{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,9]],"date-time":"2026-02-09T23:38:14Z","timestamp":1770680294744,"version":"3.49.0"},"reference-count":23,"publisher":"International Union of Crystallography (IUCr)","issue":"5","license":[{"start":{"date-parts":[[2015,4,22]],"date-time":"2015-04-22T00:00:00Z","timestamp":1429660800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2015,4,22]],"date-time":"2015-04-22T00:00:00Z","timestamp":1429660800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2015,5,1]]},"abstract":"<jats:p>The structure of the title compound, [Cr(NCS)<jats:sub>2<\/jats:sub>(cyclam)]<jats:sub>2<\/jats:sub>[ZnCl<jats:sub>4<\/jats:sub>] (cyclam = 1,4,8,11-tetraazacyclotetradecane, C<jats:sub>10<\/jats:sub>H<jats:sub>24<\/jats:sub>N<jats:sub>4<\/jats:sub>), has been determined from synchrotron data. The asymmetric unit contains two independent halves of the Cr<jats:sup>III<\/jats:sup>complex cations and half of a tetrachloridozincate anion. In each complex cation, the Cr<jats:sup>III<\/jats:sup>atom is coordinated by the four N atoms of the cyclam ligand in the equatorial plane and by two N-bound NCS<jats:sup>\u2212<\/jats:sup>anions in a<jats:italic>trans<\/jats:italic>axial arrangement, displaying a distorted octahedral geometry with crystallographic inversion symmetry. The mean Cr\u2014N(cyclam) and Cr\u2014N(NCS) bond lengths are 2.065\u2005(4) and 1.995\u2005(6)\u2005\u00c5, respectively. The macrocyclic cyclam moieties adopt centrosymmetric<jats:italic>trans<\/jats:italic>-III configurations with six- and five-membered chelate rings in chair and<jats:italic>gauche<\/jats:italic>configurations, respectively. The [ZnCl<jats:sub>4<\/jats:sub>]<jats:sup>2\u2212<\/jats:sup>anion, which lies about a twofold rotation axis, has a slightly distorted tetrahedral geometry. The crystal packing is stabilized by hydrogen-bonding interactions between the N\u2014H groups of the cyclam ligands, the S atoms of the NCS<jats:sup>\u2212<\/jats:sup>groups and the Cl<jats:sup>\u2212<\/jats:sup>ligands of the anion.<\/jats:p>","DOI":"10.1107\/s205698901500746x","type":"journal-article","created":{"date-parts":[[2015,4,21]],"date-time":"2015-04-21T11:49:36Z","timestamp":1429616976000},"page":"540-543","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":6,"title":["Crystal structure of bis[<i>trans<\/i>-(1,4,8,11-tetraazacyclotetradecane-\u03ba<sup>4<\/sup><i>N<\/i>)bis(thiocyanato-\u03ba<i>N<\/i>)chromium(III)] tetrachloridozincate from synchrotron data"],"prefix":"10.1107","volume":"71","author":[{"given":"Dohyun","family":"Moon","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Keon Sang","family":"Ryoo","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jong-Ha","family":"Choi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2015,4,22]]},"reference":[{"key":"sj5452_bb1","unstructured":"Arvai, A. 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