/ic300882r","volume":"51","author":"Scarborough","year":"2012","journal-title":"Inorg. Chem."},{"key":"wm5123_bb22","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053273314026370","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. A"},{"key":"wm5123_bb23","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"wm5123_bb24","doi-asserted-by":"crossref","first-page":"920","DOI":"10.1107\/S0021889810022120","volume":"43","author":"Westrip","year":"2010","journal-title":"J. Appl. Cryst."}],"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2015\/03\/00\/wm5123\/wm5123.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2015\/03\/00\/wm5123\/wm5123.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T10:13:13Z","timestamp":1736763193000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2056989015003266"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2015,2,21]]},"references-count":24,"journal-issue":{"issue":"3","published-online":{"date-parts":[[2015,3]]}},"alternative-id":["S2056989015003266"],"URL":"https:\/\/doi.org\/10.1107\/s2056989015003266","relation":{},"ISSN":["2056-9890"],"issn-type":[{"type":"electronic","value":"2056-9890"}],"subject":[],"published":{"date-parts":[[2015,2,21]]},"assertion":[{"value":"Acta Crystallographica Section E: Crystallographic Communications","name":"journal","label":"Journal","explanation":{"URL":"http:\/\/journals.iucr.org\/e"}},{"value":"research communications","name":"content_type","label":"Content type","explanation":{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2011\/01\/00\/me0439\/index.html"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"3 February 2015","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"16 February 2015","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"21 February 2015","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"http:\/\/scripts.iucr.org\/cgi-bin\/sendsup?wm5123"}},{"value":"\u00a9 2015 Moon and Choi","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}