{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:16:56Z","timestamp":1736831816285,"version":"3.33.0"},"reference-count":19,"publisher":"International Union of Crystallography (IUCr)","issue":"6","license":[{"start":{"date-parts":[[2015,5,16]],"date-time":"2015-05-16T00:00:00Z","timestamp":1431734400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2015,5,16]],"date-time":"2015-05-16T00:00:00Z","timestamp":1431734400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2015,6,1]]},"abstract":"<jats:p>Caesium chromium(III) diarsenate(V), CsCrAs<jats:sub>2<\/jats:sub>O<jats:sub>7<\/jats:sub>, was prepared by solid-state reactions. The title structure consists of isolated CrO<jats:sub>6<\/jats:sub>octahedra and As<jats:sub>2<\/jats:sub>O<jats:sub>7<\/jats:sub>diarsenate groups, sharing corners to build up a three-dimensional [CrAs<jats:sub>2<\/jats:sub>O<jats:sub>7<\/jats:sub>]<jats:sup>\u2212<\/jats:sup>anionic framework. In this framework, channels extending parallel to [001] are present in which the ten-coordinate Cs<jats:sup>+<\/jats:sup>ions reside. CsCrAs<jats:sub>2<\/jats:sub>O<jats:sub>7<\/jats:sub>is isotypic with the monoclinic<jats:italic>A<\/jats:italic><jats:sup>I<\/jats:sup><jats:italic>M<\/jats:italic><jats:sup>III<\/jats:sup><jats:italic>X<\/jats:italic><jats:sub>2<\/jats:sub>O<jats:sub>7<\/jats:sub>(<jats:italic>A<\/jats:italic><jats:sup>I<\/jats:sup>= alkali metal;<jats:italic>M<\/jats:italic><jats:sup>III<\/jats:sup>= Al, Cr, Fe;<jats:italic>X<\/jats:italic>= As, P) type I family of compounds crystallizing in the space group<jats:italic>P<\/jats:italic>2<jats:sub>1<\/jats:sub>\/<jats:italic>c<\/jats:italic>.<\/jats:p>","DOI":"10.1107\/s205698901500910x","type":"journal-article","created":{"date-parts":[[2015,5,14]],"date-time":"2015-05-14T15:06:56Z","timestamp":1431616016000},"page":"636-639","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":4,"title":["Crystal structure of CsCrAs<sub>2<\/sub>O<sub>7<\/sub>, a new member of the diarsenate family"],"prefix":"10.1107","volume":"71","author":[{"given":"Mohamad Alem","family":"Bouhassine","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Habib","family":"Boughzala","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2015,5,16]]},"reference":[{"key":"wm5157_bb1","doi-asserted-by":"crossref","first-page":"53","DOI":"10.1524\/zkri.1982.161.1-2.53","volume":"161","author":"Bohat\u00fd","year":"1982","journal-title":"Z. Kristallogr."},{"key":"wm5157_bb2","doi-asserted-by":"crossref","first-page":"425","DOI":"10.1107\/S0108270192006772","volume":"49","author":"Boughzala","year":"1993","journal-title":"Acta Cryst. C"},{"key":"wm5157_bb3","first-page":"1419","volume":"II","author":"Boughzala","year":"1992","journal-title":"C. R. Acad. Sci. Paris Ser."},{"key":"wm5157_bb4","doi-asserted-by":"crossref","first-page":"179","DOI":"10.1107\/S0108270194010395","volume":"51","author":"Boughzala","year":"1995","journal-title":"Acta Cryst. C"},{"key":"wm5157_bb5","unstructured":"Brandenburg, K. (2008). DIAMOND. Crystal Impact GbR, Bonn, Germany."},{"key":"wm5157_bb6","unstructured":"Brown, I. D. (2002). In he Chemical Bond in Inorganic Chemistry: The Bond Valence Model. Oxford University Press."},{"key":"wm5157_bb7","unstructured":"Enraf-Nonius (1994). CAD-4 EXPRESS. Enraf-Nonius, Delft, The Netherlands."},{"key":"wm5157_bb8","doi-asserted-by":"crossref","first-page":"389","DOI":"10.1016\/0022-4596(82)90184-0","volume":"45","author":"Gabelica-Robert","year":"1982","journal-title":"J. Solid State Chem."},{"key":"wm5157_bb9","doi-asserted-by":"crossref","first-page":"35","DOI":"10.1080\/00150199708222186","volume":"204","author":"Gentil","year":"1997","journal-title":"Ferroelectrics"},{"key":"wm5157_bb10","unstructured":"Harms, K. & Wocadlo, S. (1995). XCAD4. University of Marburg, Germany."},{"key":"wm5157_bb11","doi-asserted-by":"crossref","first-page":"i70","DOI":"10.1107\/S1600536807005752","volume":"63","author":"Ivashkevich","year":"2007","journal-title":"Acta Cryst. E"},{"key":"wm5157_bb12","first-page":"464","volume":"18","author":"Linde","year":"1982","journal-title":"Izv. Akad. Nauk SSSR Neorg. Mater."},{"key":"wm5157_bb13","doi-asserted-by":"crossref","first-page":"2613","DOI":"10.1139\/v73-395","volume":"51","author":"Ng","year":"1973","journal-title":"Can. J. Chem."},{"key":"wm5157_bb14","doi-asserted-by":"crossref","first-page":"351","DOI":"10.1107\/S0567739468000707","volume":"24","author":"North","year":"1968","journal-title":"Acta Cryst. A"},{"key":"wm5157_bb15","first-page":"215","volume":"25","author":"Riou","year":"1988","journal-title":"Eur. J. Solid. State Inorg. Chem."},{"key":"wm5157_bb16","doi-asserted-by":"crossref","first-page":"1363","DOI":"10.1016\/0025-5408(90)90218-Q","volume":"25","author":"Riou","year":"1990","journal-title":"Mater. Res. Bull."},{"key":"wm5157_bb17","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","volume":"64","author":"Sheldrick","year":"2008","journal-title":"Acta Cryst. A"},{"key":"wm5157_bb18","doi-asserted-by":"crossref","first-page":"920","DOI":"10.1107\/S0021889810022120","volume":"43","author":"Westrip","year":"2010","journal-title":"J. Appl. Cryst."},{"key":"wm5157_bb19","first-page":"443","volume":"226","author":"Zhao","year":"2011","journal-title":"Z. Kristallogr."}],"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2015\/06\/00\/wm5157\/wm5157.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2015\/06\/00\/wm5157\/wm5157.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T10:36:58Z","timestamp":1736764618000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S205698901500910X"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2015,5,16]]},"references-count":19,"journal-issue":{"issue":"6","published-online":{"date-parts":[[2015,6]]}},"alternative-id":["S205698901500910X"],"URL":"https:\/\/doi.org\/10.1107\/s205698901500910x","relation":{},"ISSN":["2056-9890"],"issn-type":[{"type":"electronic","value":"2056-9890"}],"subject":[],"published":{"date-parts":[[2015,5,16]]},"assertion":[{"value":"Acta Crystallographica Section E: Crystallographic Communications","name":"journal","label":"Journal","explanation":{"URL":"http:\/\/journals.iucr.org\/e"}},{"value":"research communications","name":"content_type","label":"Content type","explanation":{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2011\/01\/00\/me0439\/index.html"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"4 May 2015","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"11 May 2015","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"16 May 2015","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"http:\/\/scripts.iucr.org\/cgi-bin\/sendsup?wm5157"}},{"value":"\u00a9 2015 Bouhassine and Boughzala","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}