{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,11,25]],"date-time":"2025-11-25T13:58:15Z","timestamp":1764079095939,"version":"3.33.0"},"reference-count":28,"publisher":"International Union of Crystallography (IUCr)","issue":"5","license":[{"start":{"date-parts":[[2015,4,2]],"date-time":"2015-04-02T00:00:00Z","timestamp":1427932800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2015,4,2]],"date-time":"2015-04-02T00:00:00Z","timestamp":1427932800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2015,5,1]]},"abstract":"<jats:p>The crystal structures of dichloridopalladium(II), -platinum(II) and -rhodium(III) complexes containing 8-(diphenylphosphanyl)quinoline, (<jats:italic>SP<\/jats:italic>-4)-[PdCl<jats:sub>2<\/jats:sub>(C<jats:sub>21<\/jats:sub>H<jats:sub>16<\/jats:sub>NP)], (1) [systematic name: dichlorido(8-diphenylphosphanylquinoline)palladium(II)], (<jats:italic>SP<\/jats:italic>-4)-[PtCl<jats:sub>2<\/jats:sub>(C<jats:sub>21<\/jats:sub>H<jats:sub>16<\/jats:sub>NP)]\u00b7CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>, (2) [systematic name: dichlorido(8-diphenylphosphanylquinoline)platinum(II) dichloromethane monosolvate], and (<jats:italic>OC<\/jats:italic>-6\u201332)-[RhCl<jats:sub>2<\/jats:sub>(C<jats:sub>21<\/jats:sub>H<jats:sub>16<\/jats:sub>NP)<jats:sub>2<\/jats:sub>]PF<jats:sub>6<\/jats:sub>\u00b70.5CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>\u00b70.5CH<jats:sub>3<\/jats:sub>OH, (3) [systematic name:<jats:italic>cis<\/jats:italic>-dichloridobis(8-diphenylphosphanylquinoline)rhodium(III) hexafluoridophosphate dichloromethane\/methanol hemisolvate] are reported. In these complexes, the phosphanylquinoline acts as a bidentate ligand, forming a planar asymmetrical five-membered chelate ring. The palladium(II) and platinum(II) complex molecules in (1) and (2), respectively, show a typical square-planar coordination geometry and form a dimeric structure through an intermolecular \u03c0\u2013\u03c0 stacking interaction between the quinolyl rings. The centroid\u2013centroid distances between the stacked six-membered rings in (1) and (2) are 3.633\u2005(2) and 3.644\u2005(2)\u2005\u00c5, respectively. The cationic rhodium(III) complex in (3) has a<jats:italic>cis(Cl),cis(P),cis(N)<\/jats:italic>(<jats:italic>OC<\/jats:italic>-6\u201332) configuration of the ligands, in which two kinds of intramolecular \u03c0\u2013\u03c0 stacking interactions are observed: between the quinolyl and phenyl rings and between two phenyl rings, the centroid\u2013centroid distances being 3.458\u2005(2) and 3.717\u2005(2)\u2005\u00c5, respectively. The PF<jats:sub>6<\/jats:sub><jats:sup>\u2212<\/jats:sup>anion in (3) is rotationally disordered, the site occupancies of each F atom being 0.613\u2005(14) and 0.387\u2005(14). The CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>and CH<jats:sub>3<\/jats:sub>OH solvent molecules are also disordered and equal site occupancies of 0.5 are assumed.<\/jats:p>","DOI":"10.1107\/s2056989015006076","type":"journal-article","created":{"date-parts":[[2015,4,1]],"date-time":"2015-04-01T20:40:14Z","timestamp":1427920814000},"page":"447-451","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":6,"title":["Crystal structures of dichloridopalladium(II), -platinum(II) and -rhodium(III) complexes containing 8-(diphenylphosphanyl)quinoline"],"prefix":"10.1107","volume":"71","author":[{"given":"Takayoshi","family":"Suzuki","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hiroshi","family":"Yamaguchi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Masayuki","family":"Fujiki","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Akira","family":"Hashimoto","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hideo D.","family":"Takagi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2015,4,2]]},"reference":[{"key":"is5392_bb1","doi-asserted-by":"crossref","first-page":"5419","DOI":"10.1039\/b704615b","author":"Aguirre","year":"2007","journal-title":"Dalton Trans."},{"key":"is5392_bb2","unstructured":""},{"key":"is5392_bb3","unstructured":"Beurskens, P. 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