{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T00:46:26Z","timestamp":1789951586729,"version":"4.0.1"},"reference-count":17,"publisher":"International Union of Crystallography (IUCr)","issue":"9","license":[{"start":{"date-parts":[[2015,8,6]],"date-time":"2015-08-06T00:00:00Z","timestamp":1438819200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2015,8,6]],"date-time":"2015-08-06T00:00:00Z","timestamp":1438819200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2015,9,1]]},"abstract":"<jats:p>The title compound, [Re<jats:sub>6<\/jats:sub>Se<jats:sub>8<\/jats:sub>{O<jats:sub>3<\/jats:sub>SC<jats:sub>6<\/jats:sub>H<jats:sub>4<\/jats:sub>(CH<jats:sub>3<\/jats:sub>)}{P(C<jats:sub>2<\/jats:sub>H<jats:sub>5<\/jats:sub>)<jats:sub>3<\/jats:sub>}<jats:sub>5<\/jats:sub>](CH<jats:sub>3<\/jats:sub>C<jats:sub>6<\/jats:sub>H<jats:sub>4<\/jats:sub>SO<jats:sub>3<\/jats:sub>)\u00b72CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>, contains the face-capped hexanuclear [Re<jats:sub>6<\/jats:sub>(\u03bc<jats:sub>3<\/jats:sub>-Se)<jats:sub>8<\/jats:sub>]<jats:sup>2+<\/jats:sup>cluster core. The [Re<jats:sub>6<\/jats:sub>Se<jats:sub>8<\/jats:sub>]<jats:sup>2+<\/jats:sup>cluster core displays a non-crystallographic center of symmetry and is bonded through the Re<jats:sup>III<\/jats:sup>atoms to five triethylphosphane ligands and one<jats:italic>p<\/jats:italic>-toluenesulfonate ligand. One<jats:italic>p<\/jats:italic>-toluenesulfonate counter-ion and two dichloromethane solvent molecules are also present in the asymmetric unit. One of the ethyl chains of one triethylphosphane ligand and one of the CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>solvent molecules are disordered over two sets of sites (occupancy ratios 0.65:0.35 and 0.5:0.5, respectively). The Re\u2014O(sulfonate) bond length of 2.123\u2005(5)\u2005\u00c5 is similar to other Re\u2014O bond lengths of hexanuclear rhenium chalcogenide clusters containing other<jats:italic>O<\/jats:italic>-donor ligands such as dimethyl sulfoxide (DMSO), dimethylformamide (DMF) and hydroxide.<\/jats:p>","DOI":"10.1107\/s2056989015014334","type":"journal-article","created":{"date-parts":[[2015,8,5]],"date-time":"2015-08-05T09:04:05Z","timestamp":1438765445000},"page":"m158-m159","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":5,"title":["Crystal structure of octa-\u03bc<sub>3<\/sub>-selenido-(<i>p<\/i>-toluenesulfonato-\u03ba<i>O<\/i>)pentakis(triethylphosphane-\u03ba<i>P<\/i>)-<i>octahedro<\/i>-hexarhenium(III)<i>p<\/i>-toluenesulfonate dichloromethane disolvate"],"prefix":"10.1107","volume":"71","author":[{"given":"Julia A.","family":"Edwards","sequence":"first","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Robert","family":"McDonald","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lisa F.","family":"Szczepura","sequence":"additional","affiliation":[],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"329","published-online":{"date-parts":[[2015,8,6]]},"reference":[{"key":"pj2021_bb1","unstructured":"Beurskens, P. 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