{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,17]],"date-time":"2026-09-17T18:47:06Z","timestamp":1789670826964,"version":"4.0.1"},"reference-count":12,"publisher":"International Union of Crystallography (IUCr)","issue":"3","license":[{"start":{"date-parts":[[2015,2,28]],"date-time":"2015-02-28T00:00:00Z","timestamp":1425081600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2015,2,28]],"date-time":"2015-02-28T00:00:00Z","timestamp":1425081600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2015,3,1]]},"abstract":"<jats:p>The title compound, [Mg(C<jats:sub>44<\/jats:sub>H<jats:sub>24<\/jats:sub>Br<jats:sub>4<\/jats:sub>N<jats:sub>4<\/jats:sub>)(H<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub>] or [Mg(TBrPP)(H<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub>], where TBrPP is the 5,10,15,20-tetrakis(4-bromophenyl)porphyrinato ligand, was obtained unintentionally as a by-product of the reaction of the [Mg(TBrPP)] complex with an excess of dimethylglyoxime in dichloromethane. The entire molecule exhibits point group symmetry 4\/<jats:italic>m<\/jats:italic>. In the asymmetric unit, except for two C atoms of the phenyl ring, all other atoms lie on special positions. The Mg<jats:sup>II<\/jats:sup>atom is situated at a site with symmetry 4\/<jats:italic>m<\/jats:italic>, while the N and the C atoms of the porphyrin macrocycle, as well as two C atoms of the phenyl ring and the Br atom lie in the mirror plane containing the porphyrin core. The H atoms of the axially bonded water molecule are incompatible with the fourfold rotation axis and are disordered over two sites. In the crystal, molecules are packed in rows along [001]. Weak intermolecular C\u2014H...\u03c0 and C\u2014H...Br interactions, as well as O\u2014H...Br hydrogen bonds, stabilize the crystal packing.<\/jats:p>","DOI":"10.1107\/s2056989015003722","type":"journal-article","created":{"date-parts":[[2015,2,27]],"date-time":"2015-02-27T09:23:56Z","timestamp":1425029036000},"page":"m73-m74","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":12,"title":["Crystal structure of diaqua[5,10,15,20-tetrakis(4-bromophenyl)porphyrinato-\u03ba<sup>4<\/sup><i>N<\/i>]magnesium"],"prefix":"10.1107","volume":"71","author":[{"given":"Nesrine","family":"Amiri","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Soumaya","family":"Nasri","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Thierry","family":"Roisnel","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"G\u00e9rard","family":"Simonneaux","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Habib","family":"Nasri","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2015,2,28]]},"reference":[{"key":"wm5127_bb1","doi-asserted-by":"crossref","first-page":"115","DOI":"10.1107\/S0021889898007717","volume":"32","author":"Altomare","year":"1999","journal-title":"J. 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