{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:16:46Z","timestamp":1736831806484,"version":"3.33.0"},"reference-count":7,"publisher":"International Union of Crystallography (IUCr)","issue":"6","license":[{"start":{"date-parts":[[2015,5,13]],"date-time":"2015-05-13T00:00:00Z","timestamp":1431475200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2015,5,13]],"date-time":"2015-05-13T00:00:00Z","timestamp":1431475200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2015,6,1]]},"abstract":"<jats:p>The crystal structure of the title compound, [Cd(NCS)<jats:sub>2<\/jats:sub>(C<jats:sub>6<\/jats:sub>H<jats:sub>7<\/jats:sub>NO)<jats:sub>2<\/jats:sub>]<jats:sub><jats:italic>n<\/jats:italic><\/jats:sub>is made up of Cd<jats:sup>2+<\/jats:sup>cations that are coordinated by three thiocyanate ligands and three 4-(hydroxymethyl)pyridine ligands within distorted N<jats:sub>4<\/jats:sub>OS octahedra. The asymmetric unit consists of one Cd<jats:sup>2+<\/jats:sup>cation, two thiocyanate anions and two 4-(hydroxymethyl)pyridine ligands in general positions. Two Cd<jats:sup>2+<\/jats:sup>cations are linked by two \u03bc-1,3<jats:italic>N<\/jats:italic>- and<jats:italic>S<\/jats:italic>-bonding thioycanate anions into dimers which are further linked into branched chains along [100] by two \u03bc-1,6<jats:italic>N<\/jats:italic>- and<jats:italic>O<\/jats:italic>-bonding 4-(hydroxymethyl)pyridine ligands. One additional<jats:italic>N<\/jats:italic>-bonded 4-(hydroxymethyl)pyridine ligand and one additional<jats:italic>N<\/jats:italic>-bonded thiocyanate anion are only terminally bonded to the metal cation. Interchain O\u2014H...S hydrogen bonds between the hydroxy H atoms and one of the thiocyanate S atoms connect the chains into a three-dimensional network.<\/jats:p>","DOI":"10.1107\/s2056989015008890","type":"journal-article","created":{"date-parts":[[2015,5,12]],"date-time":"2015-05-12T09:46:54Z","timestamp":1431424014000},"page":"m129-m130","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structure of poly[[\u03bc-4-(hydroxymethyl)pyridine-\u03ba<sup>2<\/sup><i>N<\/i>:<i>O<\/i>][4-(hydroxymethyl)pyridine-\u03ba<i>N<\/i>](\u03bc-thiocyanato-\u03ba<sup>2<\/sup><i>N<\/i>:<i>S<\/i>)(thiocyanato-\u03ba<i>N<\/i>)cadmium]"],"prefix":"10.1107","volume":"71","author":[{"given":"Julia","family":"Werner","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Inke","family":"Jess","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Christian","family":"N\u00e4ther","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2015,5,13]]},"reference":[{"key":"wm5156_bb1","doi-asserted-by":"crossref","first-page":"535","DOI":"10.1016\/j.ica.2004.07.048","volume":"358","author":"Banerjee","year":"2005","journal-title":"Inorg. 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