{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:17:27Z","timestamp":1736831847926,"version":"3.33.0"},"reference-count":42,"publisher":"International Union of Crystallography (IUCr)","issue":"9","license":[{"start":{"date-parts":[[2015,8,26]],"date-time":"2015-08-26T00:00:00Z","timestamp":1440547200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2015,8,26]],"date-time":"2015-08-26T00:00:00Z","timestamp":1440547200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2015,9,1]]},"abstract":"<jats:p>The title compound, [CoFe(C<jats:sub>5<\/jats:sub>H<jats:sub>5<\/jats:sub>)(C<jats:sub>16<\/jats:sub>H<jats:sub>14<\/jats:sub>N<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub>)(C<jats:sub>11<\/jats:sub>H<jats:sub>9<\/jats:sub>N<jats:sub>2<\/jats:sub>O)], was prepared as an air-stable red\u2013brown solid by mixing equimolar amounts of {2,2\u2032-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato}cobalt(II) and<jats:italic>N<\/jats:italic>-ferrocenylisonicotinamide in dry dichloromethane under nitrogen and was characterized by ESI\u2013MS, IR, and single-crystal X-ray diffraction. The structure at 100\u2005K has triclinic (<jats:italic>P<\/jats:italic>-1) symmetry and indicates that the complex crystallizes as a mixture of \u03bb and \u03b4 conformers. It exhibits the expected square pyramidal geometry about Co, and forms hydrogen-bonded dimers through amide N\u2014H groups and phenolate O atoms on an adjacent molecule. The involvement of only half of the salen ring structure in hydrogen-bonding interactions results in slight folding of the salen ring away from the pyridine coordination site in the \u03b4 conformer with an inter-salicylidene fold angle of 9.9\u2005(7)\u00b0. In contrast, the \u03bb conformer is nearly planar. The dimers pack into an open structure containing channels filled with highly disordered solvent molecules. These solvent molecules' contributions to the intensity data were removed with the SQUEEZE procedure [Spek (2015).<jats:italic>Acta Cryst.<\/jats:italic>C<jats:bold>71<\/jats:bold>, 9\u201318] available in<jats:italic>PLATON<\/jats:italic>.<\/jats:p>","DOI":"10.1107\/s2056989015014723","type":"journal-article","created":{"date-parts":[[2015,8,25]],"date-time":"2015-08-25T09:10:53Z","timestamp":1440493853000},"page":"1100-1104","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":0,"title":["Crystal structure of an unknown solvate of {2,2\u2032-[ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato-\u03ba<sup>4<\/sup><i>O<\/i>,<i>N<\/i>,<i>N<\/i>\u2032,<i>O<\/i>\u2032}(<i>N<\/i>-ferrocenylisonicotinamide-\u03ba<i>N<\/i><sup>1<\/sup>)cobalt(II): a Co<sup>II<\/sup>\u2013salen complex that forms hydrogen-bonded dimers"],"prefix":"10.1107","volume":"71","author":[{"given":"Bryan","family":"Brautigam","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Chelsea","family":"Herholdt","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"William","family":"Farnsworth","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ellen","family":"Brudi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Eric","family":"McDonald","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Guang","family":"Wu","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Stephen","family":"Contakes","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2015,8,26]]},"reference":[{"key":"zl2632_bb1","doi-asserted-by":"crossref","unstructured":"Allen, F. H., Watson, D. G., Brammer, L., Orpen, A. G. & Taylor, R. (2006). International Tables for Crystallography, Vol. C, edited by E. Prince, pp. 790-811. Chester: International Union of Crystallography.","DOI":"10.1107\/97809553602060000621"},{"key":"zl2632_bb2","doi-asserted-by":"crossref","first-page":"4965","DOI":"10.1002\/chem.200600156","volume":"12","author":"Barisi\u0107","year":"2006","journal-title":"Chem. Eur. J."},{"key":"zl2632_bb3","doi-asserted-by":"crossref","first-page":"59","DOI":"10.1107\/S2053273314022207","volume":"71","author":"Bourhis","year":"2015","journal-title":"Acta Cryst. A"},{"key":"zl2632_bb4","doi-asserted-by":"crossref","first-page":"1671","DOI":"10.1107\/S0567740869004523","volume":"25","author":"Br\u00fcckner","year":"1969","journal-title":"Acta Cryst. B"},{"key":"zl2632_bb5","unstructured":"Bruker (2005). APEX2. Bruker AXS Inc., Madison, Wisconsin, USA."},{"key":"zl2632_bb6","doi-asserted-by":"crossref","first-page":"2411","DOI":"10.1039\/J19700002411","volume":"A","author":"Calligaris","year":"1970","journal-title":"J. Chem. Soc."},{"key":"zl2632_bb7","doi-asserted-by":"crossref","first-page":"477","DOI":"10.1016\/0020-1650(72)80257-5","volume":"8","author":"Calligaris","year":"1972","journal-title":"Inorg. Nucl. Chem. Lett."},{"key":"zl2632_bb8","doi-asserted-by":"crossref","first-page":"2254","DOI":"10.1021\/ja01215a041","volume":"68","author":"Calvin","year":"1946","journal-title":"J. Am. Chem. Soc."},{"key":"zl2632_bb9","doi-asserted-by":"crossref","first-page":"2647","DOI":"10.1021\/ic00312a029","volume":"28","author":"Chen","year":"1989","journal-title":"Inorg. Chem."},{"key":"zl2632_bb10","doi-asserted-by":"crossref","first-page":"410","DOI":"10.1039\/B307853C","volume":"33","author":"Cozzi","year":"2004","journal-title":"Chem. Soc. Rev."},{"key":"zl2632_bb11","doi-asserted-by":"crossref","first-page":"16788","DOI":"10.1021\/ja5105602","volume":"136","author":"Crossley","year":"2014","journal-title":"J. Am. Chem. Soc."},{"key":"zl2632_bb12","unstructured":"Dai, L.-X. & Hou, X.-L. (2010). In Chiral Ferrocenes in Asymmetric Catalysis. Weinheim: Wiley-VCH."},{"key":"zl2632_bb13","doi-asserted-by":"crossref","first-page":"2388","DOI":"10.1021\/cr068363q","volume":"107","author":"Darensbourg","year":"2007","journal-title":"Chem. Rev."},{"key":"zl2632_bb14","doi-asserted-by":"crossref","first-page":"339","DOI":"10.1107\/S0021889808042726","volume":"42","author":"Dolomanov","year":"2009","journal-title":"J. Appl. Cryst."},{"key":"zl2632_bb15","doi-asserted-by":"crossref","first-page":"520","DOI":"10.1002\/recl.19670860506","volume":"86","author":"Dort","year":"1967","journal-title":"Recl. Trav. Chim. Pays Bas"},{"key":"zl2632_bb16","doi-asserted-by":"crossref","first-page":"946","DOI":"10.1039\/j19690000946","volume":"A","author":"Floriani","year":"1969","journal-title":"J. Chem. Soc."},{"key":"zl2632_bb17","doi-asserted-by":"crossref","first-page":"15595","DOI":"10.1021\/ja408027p","volume":"135","author":"Ford","year":"2013","journal-title":"J. Am. Chem. Soc."},{"key":"zl2632_bb18","doi-asserted-by":"crossref","first-page":"2170","DOI":"10.1021\/ic50127a047","volume":"12","author":"Fritch","year":"1973","journal-title":"Inorg. Chem."},{"key":"zl2632_bb19","doi-asserted-by":"crossref","first-page":"1420","DOI":"10.1016\/j.ccr.2007.09.005","volume":"252","author":"Gupta","year":"2008","journal-title":"Coord. Chem. Rev."},{"key":"zl2632_bb20","doi-asserted-by":"crossref","first-page":"1498","DOI":"10.1021\/ic50101a036","volume":"10","author":"Holt","year":"1971","journal-title":"Inorg. Chem."},{"key":"zl2632_bb21","doi-asserted-by":"crossref","first-page":"453","DOI":"10.1107\/S002188980600731X","volume":"39","author":"Macrae","year":"2006","journal-title":"J. Appl. Cryst."},{"key":"zl2632_bb22","doi-asserted-by":"crossref","first-page":"248","DOI":"10.1016\/j.jorganchem.2006.08.067","volume":"692","author":"Okamura","year":"2007","journal-title":"J. Organomet. Chem."},{"key":"zl2632_bb23","doi-asserted-by":"crossref","first-page":"1270","DOI":"10.1246\/bcsj.78.1270","volume":"78","author":"Okamura","year":"2005","journal-title":"Bull. Chem. Soc. Jpn"},{"key":"zl2632_bb24","doi-asserted-by":"crossref","first-page":"6731","DOI":"10.1021\/ic9806939","volume":"37","author":"Okamura","year":"1998","journal-title":"Inorg. Chem."},{"key":"zl2632_bb25","doi-asserted-by":"crossref","first-page":"721","DOI":"10.1039\/C4QI00111G","volume":"1","author":"Ou","year":"2014","journal-title":"Inorg. Chem. Front."},{"key":"zl2632_bb26","doi-asserted-by":"crossref","first-page":"36","DOI":"10.1016\/j.inoche.2014.10.035","volume":"51","author":"Patterson","year":"2015","journal-title":"Inorg. Chem. Commun."},{"key":"zl2632_bb27","doi-asserted-by":"crossref","first-page":"340","DOI":"10.1021\/ic50204a013","volume":"19","author":"Schaefer","year":"1980","journal-title":"Inorg. Chem."},{"key":"zl2632_bb28","doi-asserted-by":"crossref","first-page":"1675","DOI":"10.1107\/S0567740869004547","volume":"25","author":"Schaefer","year":"1969","journal-title":"Acta Cryst. B"},{"key":"zl2632_bb29","doi-asserted-by":"crossref","first-page":"1307","DOI":"10.1021\/ja016737l","volume":"124","author":"Schaus","year":"2002","journal-title":"J. Am. Chem. Soc."},{"key":"zl2632_bb30","unstructured":"Sheldrick, G. M. (2012). SADABS. University of G\u00f6ttingen, Germany."},{"key":"zl2632_bb31","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Cryst. C"},{"key":"zl2632_bb32","doi-asserted-by":"crossref","first-page":"206","DOI":"10.1107\/S0108270194009091","volume":"51","author":"Shi","year":"1995","journal-title":"Acta Cryst. C"},{"key":"zl2632_bb33","doi-asserted-by":"crossref","first-page":"148","DOI":"10.1107\/S090744490804362X","volume":"65","author":"Spek","year":"2009","journal-title":"Acta Cryst. D"},{"key":"zl2632_bb34","doi-asserted-by":"crossref","first-page":"9","DOI":"10.1107\/S2053229614024929","volume":"71","author":"Spek","year":"2015","journal-title":"Acta Cryst. C"},{"key":"zl2632_bb35","doi-asserted-by":"crossref","first-page":"48","DOI":"10.1002\/1521-3773(20020104)41:1<48::AID-ANIE48>3.0.CO;2-U","volume":"41","author":"Steiner","year":"2002","journal-title":"Angew. Chem. Int. Ed."},{"key":"zl2632_bb36","doi-asserted-by":"crossref","unstructured":"Stepnicka, P. (2008). In Ferrocenes: Ligands, Materials and Biomolecules. Chichester, West Sussex: John Wiley and Sons Ltd.","DOI":"10.1002\/9780470985663"},{"key":"zl2632_bb37","doi-asserted-by":"crossref","first-page":"936","DOI":"10.1126\/science.277.5328.936","volume":"277","author":"Tokunaga","year":"1997","journal-title":"Science"},{"key":"zl2632_bb38","doi-asserted-by":"crossref","first-page":"252","DOI":"10.1246\/bcsj.13.252","volume":"13","author":"Tsumaki","year":"1938","journal-title":"Bull. Chem. Soc. Jpn"},{"key":"zl2632_bb39","doi-asserted-by":"crossref","first-page":"4165","DOI":"10.1016\/j.tet.2014.03.043","volume":"70","author":"White","year":"2014","journal-title":"Tetrahedron"},{"key":"zl2632_bb40","doi-asserted-by":"crossref","first-page":"537","DOI":"10.1016\/S0010-8545(99)00099-5","volume":"190-192","author":"Yamada","year":"1999","journal-title":"Coord. Chem. Rev."},{"key":"zl2632_bb41","doi-asserted-by":"crossref","first-page":"1691","DOI":"10.1126\/science.1083622","volume":"299","author":"Yoon","year":"2003","journal-title":"Science"},{"key":"zl2632_bb42","doi-asserted-by":"crossref","first-page":"2801","DOI":"10.1021\/ja00163a052","volume":"112","author":"Zhang","year":"1990","journal-title":"J. Am. Chem. Soc."}],"container-title":["Acta Crystallographica Section E Crystallographic Communications"],"original-title":[],"link":[{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2015\/09\/00\/zl2632\/zl2632.pdf","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2015\/09\/00\/zl2632\/zl2632.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,1,13]],"date-time":"2025-01-13T10:45:38Z","timestamp":1736765138000},"score":1,"resource":{"primary":{"URL":"https:\/\/journals.iucr.org\/paper?S2056989015014723"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2015,8,26]]},"references-count":42,"journal-issue":{"issue":"9","published-online":{"date-parts":[[2015,9]]}},"alternative-id":["S2056989015014723"],"URL":"https:\/\/doi.org\/10.1107\/s2056989015014723","relation":{},"ISSN":["2056-9890"],"issn-type":[{"type":"electronic","value":"2056-9890"}],"subject":[],"published":{"date-parts":[[2015,8,26]]},"assertion":[{"value":"Acta Crystallographica Section E: Crystallographic Communications","name":"journal","label":"Journal","explanation":{"URL":"http:\/\/journals.iucr.org\/e"}},{"value":"research communications","name":"content_type","label":"Content type","explanation":{"URL":"http:\/\/journals.iucr.org\/e\/issues\/2011\/01\/00\/me0439\/index.html"}},{"value":"Yes","order":0,"name":"peer_reviewed","label":"Peer reviewed","group":{"name":"peer_review","label":"Peer review"}},{"value":"Single blind","order":1,"name":"review_process","label":"Review process","group":{"name":"peer_review","label":"Peer review"}},{"value":"3 July 2015","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication history"}},{"value":"5 August 2015","order":1,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication history"}},{"value":"26 August 2015","order":2,"name":"published_online","label":"Published online","group":{"name":"publication_history","label":"Publication history"}},{"value":"This article has supporting information","name":"supplementary_materials","label":"Supplementary materials","explanation":{"URL":"http:\/\/scripts.iucr.org\/cgi-bin\/sendsup?zl2632"}},{"value":"\u00a9 2015 Brautigamet al.","order":0,"name":"copyright","label":"Copyright","explanation":{"URL":"http:\/\/journals.iucr.org\/services\/copyrightpolicy.html"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}},{"value":"Creative Commons Attribution (CC-BY)","order":1,"name":"license","label":"Licence","explanation":{"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},"group":{"name":"copyright_and_licencing","label":"Copyright and licencing"}}]}}