{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,1,14]],"date-time":"2025-01-14T05:17:57Z","timestamp":1736831877521,"version":"3.33.0"},"reference-count":23,"publisher":"International Union of Crystallography (IUCr)","issue":"9","license":[{"start":{"date-parts":[[2015,8,22]],"date-time":"2015-08-22T00:00:00Z","timestamp":1440201600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"},{"start":{"date-parts":[[2015,8,22]],"date-time":"2015-08-22T00:00:00Z","timestamp":1440201600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/2.0\/uk\/legalcode"}],"content-domain":{"domain":["iucr.org","wiley.com","iucrj.org"],"crossmark-restriction":true},"short-container-title":["Acta Crystallogr E Cryst Commun","Acta Cryst E","Acta Cryst Sect E","Acta Crystallogr E","Acta Crystallogr Sect E","Acta Cryst E Cryst Commun","Acta Cryst Sect E Cryst Commun"],"published-print":{"date-parts":[[2015,9,1]]},"abstract":"<jats:p>The structure of the title compound,<jats:italic>cis<\/jats:italic>-[CrCl(cyc<jats:italic>b<\/jats:italic>)(H<jats:sub>2<\/jats:sub>O)][ZnCl<jats:sub>4<\/jats:sub>]\u00b73H<jats:sub>2<\/jats:sub>O (cyc<jats:italic>b<\/jats:italic>is<jats:italic>rac<\/jats:italic>-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane; C<jats:sub>16<\/jats:sub>H<jats:sub>36<\/jats:sub>N<jats:sub>4<\/jats:sub>), has been determined from synchrotron data. In the complex cation, the Cr<jats:sup>III<\/jats:sup>ion is bound by four N atoms from the tetradentate cyc<jats:italic>b<\/jats:italic>ligand, a chloride ion and one water molecule in a<jats:italic>cis<\/jats:italic>arrangement, displaying a distorted octahedral coordination geometry. The distorted tetrahedral [ZnCl<jats:sub>4<\/jats:sub>]<jats:sup>2\u2212<\/jats:sup>anion and three additional water molecules remain outside the coordination sphere. The Cr\u2014N(cyc<jats:italic>b<\/jats:italic>) bond lengths are in the range of 2.0837\u2005(14) to 2.1399\u2005(12)\u2005\u00c5 while the Cr\u2014Cl and Cr\u2014(OH<jats:sub>2<\/jats:sub>) bond lengths are 2.2940\u2005(8) and 2.0082\u2005(13)\u2005\u00c5, respectively. The crystal packing is stabilized by hydrogen-bonding interactions between the N\u2014H groups of the macrocyclic ligand, the O\u2014H groups of the water molecules and the Cl atoms of the tetrachloridozincate anion, leading to the formation of a three-dimensional network.<\/jats:p>","DOI":"10.1107\/s2056989015015212","type":"journal-article","created":{"date-parts":[[2015,8,21]],"date-time":"2015-08-21T11:45:54Z","timestamp":1440157554000},"page":"1054-1057","update-policy":"https:\/\/doi.org\/10.1107\/cm_01","source":"Crossref","is-referenced-by-count":1,"title":["Crystal structure of<i>cis<\/i>-aquachlorido(<i>rac<\/i>-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-\u03ba<sup>4<\/sup><i>N<\/i>)chromium(III) tetrachloridozincate trihydrate from synchrotron data"],"prefix":"10.1107","volume":"71","author":[{"given":"Dohyun","family":"Moon","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Jong-Ha","family":"Choi","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"329","published-online":{"date-parts":[[2015,8,22]]},"reference":[{"key":"wm5196_bb1","unstructured":"Arvai, A. 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